Conventional water resources in many regions are insufficient to meet the water needs of growing populations, thus reuse is gaining acceptance as a method of water supply augmentation. Recent ...advancements in membrane technology have allowed for the reclamation of municipal wastewater for the production of drinking water, i.e., potable reuse. Although public perception can be a challenge, potable reuse is often the least energy-intensive method of providing additional drinking water to water stressed regions. A variety of membranes have been developed that can remove water contaminants ranging from particles and pathogens to dissolved organic compounds and salts. Typically, potable reuse treatment plants use polymeric membranes for microfiltration or ultrafiltration in conjunction with reverse osmosis and, in some cases, nanofiltration. Membrane properties, including pore size, wettability, surface charge, roughness, thermal resistance, chemical stability, permeability, thickness and mechanical strength, vary between membranes and applications. Advancements in membrane technology including new membrane materials, coatings, and manufacturing methods, as well as emerging membrane processes such as membrane bioreactors, electrodialysis, and forward osmosis have been developed to improve selectivity, energy consumption, fouling resistance, and/or capital cost. The purpose of this review is to provide a comprehensive summary of the role of polymeric membranes and process components in the treatment of wastewater to potable water quality and to highlight recent advancements and needs in separation processes. Beyond membranes themselves, this review covers the background and history of potable reuse, and commonly used potable reuse process chains, pretreatment steps, and advanced oxidation processes. Key trends in membrane technology include novel configurations, materials, and fouling prevention techniques. Challenges still facing membrane-based potable reuse applications, including chemical and biological contaminant removal, membrane fouling, and public perception, are highlighted as areas in need of further research and development.
To assist in emergency preparedness for a biological agent terrorist attack or accidental pathogen release, potential contaminant levels and migration pathways of spores spread by urban stormwater ...were evaluated using a Storm Water Management Model (SWMM) of U.S. Coast Guard Base Elizabeth City, North Carolina. The high temporal-spatial resolution SWMM model was built using spore concentrations in stormwater runoff from asphalt, grass, and concrete collected from a point-scale field study. The subsequent modeled contamination scenarios included a notional plume release and point releases mimicking the field study under three rainfall conditions. The rainfall scenarios included a 6-hour natural rainfall event on Dec. 8, 2021 and two design storms (2-year and 100-year events). The observed spore concentrations from asphalt and concrete from the actual field experiment were applied to calibrate the washoff parameters in the SWMM model, using an exponential washoff function. The calibrated washoff coefficient (c1) and exponent (c2) were 0.01 and 1.00 for asphalt, 0.05 and 1.45 for grass, and 2.45 and 1.00 for concrete, respectively. The calibrated SWMM model simulated spore concentrations in runoff at times and magnitudes similar to the field study data. In the point release modeled scenario, the concrete surface generated 55.6% higher average spore concentrations than asphalt. Similarly, in the field experiment, a 175% (p < 0.05) higher average spore concentration in surface runoff was observed from concrete than from asphalt. This study demonstrates how SWMM may be used to evaluate spore washoff from urban surfaces under different precipitation amounts, intensities, and durations, and how visualized spatial migration pathways in stormwater runoff may be used for emergency planning and remediation.
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•Calibrated SWMM model using observed spores from a field experiment.•Compared the impact of different types of rainfall and washoff coefficients on spore transport.•Evaluated spores washoff amount from asphalt, grass, and concrete surfaces.•Identified spore migration pathways and hotspot areas under a hypothetical plume scenario.
Development of numerical models to predict stormwater-mediated transport of pathogenic spores in the environment depends on an understanding of adhesion forces that dictate detachment after rain ...events. Zeta potential values were measured in the laboratory for Bacillus globigii and Bacillus thuringiensis kurstaki, two common surrogates used to represent Bacillus anthracis, in synthetic baseline ultrapure water and laboratory prepared stormwater. Zeta potential curves were also determined for materials representative of urban infrastructure (concrete and asphalt). These data were used to predict the interaction energy between the spores and urban materials using Derjaguin-Landau-Verwey-Overbeek (DLVO) modeling. B. globigii and B. thuringiensis kurstaki sourced from Yakibou Inc., were found to have similar zeta potential curves, whereas spores sourced from the U.S. military's Dugway laboratory were found to diverge. In the ultrapure water, the modeling results use the laboratory data to demonstrate that the energy barriers between the spores and the urban materials were tunable through compression of the electrical double layer of the spores via changes of ionic strength and pH of the water. In the runoff water, charge neutralization dominated surface processes. The cations, metals, and natural organic matter (NOM) in the runoff water contributed to equalizing the zeta potential values for Dugway B. globigii and B. thuringiensis kurstaki, and drastically modified the surface of the concrete and asphalt. All DLVO energy curves using the runoff water were repulsive. The highest energy barrier predicted in this study was for Dugway B. globigii spores interacting with a concrete surface in runoff water, suggesting that this would be the most challenging combination to detach through water-based decontamination.
