Abstract At mid-ocean ridges, melts that formed during adiabatic melting of a heterogeneous mantle migrate upwards and ultimately crystallize the oceanic crust. The lower crustal gabbros represent ...the first crystallization products of these melts and the processes involved in the accretion of the lowermost crust drive the chemical evolution of the magmas forming two thirds of Earth’s surface. At fast-spreading ridges, elevated melt supply leads to the formation of a ⁓6-km-thick layered oceanic crust. Here, we provide a detailed petrochemical characterization of the lower portion of the fast-spread oceanic crust drilled during IODP Expedition 345 at the East Pacific Rise (IODP Holes U1415), together with the processes involved in crustal accretion. The recovered gabbroic rocks are primitive in composition and range from troctolites to olivine gabbros, olivine gabbronorites and gabbros. Although textural evidence of dissolution-precipitation processes is widespread within this gabbroic section, only the most interstitial phases record chemical compositions driven by melt-mush interaction processes during closure of the magmatic system. Comparing mineral compositions from this lower crustal section with its slow-spreading counterparts, we propose that the impact of reactive processes on the chemical evolution of the parental melts is dampened in the lower gabbros from magmatically productive spreading centres. Oceanic accretion thereby seems driven by fractional crystallization in the lower gabbroic layers, followed by upward reactive percolation of melts towards shallower sections. Using the composition of clinopyroxene from these primitive, nearly unmodified gabbros, we estimate the parental melt trace element compositions of Hess Deep, showing that the primary melts of the East Pacific Rise are more depleted in incompatible trace elements compared to those formed at slower spreading rates, as a result of higher melting degrees of the underlying mantle.
Abstract Our understanding of the processes at work in the lower crust/upper mantle transition zone during subduction initiation and early arc development has suffered from a general lack of in situ ...samples. Here, we present the results of petrographic and geochemical analysis of 34 samples (9 harzburgites, 13 dunites, 2 orthopyroxenites, 3 olivine-gabbros, and 7 wehrlites) collected from the inner trench wall of the Bonin Ridge, Izu–Bonin forearc. The sample suite records three main melt–rock reaction events involving melts with forearc basalt (FAB)-like, boninitic, and transitional compositions. The wehrlitic and gabbroic rocks trend towards more transitional to FAB compositions and the rest towards more boninitic compositions. The crosscutting occurrence of all three events in a single sample (wehrlite D31–106) establishes a relative timing of the events like that reported for the volcanic edifice of the Bonin Ridge, which transitioned from forearc basalt volcanism at subduction initiation (c.a., 51–52 Ma) to boninitic volcanism (c.a., 50–51 Ma) as the subduction system matured. We therefore suggest that the lower crust/upper mantle transition of the Bonin Ridge preserves a record of the transition from FAB melts created by decompression melting at subduction initiation to arc-type flux melting and boninitic volcanism thereafter. Orthopyroxenites and two anomalously fresh harzburgites from the sample suite are suggested to represent the later boninitic melts and possibly the result of hybridization between such melts and residual peridotites, respectively. Diffuse melt–rock reaction between the later boninites and/or subduction-related fluids and the earlier-formed FAB-related crust is recorded by enrichments in fluid mobile elements and depletions in first row transition metals in clinopyroxenes from a metasomatic vein in wehrlite sample D31–106. The chemistry of the wehrlitic and gabbroic clinopyroxenes suggests that they crystallized from hydrous, highly depleted melts which lack a slab fluid signature. We thus suggest that highly depleted melt fractions might be created early on during subduction initiation by the introduction of seawater into the proto-mantle wedge. The overall FAB-like nature of the crustal wehrlites and gabbros would suggest that most of the lower arc crust was created by forearc extension during/following subduction initiation and that later, mature arc volcanism may have contributed little or no material to the lower crust/upper mantle record in the outer forearc.
