Several lines of geological and geochemical evidence indicate that the level of atmospheric oxygen was extremely low before 2.45 billion years (Gyr) ago, and that it had reached considerable levels ...by 2.22 Gyr ago. Here we present evidence that the rise of atmospheric oxygen had occurred by 2.32 Gyr ago. We found that syngenetic pyrite is present in organic-rich shales of the 2.32-Gyr-old Rooihoogte and Timeball Hill formations, South Africa. The range of the isotopic composition of sulphur in this pyrite is large and shows no evidence of mass-independent fractionation, indicating that atmospheric oxygen was present at significant levels (that is, greater than 10(-5) times that of the present atmospheric level) during the deposition of these units. The presence of rounded pebbles of sideritic iron formation at the base of the Rooihoogte Formation and an extensive and thick ironstone layer consisting of haematitic pisolites and oölites in the upper Timeball Hill Formation indicate that atmospheric oxygen rose significantly, perhaps for the first time, during the deposition of the Rooihoogte and Timeball Hill formations. These units were deposited between what are probably the second and third of the three Palaeoproterozoic glacial events.
ABSTRACT
Radiative feedback can influence subsequent star formation. We quantify the heating from OB stars in the local star-forming regions in the James Clerk Maxwell Telescope (JCMT) Gould Belt ...Survey. Dust temperatures are calculated from 450/850 $\mu$m flux ratios from SCUBA-2 observations at the JCMT assuming a fixed dust opacity spectral index β = 1.8. Mean dust temperatures are calculated for each submillimetre clump along with projected distances from the main OB star in the region. Temperature versus distance is fitted with a simple model of dust heating by the OB star radiation plus the interstellar radiation field and dust cooling through optically thin radiation. Classifying the heating sources by spectral type, O-type stars produce the greatest clump average temperature rises and largest heating extent, with temperatures of over 40 K and significant heating out to at least 2.4 pc. Early-type B stars (B4 and above) produce temperatures of over 20 K and significant heating over 0.4 pc. Late-type B stars show a marginal heating effect within 0.2 pc. For a given projected distance, there is a significant scatter in clump temperatures that is due to local heating by other luminous stars in the region, projection effects, or shadowing effects. Even in these local, ‘low-mass’ star-forming regions, radiative feedback is having an effect on parsec scales, with 24 per cent of the clumps heated to at least 3 K above the 15 K base temperature expected from heating by only the interstellar radiation field, and a mean dust temperature for heated clumps of 24 K.
In this paper, we present the first observations of the Ophiuchus molecular cloud performed as part of the James Clerk Maxwell Telescope (JCMT) Gould Belt Survey (GBS) with the SCUBA-2 instrument. We ...demonstrate methods for combining these data with previous HARP CO, Herschel, and IRAM N2H+ observations in order to accurately quantify the properties of the SCUBA-2 sources in Ophiuchus. We produce a catalogue of all of the sources found by SCUBA-2. We separate these into protostars and starless cores. We list all of the starless cores and perform a full virial analysis, including external pressure. This is the first time that external pressure has been included in this level of detail. We find that the majority of our cores are either bound or virialized. Gravitational energy and external pressure are on average of a similar order of magnitude, but with some variation from region to region. We find that cores in the Oph A region are gravitationally bound prestellar cores, while cores in the Oph C and E regions are pressure-confined. We determine that N2H+ is a good tracer of the bound material of prestellar cores, although we find some evidence for N2H+ freeze-out at the very highest core densities. We find that non-thermal linewidths decrease substantially between the gas traced by C18O and that traced by N2H+, indicating the dissipation of turbulence at higher densities. We find that the critical Bonnor–Ebert stability criterion is not a good indicator of the boundedness of our cores. We detect the pre-brown dwarf candidate Oph B-11 and find a flux density and mass consistent with previous work. We discuss regional variations in the nature of the cores and find further support for our previous hypothesis of a global evolutionary gradient across the cloud from south-west to north-east, indicating sequential star formation across the region.
Step kinematic variability has been characterized during gait using spatial and temporal kinematic characteristics. However, people can adopt different trajectory paths both between individuals and ...even within individuals at different speeds. Single point measures such as minimum toe clearance (MTC) and step length (SL) do not necessarily account for the multiple paths that the foot may take during the swing phase to reach the same foot fall endpoint. The purpose of this study was to test a step-by-step foot trajectory area (SBS-FTA) variability measure that is able to characterize sagittal plane foot trajectories of varying areas, and compare this measure against MTC and SL variability at different speeds. We hypothesize that the SBS-FTA variability would demonstrate increased variability with speed. Second, we hypothesize that SBS-FTA would have a stronger curvilinear fit compared with the CV and SD of SL and MTC. Third, we hypothesize SBS-FTA would be more responsive to change in the foot trajectory at a given speed compared to SL and MTC. Fourth, SBS-FTA variability would not strongly co-vary with SL and MTC variability measures since it represents a different construct related to foot trajectory area variability.
We studied 15 nonimpaired individuals during walking at progressively faster speeds. We calculated SL, MTC, and SBS-FTA area.