•Stormwater equalizes surface charge differences between different surrogates for B. anthracis.•Surface properties of urban materials dictate spore-surface interactions in stormwater.•DLVO modeling predicted highest energy barrier between B. globigii spores and concrete.
This article examines the influence of three common stabilizing agents (citrate, poly(vinylpyrrolidone) (PVP), and branched poly(ethylenimine) (BPEI)) on the attachment affinity of silver ...nanoparticles to ceramic water filters. Citrate-stabilized silver nanoparticles were found to have the highest attachment affinity (under conditions in which the surface potential was of opposite sign to the filter). This work demonstrates that the interaction between the electrical double layers plays a critical role in the attachment of nanoparticles to flat surfaces and, in particular, that predictions of double-layer interactions are sensitive to boundary condition assumptions (constant charge vs constant potential). The experimental deposition results can be explained when using different boundary condition assumptions for different stabilizing molecules but not when the same assumption was assumed for all three types of particles. The integration of steric interactions can also explain the experimental deposition results. Particle size was demonstrated to have an effect on the predicted deposition for BPEI-stabilized particles but not for PVP.
Aims
The goal of this study was to measure the removal efficacy of Bacillus atrophaeus spores from a parking lot using spray‐based washing methods (a pressure washer and a garden hose) and wash aids. ...B. atrophaeus is a commonly used nonpathogenic surrogate for B. anthracis, the causative agent of anthrax and a deadly bioterrorism agent that would cause major disruptions and damage to public health should it be disseminated over an urban area.
Methods and Results
Five wash aids (1 mM sodium chloride, an Instant Ocean® seawater solution, 0.01% Tween 20, 0.01% sodium dodecyl sulfate, and unamended tap water) were used along with two different spray sequences in this study. Across all treatment conditions, 3.7–6.4 log10 colony forming unit were recovered in the runoff water, and 0.15%–23% of spores were removed from the surface of the parking lot.
Conclusions
Pressure washing removed more spores than the garden hose, and for both types of washing methods, the first pass removed more spores than the subsequent passes. The Instant Ocean and Tween 20 wash aids were found to significantly increase the percentage of spore removal when using the pressure washer, but the overall increase was only 1%–2% compared to the tap water alone.
Significance and Impact of Study
This study provides public officials and emergency responders with baseline spore physical removal information for situations where a corrosive disinfectant might have a negative impact on the environment and washing is being considered as an alternative remediation approach.
This research examined how variations in synthesis methods of silver nanoparticles affect both the release of silver from ceramic water filters (CWFs) and disinfection efficacy. The silver ...nanoparticles used were stabilized by four different molecules: citrate, polyvinylpyrrolidone, branched polyethylenimine, and casein. A multilevel statistical model was built to quantify if there was a significant difference in: a) extent of silver lost, b) initial amount of silver lost, c) silver lost for water of different quality, and d) total coliform removal. Experiments were performed on location at Pure Home Water, a CWF factory in Tamale, Ghana using stored rainwater and dugout water (a local surface water). The results indicated that using dugout vs. rainwater significantly affects the initial (p-value 0.0015) and sustained (p-value 0.0124) loss of silver, but that silver type does not have a significant effect. On average, dugout water removed 37.5μg/L more initial silver and had 1.1μg/L more silver in the filtrate than rainwater. Initially, filters achieved 1.9 log reduction values (LRVs) on average, but among different silver and water types this varied by as much as 2.5 LRV units. Overall, bacterial removal effectiveness was more challenging to evaluate, but some data suggest that the branched polyethylenimine silver nanoparticles provided improved initial bacterial removal over filters which were not painted with silver nanoparticles (p-value 0.038).
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•Multilevel modeling is useful for analysis of environmental data.•Ag NP stabilizer does not significantly affect total Ag release from CWFs.•Water type significantly affects the release of total Ag from CWFs.•BPEI silver nanoparticles may provide improved coliform removal.
This paper presents a Stormwater Emergency Response Framework (SERF) for use in the containment and treatment of stormwater runoff following a hazardous material release. The framework consists of ...four high level process steps and a decision tree. These resources are intended to assist stormwater managers in fulfilling their emergency response responsibilities within the United States' National Incident Management System. Robust hydraulic and watershed modeling may take weeks to months to develop for a contaminated site, whereas decisions made in the initial hours can have a significant impact on limiting contamination spread. Many web resources are publicly available to assist responders in visualizing stormwater runoff flow paths. A case study provided in this paper also demonstrates how simple calculations may be utilized to estimate peak flows and storage volumes necessary to respond to precipitation events immediately. These calculations are useful for decision makers’ allocation of containment and treatment resources within the impacted area. This includes where to deploy available resources to minimize contamination risks to downstream communities and where supplemental resources from outside partners are urgently needed.
