The development of isotopic baselines for comparison with paleodietary data is crucial, but often overlooked. We review the factors affecting the carbon (δ(13)C) and nitrogen (δ(15)N) isotopic ...compositions of plants, with a special focus on the carbon and nitrogen isotopic compositions of twelve different species of cultivated plants (n = 91) and 139 wild plant species collected in northern Peru. The cultivated plants were collected from nineteen local markets. The mean δ(13)C value for maize (grain) was -11.8±0.4 ‰ (n = 27). Leguminous cultigens (beans, Andean lupin) were characterized by significantly lower δ(15)N values and significantly higher %N than non-leguminous cultigens. Wild plants from thirteen sites were collected in the Moche River Valley area between sea level and ∼4,000 meters above sea level (masl). These sites were associated with mean annual precipitation ranging from 0 to 710 mm. Plants growing at low altitude sites receiving low amounts of precipitation were characterized by higher δ(15)N values than plants growing at higher altitudes and receiving higher amounts of precipitation, although this trend dissipated when altitude was >2,000 masl and MAP was >400 mm. For C(3) plants, foliar δ(13)C was positively correlated with altitude and precipitation. This suggests that the influence of altitude may overshadow the influence of water availability on foliar δ(13)C values at this scale.
Development of renewable fuels from solar light appears as one of the main current challenges in energy science. A plethora of photocatalysts have been investigated to obtain hydrogen and oxygen from ...water and solar light in the last decades. However, the photon-to-hydrogen molecule conversion is still far from allowing real implementation of solar fuels. Here we show that 111 facet-oriented gold nanoplatelets on multilayer graphene films deposited on quartz is a highly active photocatalyst for simulated sunlight overall water splitting into hydrogen and oxygen in the absence of sacrificial electron donors, achieving hydrogen production rate of 1.2 molH2 per gcomposite per h. This photocatalytic activity arises from the gold preferential orientation and the strong gold-graphene interaction occurring in the composite system.
The mass–metallicity relation revisited with CALIFA Sánchez, S. F; Barrera-Ballesteros, J. K; Sánchez-Menguiano, L ...
Monthly notices of the Royal Astronomical Society,
08/2017, Letnik:
469, Številka:
2
Journal Article
Recenzirano
Odprti dostop
Abstract
We present an updated version of the mass–metallicity (MZ) relation using integral field spectroscopy data obtained from 734 galaxies observed by the CALIFA survey. These unparalleled ...spatially resolved spectroscopic data allow us to determine the metallicity at the same physical scale (Re) for different calibrators. We obtain MZ relations with similar shapes for all calibrators, once the scalefactors among them are taken into account. We do not find any significant secondary relation of the MZ relation with either the star formation rate (SFR) or the specific SFR for any of the calibrators used in this study, based on the analysis of the residuals of the best-fitted relation. However, we do see a hint for an (s)SFR-dependent deviation of the MZ relation at low masses (M < 109.5 M⊙), where our sample is not complete. We are thus unable to confirm the results by Mannucci et al. (2010), although we cannot exclude that this result is due to the differences in the analysed data sets. In contrast, our results are inconsistent with the results by Lara-López et al. (2010), and we can exclude the presence of an SFR–mass–oxygen abundance fundamental plane. These results agree with previous findings suggesting that either (1) the secondary relation with the SFR could be induced by an aperture effect in single fibre/aperture spectroscopic surveys, (2) it could be related to a local effect confined to the central regions of galaxies or (3) it is just restricted to the low-mass regime, or a combination of the three effects.
Silicon-substituted hydroxyapatite (SiHA) macroporous scaffolds have been prepared by robocasting. In order to optimize their bone regeneration properties, we have manufactured these scaffolds ...presenting different microstructures: nanocrystalline and crystalline. Moreover, their surfaces have been decorated with vascular endothelial growth factor (VEGF) to evaluate the potential coupling between vascularization and bone regeneration. In vitro cell culture tests evidence that nanocrystalline SiHA hinders pre-osteblast proliferation, whereas the presence of VEGF enhances the biological functions of both endothelial cells and pre-osteoblasts. The bone regeneration capability has been evaluated using an osteoporotic sheep model. In vivo observations strongly correlate with in vitro cell culture tests. Those scaffolds made of nanocrystalline SiHA were colonized by fibrous tissue, promoted inflammatory response and fostered osteoclast recruitment. These observations discard nanocystalline SiHA as a suitable material for bone regeneration purposes. On the contrary, those scaffolds made of crystalline SiHA and decorated with VEGF exhibited bone regeneration properties, with high ossification degree, thicker trabeculae and higher presence of osteoblasts and blood vessels. Considering these results, macroporous scaffolds made of SiHA and decorated with VEGF are suitable bone grafts for regeneration purposes, even in adverse pathological scenarios such as osteoporosis.