SBS-FTA variability increased with speed, had a stronger curvilinear fit compared with the CV and SD of SL and MTC, was more responsive at a given speed, and did not strongly co-vary with SL and MTC variability measures.
SBS foot trajectory area variability was sensitive to change with faster speeds, captured a relationship that the majority of the other measures did not demonstrate, and did not co-vary strongly with other measures that are also components of the trajectory.
Biopsychosocial factors above and beyond pathoanatomical changes likely contribute to the severity of chronic low back pain. A pro-nociceptive endogenous pain modulatory balance (↓inhibition and ...↑facilitation) may be an important contributor to chronic low back pain severity and physical function; however, additional research is needed to address this possibility. The objective of this study was to determine whether quantitative sensory tests of endogenous pain inhibition and facilitation prospectively predict movement-evoked pain and cLBP severity self-reported on a validated questionnaire.
One hundred thirty-four individuals with chronic low back pain were enrolled in this two-session study. During the first study session, temporal summation of mechanical pain and conditioned pain modulation were assessed at the lumbar spine to determine endogenous pain facilitation and inhibition, respectively. One week later, participants returned for a second study session whereby they reported their pain severity and pain interference using the Brief Pain Inventory-Short Form. Movement-evoked pain and physical function capacity were assessed upon completion of the balance, walking, and transition from sit to stand tests of the Short Physical Performance Battery.
Temporal summation of mechanical pain, but not conditioned pain modulation, significantly and prospectively predicted greater movement-evoked pain and poorer physical function on the Short Physical Performance Battery. Neither temporal summation nor conditioned pain modulation were significantly related to self-reported pain severity or pain interference on the Brief Pain Inventory-Short Form.
Findings suggest that a pro-nociceptive pain modulatory balance characterized by enhanced pain facilitation may be an important driver of movement-evoked pain severity and poor physical function in individuals with chronic low back pain.
The petrogenesis and relationship of diamondite to well-studied monocrystalline and fibrous diamonds are poorly understood yet would potentially reveal new aspects of how diamond-forming fluids are ...transported through the lithosphere and equilibrate with surrounding silicates. Of twenty-two silicate- and oxide-bearing diamondites investigated, most yielded garnet intergrowths (n = 15) with major element geochemistry (i.e. Ca-Cr) classifying these samples as low-Ca websteritic or eclogitic. The garnet REE patterns fit an equilibrium model suggesting the diamond-forming fluid shares an affinity with high-density fluids (HDF) observed in fibrous diamonds, specifically on the join between the saline–carbonate end- members. The δ13C values for the diamonds range from -5.27 to -22.48 ‰ (V-PDB) with δ18O values for websteritic garnets ranging from +7.6 to +5.9 ‰ (V-SMOW). The combined C-O stable isotope data support a model for a hydrothermally altered and organic carbon-bearing subducted crustal source(s) for the diamond- and garnet-forming media. The nitrogen aggregation states of the diamonds require that diamondite-formation event(s) pre-dates fibrous diamond-formation and post-dates most of the gem monocrystalline diamond-formation events at Orapa. The modelled fluid compositions responsible for the precipitation of diamondites match the fluid-poor and fluid-rich (fibrous) monocrystalline diamonds, where all grow from HDFs within the saline-silicic-carbonatitic ternary system. However, while the nature of the parental fluid(s) share a common lithophile element geochemical affinity, the origin(s) of the saline, silicic, and/or carbonatitic components of these HDFs do not always share a common origin. Therefore, it is wholly conceivable that the diamondites are evidence of a distinct and temporally unconstrained tectono-thermal diamond-forming event beneath the Kaapvaal craton.
Considerable evidence suggests that there are significant ethnic/racial differences in the experience of pain among individuals suffering from chronic musculoskeletal conditions. Additionally, low ...levels of vitamin D have been associated with pain severity. Further, vitamin D deficiency is more prevalent in Non-Hispanic Black (NHB) individuals compared to Non-Hispanic Whites (NHW).
The aim of this study was to investigate the associations among race, pain severity, and serum levels of vitamin D in a sample of patients with chronic low back pain (cLBP).
All study participants (n = 155) self-identified their race/ethnicity as either NHB or NHW. Blood samples were collected to assess circulating levels of serum 25- hydroxy vitamin D. Vitamin D levels were categorized as optimal (≥20 ng/mL), insufficient (12-19 ng/mL) or deficient (<12 ng/mL). Participants then self-reported their pain severity using the Brief Pain Inventory - Short Form.
Results showed that a greater proportion of NHB versus NHW participants were categorized as Vitamin D deficient (
(2, N = 155) = 16.79, p < 0.001). An analysis of covariance (ANCOVA) revealed that NHBs reported significantly greater pain severity relative to NHWs (F(1150) = 6.45)
= 0.012. Further, self-reported pain severity significantly differed according to Vitamin D clinical categories (F(2150) = 4.19, p = 0.013). Participants with deficient vitamin D reported significantly greater pain severity in comparison to participants with optimal vitamin D (F(1101) = 7.28,
= 0.008).
The findings suggest that Vitamin D deficiency may be linked to greater pain severity in a sample of individuals with cLBP, especially for those who identify as NHB.