•Process steps and decision tree for response to a hazardous material release.•Overview of web resources available to rapidly visualize runoff flow paths.•Framework application to a notional wide-area contamination case study.
After a biological terrorist attack, understanding the migration of agents such as Bacillus anthracis is critical due to their deadly nature. This is important in urban settings with higher ...likelihood of human exposure and a large fraction of impervious materials contributing to pollutant washoff. The study goals were to understand the removal of spores from urban surfaces under different rainfall conditions, to compare washoff of two B. anthracis surrogate spores, and to compare two empirical fits for the first flush of spores from small areas. Concrete and asphalt were inoculated with either Bacillus atrophaeus or Bacillus thuringiensis kurstaki spores and exposed to simulated rainfall. The study assessed goodness‐of‐fit for the Storm Water Management Model (SWMM)'s exponential washoff function compared to an alternative two‐stage exponential function. The highest average washoff of spores was 15% for an hour‐long experiment. Spore washoff was not significantly different for the two spore types, but there were significant differences in washoff from asphalt versus concrete with more occurring from asphalt. Average kinetic energy of the storm event impacted washoff from asphalt, but not concrete. The two‐stage function had a better goodness‐of‐fit than the SWMM exponential function. As such, emergency responders should be aware that the spread of contamination is impacted by the droplet characteristics of the storm event and the surface material type in the contaminated area; modelers should be aware that different data‐fitting approaches may be more appropriate for first‐flush calculations of small washoff areas than those used for continuous long‐term simulation of large subcatchments.
Key Points
Washoff of Bacillus atrophaeus and Bacillus thuringiensis kurstaki spores was not significantly different
Greater spore washoff occurred from asphalt than concrete coupons
Washoff results were fit to EPA's SWMM exponential washoff function and compared to an alternative two‐stage exponential removal function
This paper presents a case study demonstrating the process used to develop an overland flow model of radionuclide transport following an aerosol deposition from a hypothetical radiological dispersal ...device explosion. The process included the integration of digital elevation, building, and land cover information with hydrologic information from a calibrated Stormwater Management Model (SWMM) model. The overland flow model was used to explore the impact of washoff parameter selection and different storm events on radionuclide transport in surface flow. The range of washoff parameters used in the literature resulted in over a 7 times difference in radionuclide washoff, from a small surface removal to nearly full removal. The overland flow model illuminated the primary pathways of contaminant transport, a potentially useful tool that informs emergency response, planning, and remediation activities.
This study examined the washoff of Bacillus globigii (Bg) spores from concrete, asphalt, and grass surfaces by stormwater. Bg is a nonpathogenic surrogate for Bacillus anthracis, which is a ...biological select agent. Areas (2.74 m × 7.62 m) of concrete, grass, and asphalt were inoculated twice at the field site during the study. Spore concentrations were measured in runoff water after seven rainfall events (1.2–65.4 mm) and complimentary watershed data were collected for soil moisture, depth of water in collection troughs, and rainfall using custom-built telemetry units. An average surface loading of 107.79 Bg spores/m2 resulted in peak spore concentrations in runoff water of 102, 260, and 4.1 CFU/mL from asphalt, concrete, and grass surfaces, respectively. Spore concentrations in the stormwater runoff were greatly reduced by the third rain event after both inoculations, but still detectable in some samples. When initial rainfall events occurred longer after the initial inoculation, the spore concentrations (both peak and average) in the runoff were diminished. The study also compared rainfall data from 4 tipping bucket rain gauges and a laser disdrometer and found they performed similarly for values of total rainfall accumulation while the laser disdrometer provided additional information (total storm kinetic energy) useful in comparing the seven different rain events. The soil moisture probes are recommended for assistance in predicting when to sample sites with intermittent runoff. Sampling trough level readings were critical to understanding the dilution factor of the storm event and the age of the sample collected. Collectively the spore and watershed data are useful for emergency responders faced with remediation decisions after a biological agent incident as the results provide insight into what equipment to deploy and that spores may persist in runoff water at quantifiable levels for months. The spore measurements are also a novel dataset for stormwater model parameterization for biological contamination of urban watersheds.
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•Washoff of Bg was quantified in stormwater runoff from seven storm events.•Storm intensity and duration influenced Bg concentrations in runoff.•Rainfall, soil moisture, and sampling trough depth were useful complementary data.•Automated and remotely operated sample collection was successfully implemented.
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