A sensor with a red‐emission signal is successfully obtained by the solvothermal reaction of Eu3+ and heterofunctional ligand bpydbH2 (4,4′‐(4,4′‐bipyridine‐2,6‐diyl) dibenzoic acid), followed by ...terminal‐ligand exchange in a single‐crystal‐to‐single‐crystal transformation. As a result of treatments both before and after the metal–organic framework formation, accessible Lewis‐base sites and coordinated water molecules are successfully anchored onto the host material, and they act as signal transmission media for the recognition of analytes at the molecular level. This is the first reported sensor based on a metal–organic framework (MOF) with multi‐responsive optical sensing properties. It is capable of sensing small organic molecules and inorganic ions, and unprecedentedly it can discriminate among the homologues and isomers of aliphatic alcohols as well as detect highly explosive 2,4,6‐trinitrophenol (TNP) in water or in the vapor phase. This work highlights the practical application of luminescent MOFs as sensors, and it paves the way toward other multi‐responsive sensors by demonstrating the incorporation of various functional groups into a single framework.
Multi‐responsive fluorescent sensing is achieved using a Eu metal–organic framework (EuMOF). Accessible Lewis‐base sites and coordinated water molecules are successfully anchored on the EuMOF‐based sensor for the recognition of different analytes at the molecular level. This strategy paves the way for the practical application of luminescent MOF sensors in pollutant‐detection.
A series of lanthanide metal‐organic frameworks (Ln‐MOFs) are synthesized through solvothermal conditions with 1,3‐bis(4‐carboxyphenyl)imidazolium (H2L). Owing to the lanthanide contraction effect, ...two different types of Ln‐MOFs, namely, {Ln(L)2(OH)·3H2O}n (Ln:Pr, Nd, Sm) and {Ln(L)2(COO)(H2O)2·H2O}n (Ln: Eu, Gd, Tb, Dy, Tm, Yb, Y), and their corresponding codoped Ln‐MOFs EuxTb1‐xL are obtained. With careful adjustment of the relative concentration of the lanthanide ions and the excitation wavelength, the color of the luminescence can be systematically modulated and white light emission can be further successfully achieved. Furthermore, by virtue of the temperature‐dependent luminescent behavior, Eu0.2Tb0.8L allows for the design of a thermometer with an excellent linear response to temperature over a wide range, from 40 to 300 K. This work highlights the practical applications of Ln‐MOFs for tailoring fluorescent color and even obtaining practical white light emission, and especially for sensing temperature as luminescent thermometers in a single framework by controlling in different ways.
Codoped Ln‐metal‐organic frameworks EuxTb1‐xL are synthesized based on the isostructural Ln‐metal‐organic frameworks using lanthanide ion emitters. With careful adjustment of the relative concentration of the lanthanide ions and the excitation wavelength, the emission trajectory can be modulated, allowing white emission. Furthermore, Eu0.2Tb0.8L allows for the design of a thermometer operating over a wide range, from 40 to 300 K.
Metal–organic frameworks (MOFs) with tunable compositions and morphologies are recognized as efficient self‐sacrificial templates to achieve function‐oriented nanostructured materials. Moreover, it ...is urgently needed to develop highly efficient noble metal‐free oxygen evolution reaction (OER) electrocatalysts to accelerate the development of overall water splitting green energy conversion systems. Herein, a facile and cost‐efficient strategy to synthesize Co9S8 nanoparticles‐embedded N/S‐codoped carbon nanofibers (Co9S8/NSCNFs) as highly active OER catalyst is developed. The hybrid precursor of core–shell ZIF‐wrapped CdS nanowires is first prepared and then leads to the formation of uniformly dispersed Co9S8/N, S‐codoped carbon nanocomposites through a one‐step calcination reaction. The optimal Co9S8/NSCNFs‐850 is demonstrated to possess excellent electrocatalytic performance for OER in 1.0 m KOH solution, affording a low overpotential of 302 mV to reach the current density of 10 mA cm−2, a small Tafel slope of 54 mV dec−1, and superior long‐term stability for 1000 cyclic voltammetry cycles. The favorable results raise a concept of exploring more MOF‐based nanohybrids as precursors to induce the synthesis of novel porous nanomaterials as non‐noble‐metal electrocatalysts for sustainable energy conversion.
Through a one‐step direct pyrolysis process, Co9S8 nanoparticles‐embedded N/S‐codoped carbon nanofibers derived from the hybrid precursor of core–shell ZIF‐wrapped CdS nanowires are successfully achieved which exhibit excellent oxygen evolution reaction catalytic performance. This presented strategy paves the way for exploring more metal–organic framework‐based nanohybrids as precursors to induce the synthesis of novel functional nanomaterials.
The effect of tetracycline (TC) on nitrogen removal in wastewater treatment plants has become a new problem. This study investigated the effects of TC on nitrogen removal using a Moving Bed Biofilm ...Reactor system. The results showed that there was no significant effect on nitrogen removal performance when the concentration of TC was 5 mg/L, and that the total nitrogen (TN) removal efficiency could reach 75-77%. However, when the concentration of TC increased to 10 mg/L, the denitrification performance was affected and the TN removal efficiency decreased to 58%. The abundance of denitrifying bacteria such as those in the genus Thauera decreased, and TC-resistant bacteria gradually became dominant. At a TC concentration of 10 mg/L, there were also increases and decreases, respectively, in the abundance of resistance and denitrification functional genes. The inhibitory effect of TC on denitrification was achieved mainly by the inhibition of nitrite-reducing bacteria.
