We report the response of newly designed 4H-SiC Schottky barrier diode (SBD) detector prototype to alpha and gamma radiation. We studied detectors of three different active area sizes (1 × 1, 2 × 2 ...and 3 × 3 mm2), while all detectors had the same 4H-SiC epi-layer thickness of approximately µm, sufficient to stop alpha particles up to 6.8 MeV, which have been used in this study. The detector response to the various alpha emitters in the 3.27 MeV to 8.79 MeV energy range clearly demonstrates the excellent linear response to alpha emissions of the detectors with the increasing active area. The detector response in gamma radiation field of Co-60 and Cs-137 sources showed a linear response to air kerma and to different air kerma rates as well, up to 4.49 Gy/h. The detector response is not in saturation for the dose rates lower than 15.3 mGy/min and that its measuring range for gamma radiation with energies of 662 keV, 1.17 MeV and 1.33 MeV is from 0.5 mGy/h–917 mGy/h. No changes to electrical properties of pristine and tested 4H-SiC SBD detectors, supported by a negligible change in carbon vacancy defect density and no creation of other deep levels, demonstrates the radiation hardness of these 4H-SiC detectors.
In 2016, the “E-SiCure” project (standing for “Engineering Silicon Carbide for Border and Port Security”), funded by the NATO Science for Peace and Security Programme was launched. The main objective ...is to combine theoretical, experimental and applied research towards the development of radiation-hard SiC-based detectors of special nuclear materials (SNM), with the end goal to enhance border and port security barriers. Prototype neutron detectors, configured as 4H-SiC-based Schottky barrier diodes, were developed for the detection of secondary charged particles (tritons, alphas and lithium atoms) which are the result of thermal neutron reactions on
10
B and
6
LiF layers above the surface of the 4H-SiC diodes. We designed a stand-alone prototype detection system, consisting of a preamplifier, shaping amplifier and a multichannel analyser operated by a laptop computer, for testing of neutron detector prototypes at the Jožef Stefan Institute (JSI) TRIGA reactor using a broad beam of reactor neutrons. The reverse bias for the detector diode and the power to electronic system were provided by a standalone battery-powered voltage source. The detector functionality was established through measurements using an
241
Am alpha particle source. Two dedicated experimental campaigns were performed at the JSI TRIGA reactor. The registered pulse height spectra from the detectors, using both
10
B and
6
LiF neutron converting layers, clearly demonstrated the neutron detection abilities of the SiC detector prototypes. The computed neutron detection sensitivity of the single prototype detectors demonstrates that scaling SiC detectors into larger arrays, of dimensions relevant for border and port radiation detectors, could enable neutron sensitivity levels matching gas-based detector technology.
In 2016, the ”E-SiCure” project (standing for Engineering Silicon Carbide for Border and Port Security), funded by the NATO Science for Peace and Security Programme, was launched. The main objective ...is to combine theoretical, experimental and applied research towards the development of radiation-hard SiC-based detectors of special nuclear materials (SNM), and by that way, to enhance border and port security barriers. Along the plan, material modification processes are employed firstly to study, and secondly to manipulate the most severe electrically active defects (which trap or annihilate free charge carriers), by specific ion implantation and defect engineering. This paper gives an overview of the experimental activities performed at the JSI TRIGA reactor in the framework of the E-SiCure project. Initial activities were aimed at obtaining information on the radiation hardness of SiC and at the study of the energy levels of the defects induced by neutron irradiation. Several Schottky barrier diodes were fabricated out of nitrogen-doped epitaxial grown 4H-SiC, and irradiated under Cd filters in the PT irradiation channel in the JSI TRIGA reactor with varying neutron fluence levels. Neutron-induced defects in the material were studied using temperature dependent current-voltage (I-V), capacitance-voltage (C-V) and Deep-Level Transient Spectroscopy (DLTS) measurements. Our prototype neutron detectors are configured as 4H-SiC-based Schottky barrier diodes for detection of secondary charged particles (tritons, alphas and lithium atoms) which are result of thermal neutron conversion process in
10
B and
6
LiF layers above the surface of the 4H-SiC diodes. For field testing of neutron detectors using a broad beam of reactor neutrons we designed a standalone prototype detection system consisting of a preamplifier, shaping amplifier and a multichannel analyser operated by a laptop computer. The reverse bias for the detector diode and the power to electronic system are provided by a standalone battery-powered voltage source. The detector functionality was established through measurements using an
241
Am alpha particle source. Two dedicated experimental campaigns were performed at the JSI TRIGA reactor. The registered pulse height spectra from the detectors, using both
10
B and
6
LiF neutron converting layers, clearly demonstrated the neutron detection abilities of the SiC detector prototypes.
Silicon carbide diodes for neutron detection Coutinho, José; Torres, Vitor J.B.; Capan, Ivana ...
Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment,
01/2021, Letnik:
986
Journal Article
Recenzirano
Odprti dostop
In the last two decades we have assisted to a rush towards finding a 3He-replacing technology capable of detecting neutrons emitted from fissile isotopes. The demand stems from applications like ...nuclear war-head screening or preventing illicit traffic of radiological materials. Semiconductor detectors stand among the strongest contenders, particularly those based on materials possessing a wide band gap like silicon carbide (SiC). We review the workings of SiC-based neutron detectors, along with several issues related to material properties, device fabrication and testing. The paper summarizes the experimental and theoretical work carried out within the E-SiCure project (Engineering Silicon Carbide for Border and Port Security), co-funded by the NATO Science for Peace and Security Programme. The main goal was the development of technologies to support the fabrication of radiation-hard silicon carbide detectors of special nuclear materials. Among the achievements, we have the development of successful Schottky barrier based detectors and the identification of the main carrier life-time-limiting defects in the SiC active areas, either already present in pristine devices or introduced upon exposure to radiation fields. The physical processes involved in neutron detection are described. Material properties as well as issues related to epitaxial growth and device fabrication are addressed. The presence of defects in as-grown material, as well as those introduced by ionizing radiation are reported. We finally describe several experiments carried out at the Jozef Stefan Institute TRIGA Mark II reactor (Ljubljana, Slovenia), where a set of SiC-based neutron detectors were tested, some of which being equipped with a thermal neutron converter layer. We show that despite the existence of large room for improvement, Schottky barrier diodes based on state-of-the-art 4H-SiC are closing the gap between gas- and semiconductor-based detectors regarding their sensitivity.
In 2016, the NATO Science for Peace and Security Programme funded research project ”Engineering Silicon Carbide for Border and Port Security” — E-SiCure was launched, its objective being the ...development of radiation-hard silicon carbide (SiC) based detectors of special nuclear materials (SNM), with the aim to enhance border and port security barriers. Detector prototypes based on SiC Schottky Barrier Diodes (SBDs) and neutron converter films were developed. This paper presents the results of a dedicated experimental testing campaign performed at the Jožef Stefan Institute (JSI) TRIGA reactor in which several SiC detector prototypes equipped with 10B and 6LiF converter films were irradiated in the Dry Chamber of the reactor. The obtained results demonstrate a clearly measurable neutron response, which varies linearly with the neutron flux. The measured particle spectra from the SiC detectors exhibit a clear structure, attributable to the nature and energy of secondary particles originating as reaction products from nuclear reactions involving 10B and 6Li isotopes. The determined sensitivity of the detectors, their active volume being 1 mm × 1 mm × 25 μm, 1 mm × 1 mm × 69 μm and 1 mm × 1 mm × 170 μm, was of the order of 2 × 10−5 counts per second, per unit of neutron flux counts s−1 per n cm−2s−1 (for neutron energies between 0 and 5 eV). Scaling the detection sensitivity by a factor of 105, i.e. to an array with a surface of around 20 cm × 2 m, comparable to large BF3 or 3He detectors, would theoretically enable an overall sensitivity of around 2 counts s−1 per n cm−2s−1, which is already comparable to typical neutron sensitivity values of gas detectors, in the range from several to over 100 counts s−1 per n cm−2s−1. Due to its outstanding tolerance to harsh environments (including high temperatures and radiation fields) and superior electronic properties when compared to other semiconductors, SiC is a promising base material for the fabrication of solid-state detectors with stable and long life-time. Improvements in sensitivity combined with the capability of fabricating large modules (SiC arrays), could make SiC an important detection technology, applicable also in the context of border and port security barrier monitoring.
In the last two decades we have assisted to a rush towards finding a He3-replacing technology capable of detecting neutrons emitted from fissile isotopes. The demand stems from applications like ...nuclear war-head screening or preventing illicit traffic of radiological materials. Semiconductor detectors stand among the stronger contenders, particularly those based on materials possessing a wide band gap like silicon carbide. We review the workings of SiC-based neutron detectors, along with several issues related to material properties, device fabrication and testing. The paper summarizes the experimental and theoretical work carried out within the E-SiCure project, co-funded by the NATO SPS Programme. Among the achievements, we have the development of successful Schottky barrier based detectors and the identification of the main carrier life-time-limiting defects in the SiC active areas, either already present in pristine devices or introduced upon exposure to radiation fields. The physical processes involved in neutron detection are described. Material properties as well as issues related to epitaxial growth and device fabrication are addressed. The presence of defects in as-grown material, as well as those introduced by ionizing radiation are reported. We finally describe several experiments carried out at the Jozef Stefan Institute TRIGA Mark II reactor (Ljubljana, Slovenia), where a set of SiC-based neutron detectors were tested, some of which being equipped with a thermal neutron converter layer. We show that despite the existence of large room for improvement, Schottky barrier diodes based on state-of-the-art 4H-SiC are closing the gap regarding the sensitivity offered by gas-based and that of semiconductor detectors.
Since 1991 ANSTO's ion beam analysis (IBA) laboratory has been sampling fine
atmospheric particles every Wednesday and Sunday at urban and rural sites in
New South Wales. Multi-elemental ...accelerator-based IBA techniques were used
to characterise major components and significant trace elements with minimum
detectable limits close to 1 ng/m3. Observed mass concentrations
will be compared with air quality US EPA standards and proposed Australian fine
particle NEPM guidelines. Trace elements strongly associated with source
fingerprints responsible for high air pollution will also be discussed in this paper.
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