For the first time, the in vivo behavior of scaffolds made of silicon substituted hydroxyapatites (SiHA) has been evaluated under osteoporosis conditions. In order to optimize the bone regeneration properties of these bioceramics, 3D macroporous scaffolds have been manufactured by robocasting and implanted in osteoporotic sheep. Our experimental design shed light on the important issue of the biological response of nano-sized bioceramics vs highly crystalline bioceramics, as well as on the importance of coupling vascularization and bone growth processes by decorating SiHA scaffolds with vascular endothelial growth factor.
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Recently, cloud point extraction (CPE) has been an attractive subject as an alternative to liquid–liquid extraction. The technique is based on the property of most non-ionic surfactants in aqueous ...solutions to form micelles and become turbid when heated to the cloud point temperature. This review covers a selection of the literature published on applications of CPE in determination of metal ions over the period between 2004 and 2008.
We present the largest and most homogeneous catalog of H ii regions and associations compiled so far. The catalog comprises more than 7000 ionized regions, extracted from 306 galaxies observed by the ...CALIFA survey. We describe the procedures used to detect, select, and analyze the spectroscopic properties of these ionized regions. In the current study we focus on characterizing of the radial gradient of the oxygen abundance in the ionized gas, based on the study of the deprojecteddistribution of H ii regions. We found that all galaxies without clear evidence of an interaction present a common gradient in the oxygen abundance, with a characteristic slope of αO/H = −0.1 dex/re between 0.3 and 2 disk effective radii (re), and a scatter compatible with random fluctuations around this value, when the gradient is normalized to the disk effective radius. The slope is independent of morphology, the incidence of bars, absolute magnitude, or mass. Only those galaxies with evidence of interactions and/or clear merging systems present a significantly shallower gradient, consistent with previous results. The majority of the 94 galaxies with H ii regions detected beyond two disk effective radii present a flattening in the oxygen abundance. The flattening is statistically significant. We cannot provide a conclusive answer regarding the origin of this flattening. However, our results indicate that its origin is most probably related to the secular evolution of galaxies. Finally, we find a drop/truncation of the oxygen abundance in the inner regions for 26 of the galaxies. All of them are non-interacting, mostly unbarred Sb/Sbc galaxies. This feature is associated with a central star-forming ring, which suggests that both features are produced by radial gas flows induced by resonance processes. Our result suggests that galaxy disks grow inside-out, with metal enrichment driven by the local star formation history and with a small variation galaxy-by-galaxy. At a certain galactocentric distance, the oxygen abundance seems to be correlated well with the stellar mass density and total stellar mass of the galaxies, independently of other properties of the galaxies. Other processes, such as radial mixing and inflows/outflows seem to have a limited effect on shaping of the radial distribution of oxygen abundances, although they are not ruled out.
Abstract
Background
Pain may increase the risk for sarcopenia, but existing literature is only from high-income countries, while the mediators of this association are largely unknown. Thus, we aimed ...to investigate the association between pain and sarcopenia using nationally representative samples of older adults from 6 low- and middle-income countries (LMICs), and to identify potential mediators.
Methods
Cross-sectional data from the WHO Study on global AGEing and adult health (SAGE) were analyzed. Sarcopenia was defined as having low skeletal muscle mass and weak handgrip strength, while the presence and severity of pain in the last 30 days were self-reported. Multivariable logistic regression and mediation analyses were performed. The control variables included age, sex, education, wealth, and chronic conditions, while affect, sleep/energy, disability, social participation, sedentary behavior, and mobility were considered potential mediators.
Results
Data on 14,585 adults aged ≥65 years were analyzed (mean SD age 72.6 11.5 years; 55.0% females). Compared to no pain, mild, moderate, severe, and extreme pain were associated with 1.42 (95% confidence interval CI = 1.05–1.94), 1.43 (95%CI = 1.02–2.00), 1.92 (95%CI = 1.09–3.37), and 2.88 (95%CI = 1.10–7.54) times higher odds for sarcopenia, respectively. Disability (mediated percentage 18.0%), sedentary behavior (12.9%), and low mobility (56.1%) were significant mediators in the association between increasing levels of pain and sarcopenia.
Conclusions
Higher levels of pain were associated with higher odds for sarcopenia among adults aged ≥65 years in 6 LMICs. Disability, sedentary behavior, and mobility problems were identified as potential mediators. Targeting these factors in people with pain may decrease the future risk of sarcopenia onset, pending future longitudinal research.
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