Microplastic had been commonly used in personal care products (PCPs) until it was documented to be a pollutant. The relative contents of microplastics in PCPs decrease in the order of the USA, ...Europe, and Asia. The geometric means of the abundance and mass of microplastics found in PCPs were 2162 particles/g and 0.04 g/g, respectively. Diameters of PCP-derived microplastics are less than 350 μm. To quantify the exact contribution of PCPs to microplastic pollution, this review surveyed the existing scientific literature and statistically integrated the findings from 88 literatures. Overall, approximately 1500 tons/year of microplastics from PCPs escape from WWTPs and enter the global aquatic environment. According to the PCP consumption and microplastics levels, the mass emission of global PCP-derived microplastics reach up to 1.2 × 104 tons/year. The two figures account for ~0.1% and ~ 0.8% of the annual global release of primary microplastics in the world oceans (~1.5 × 106 tons/year). In the last 50 years (1970–2019), up to 3.00 × 105 tons of PCP-derived microplastics have accumulated in the environment. The main plastic in PCPs is polyethylene, which is known for being a remarkably resistant polymer to degradation. Even if microbeads are completely banned globally in 2020, microplastics that have been discharged into the environment will still persist for a long time and claim our highest attention. This review provided primary information to deal effectively with the problem of PCP-derived microplastic both now and in the future.
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•The density of microplastics in PCPs showed lognormal or gamma distribution.•Microplastic in PCPs is an appreciable part of plastic pollution.•About 1500 tons/year of microplastics from PCPs enter the global aquatic environment.•Global PCP-derived microplastics reach up to 1.2 × 104 tons/year.•Emission of PCP-derived microplastics in the last 50 years reached up to 3.0 × 105 tons.
Summary
The continuing nitrogen (N) deposition observed worldwide alters ecosystem nutrient cycling and ecosystem functioning. Litter decomposition is a key process contributing to these changes, but ...the numerous mechanisms for altered decomposition remain poorly identified.
We assessed these different mechanisms with a decomposition experiment using litter from four abundant species (Achnatherum sibiricum, Agropyron cristatum, Leymus chinensis and Stipa grandis) and litter mixtures representing treatment‐specific community composition in a semi‐arid grassland under long‐term simulation of six different rates of N deposition.
Decomposition increased consistently with increasing rates of N addition in all litter types. Higher soil manganese (Mn) availability, which apparently was a consequence of N addition‐induced lower soil pH, was the most important factor for faster decomposition. Soil C : N ratios were lower with N addition that subsequently led to markedly higher bacterial to fungal ratios, which also stimulated litter decomposition.
Several factors contributed jointly to higher rates of litter decomposition in response to N deposition. Shifts in plant species composition and litter quality played a minor role compared to N‐driven reductions in soil pH and C : N, which increased soil Mn availability and altered microbial community structure. The soil‐driven effect on decomposition reported here may have long‐lasting impacts on nutrient cycling, soil organic matter dynamics and ecosystem functioning.
Among the organs in which the environmental pollutant cadmium causes toxicity, the kidney has gained the most attention in recent years. Numerous studies have sought to unravel the exact pathways by ...which cadmium enters the renal epithelial cells and the mechanisms by which it causes toxicity in the kidney. The purpose of this review is to present the progress made on the mechanisms of cadmium transport in the kidney and the role of transporter proteins in cadmium-induced nephrotoxicity.
Intrinsic and acquired anti-HER2 resistance remains a major hurdle for treating HER2-positive breast cancer. Using genome-wide CRISPR/Cas9 screening in vitro and in vivo, we identify FGFR4 as an ...essential gene following anti-HER2 treatment. FGFR4 inhibition enhances susceptibility to anti-HER2 therapy in resistant breast cancer. Mechanistically, m6A-hypomethylation regulated FGFR4 phosphorylates GSK-3β and activates β-catenin/TCF4 signaling to drive anti-HER2 resistance. Notably, suppression of FGFR4 dramatically diminishes glutathione synthesis and Fe
efflux efficiency via the β-catenin/TCF4-SLC7A11/FPN1 axis, resulting in excessive ROS production and labile iron pool accumulation. Ferroptosis, a unique iron-dependent form of oxidative cell death, is triggered after FGFR4 inhibition. Experiments involving patient-derived xenografts and organoids reveals a synergistic effect of anti-FGFR4 with anti-HER2 therapy in breast cancer with either intrinsic or acquired resistance. Together, these results pinpoint a mechanism of anti-HER2 resistance and provide a strategy for overcoming resistance via FGFR4 inhibition in recalcitrant HER2-positive breast cancer.
Recently, the emergence of photoactive metal–organic frameworks (MOFs) has given great prospects for their applications as photocatalytic materials in visible‐light‐driven hydrogen evolution. Herein, ...a highly photoactive visible‐light‐driven material for H2 evolution was prepared by introducing methylthio terephthalate into a MOF lattice via solvent‐assisted ligand‐exchange method. Accordingly, a first methylthio‐functionalized porous MOF decorated with Pt co‐catalyst for efficient photocatalytic H2 evolution was achieved, which exhibited a high quantum yield (8.90 %) at 420 nm by use sacrificial triethanolamine. This hybrid material exhibited perfect H2 production rate as high as 3814.0 μmol g−1 h−1, which even is one order of magnitude higher than that of the state‐of‐the‐art Pt/MOF photocatalyst derived from aminoterephthalate.
The in visible MOF: A high performance for visible‐light‐driven H2‐evolution is obtained with a new methylthio‐functionalized metal–organic framework (MOF) photocatalyst that is rationally designed and facilely prepared. This approach opens up a new way to achieve photocatalysis based on MOF materials with high quantum efficiency value (up to 8.9 %) and excellent photoactivity.
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