The R chondrite meteorite LaPaz Icefield (LAP) 04840 is unique among metamorphosed, non-carbonaceous chondrites in containing abundant OH-bearing silicate minerals: ∼13% ferri-magnesiohornblende and ...∼0.4% phlogopite by volume. Other minerals include olivine (Fo
62), orthopyroxene (En
69Fs
30Wo
1), albite (An
8Ab
90Or
2), magnetite, pyrrhotite, pentlandite, and apatite. Ferromagnesian minerals are rich in Fe
3+, as determined by Mössbauer spectrometry and electron microprobe chemical analyses. Fe
3+/Fe
tot values are olivine ⩽5%, amphibole 80%, phlogopite 65%, and magnetite 42%. Mineral compositions are nearly constant across grains and the section, except for a small variability in amphibole compositions reflecting the edenite exchange couple (
ANa
+
IVAl
↔
A□
+
Si). These mineral compositions, the absence of Fe–Ni metal, and the oxygen isotope data support its classification as an R (Rumuruti) chondrite. LAP 04840 is classified as petrologic grade 5, based on the chemical homogeneity of its minerals, and the presence of distinctly marked chondrules and chondrule fragments in a fine-grained crystalline matrix. The mineral assemblage of LAP 04840 allows calculation of physical and chemical conditions at the peak of its metamorphism:
T
=
670
±
60
°C from a amphibole–plagioclase thermometer;
P
H
2
O
between 250 and 500
bars as constrained by the assemblage phlogopite
+
orthopyroxene
+
olivine
+
feldspar and the absence of diopside;
P
CO
2
unconstrained;
f
O
2
at QFM
+
0.5
log units;
log
(
f
HF
/
f
H
2
O
)
≈
-
5.8
;
log
(
f
HCl
/
f
H
2
O
)
≈
-
3.3
;
and
log
(
f
HCl
/
f
HF
)
≈
-
2.6
. The hydrogen in LAP 04840 is very heavy, an average δD value of +3660
±
75‰ in the magnesiohornblende. Only a few known sources of hydrogen have such high δD and are suitable sources for LAP 04840: ordinary chondrite phyllosilicates (as in the Semarkona chondrite), and insoluble organic matter (IOM) in ordinary chondrites and CR chondrites. Hydrogen from the IOM could have been released by oxidation, and then reacted with an anhydrous R chondrite (at high temperature), but it is not clear whether this scenario is correct.
Oxygen Isotopes and the Moon-Forming Giant Impact Wiechert, U.; Halliday, A. N.; D.-C. Lee ...
Science (American Association for the Advancement of Science),
10/2001, Letnik:
294, Številka:
5541
Journal Article
Recenzirano
We have determined the abundances of16O,17O, and18O in 31 lunar samples from Apollo missions 11, 12, 15, 16, and 17 using a high-precision laser fluorination technique. All oxygen isotope ...compositions plot within ±0.016 per mil (2 standard deviations) on a single mass-dependent fractionation line that is identical to the terrestrial fractionation line within uncertainties. This observation is consistent with the Giant Impact model, provided that the proto-Earth and the smaller impactor planet (named Theia) formed from an identical mix of components. The similarity between the proto-Earth and Theia is consistent with formation at about the same heliocentric distance. The three oxygen isotopes (Δ17O) provide no evidence that isotopic heterogeneity on the Moon was created by lunar impacts.
Introduction: Previous research indicates ethnic/race group differences in pain and neurodegenerative diseases. Accounting for socioenvironmental factors reduces ethnic/race group differences in ...clinical and experimental pain. In the current study sample, we previously reported that in individuals with knee pain, ethnic/race group differences were observed in bilateral temporal lobe thickness, areas of the brain associated with risk for Alzheimer's disease, and related dementias. The purpose of the study was to determine if socioenvironmental factors reduce or account for previously observed ethnic/race group differences and explore if a combined effect of socioenvironmental risk and chronic pain severity on temporal lobe cortices is evident.
Methods: Consistent with the prior study, the sample was comprised of 147 adults (95 women, 52 men), 45–85 years of age, who self‐identified as non‐Hispanic Black (n = 72) and non‐Hispanic White (n = 75), with knee pain with/at risk for osteoarthritis. Measures included demographics, health history, pain questionnaires, cognitive screening, body mass index, individual‐ and community‐level socioenvironmental factors (education, income, household size, marital and insurance status, and area deprivation index), and brain imaging. We computed a summative socioenvironmental risk index. Results: Regression analyses showed that with the inclusion of socioenvironmental factors, the model was significant (p < .001), and sociodemographic (ethnic/race) group differences were not significant (p = .118). Additionally, findings revealed an additive stress load pattern indicating thinner temporal lobe cortices with greater socioenvironmental risk and chronic pain severity (p = .048).
Implications: Although individual socioenvironmental factors were not independent predictors, when collectively combined in models, ethnic/race group differences in bilateral temporal lobe structures were not replicated. Further, combined socioenvironmental risk factors and higher chronic pain severity were associated with thinner bilateral temporal lobes.
PDF