Mantle deformation processes leading to seafloor spreading are often difficult to infer due to the highly serpentinized and weathered state of most abyssal peridotites. We investigated the ...development of high-temperature crystal-plastic deformation and lower temperature mylonitization processes in relatively fresh (<50% modal serpentine) and ultra-fresh (<1% serpentine) mantle peridotites derived from the heterogeneous mantle in the sparsely magmatic zone of ultraslow-spreading Gakkel Ridge system by analyzing 12 peridotites from two dredge sites (<1 km apart). Microstructurally, these 12 peridotites consist of seven high-T deformed samples and five mylonites. Modally, the 12 samples include harzburgites, lherzolites, an olivine websterite, and a plagioclase-bearing lherzolite. Based on their mineral major and trace element compositions, the lherzolites, harzburgites, and olivine websterite are residual peridotites. The lherzolites containing clinopyroxenes with flat REE patterns likely underwent refertilization with a high influx of melt. The plagioclase-bearing lherzolites probably formed by subsolidus reaction after the partial melting process. Microstructural observations support that high-T crystal-plastic deformation (most likely at temperatures exceeding 1000 °C) was active in the peridotites of the high-T deformation group, accommodating mantle flow beneath the Gakkel Ridge. The identified melt refertilization process may have contributed to the formation of 010-fiber olivine fabrics in these peridotites. Mylonitic microstructures, decreasing fabric strength and grain-size reduction of olivine suggest that mylonitization occurred under relatively low-temperature mantle conditions (~800 °C) and probably accommodated strain localization. Water did not greatly affect the peridotites during the development of the shear zones, although amphibole with “dusty” zones developed in one mylonitic peridotite after mylonitization, indicating that late-stage metasomatism occurred locally within the shear zone. This low-T mylonitization is likely to have affected mantle peridotites of this region independently of petrogenetic processes. The development of these deformation processes in Gakkel Ridge suggests a shift from flow in the uppermost mantle to shear zone formation in the rift valley walls.
•Complex partial melting and refertilization developed in the heterogeneous mantle.•Peridotites later underwent mantle-flow to shear-zone plastic deformation.•Deformation in peridotites developed independent of petrogenetic processes.
The influence of oxygen fugacity and water on phase equilibria and the link between redox conditions and water activity were investigated experimentally using a primitive tholeiitic basalt ...composition relevant to the ocean crust. The crystallization experiments were performed in internally heated pressure vessels at 200 MPa in the temperature range 940–1,220°C. The oxygen fugacity was measured using the H
2
-membrane technique. To study the effect of oxygen fugacity, three sets of experiments with different hydrogen fugacities were performed, showing systematic effects on the phase relations and compositions. In each experimental series, the water content of the system was varied from nominally dry to water-saturated conditions, causing a range of oxygen fugacities varying by ~3 log units per series. The range in oxygen fugacity investigated spans ~7 log units. Systematic effects of oxygen fugacity on the stability and composition of the mafic silicate phases, Cr–spinel and Fe–Ti oxides, under varying water contents were recorded. The Mg# of the melt, and therefore also the Mg# of olivine and clinopyroxene, changed systematically as a function of oxygen fugacity. An example of the link between oxygen fugacity and water activity under hydrogen-buffered conditions is the change in the crystallization sequence (olivine and Cr–spinel) due to a change in the oxygen fugacity caused by an increase in the water activity. The stability of magnetite is restricted to highly oxidizing conditions. The absence of magnetite in most of the experiments allows the determination of differentiation trends as a function of oxygen fugacity and water content, demonstrating that in an oxide-free crystallization sequence, water systematically affects the differentiation trend, while oxygen fugacity seems to have a negligible effect.
To investigate the effect of water on phase relations and compositions in a basaltic system, we performed crystallization experiments at pressures of 100, 200 and 500 MPa in a temperature range of ...940 to 1,220 degrees C using four different water contents. Depending on the water activity, the oxygen fugacity varied between 1 and 4 log units above the quartz-magnetite-fayalite buffer. Addition of water to the dry system shifts the solidus > 250 degrees C to lower temperatures and increases the amount of melt drastically. For instance, at 1,100 degrees C and 200 MPa, the melt fraction increases from 12.5 wt% at a water content of 1.6 wt% to 96.3% at a water content of 5 wt% in the melt. The compositions of the experimental phases also show a strong effect of water. Plagioclase is shifted to higher anorthite contents by the addition of water. Olivine and clinopyroxene show generally higher MgO/FeO ratios with added water, which could also be related to the increasing oxygen fugacity with water. Moreover, water affects the partitioning of certain elements between minerals and melts, e.g., the Ca partitioning between olivine and melt. Plagioclase shows a characteristic change in the order of crystallization with water that may help to explain the formation of wehrlites intruding the lower oceanic crust (e.g., in Oman, Macquarie Island). At 100 MPa, plagioclase crystallizes before clinopyroxene at all water contents. At pressures > 100 MPa, plagioclase crystallizes before clinopyroxene at low water contents (e.g. < 3 wt%), but after clinopyroxene at H2O in the melt > 3 wt%. This change in crystallization order indicates that a paragenesis typical for wehrlites (olivine-clinopyroxene-without plagioclase) is stabilized at low pressures typical of the oceanic crust only at high water contents. This opens the possibility that typical wehrlites in the oceanic crust can be formed by the fractionation and accumulation of olivine and clinopyroxene at 1,060 degrees C and > 100 MPa in a primitive tholeiitic basaltic system containing more than 3 wt% water. The comparison of the experimental results with evolution trends calculated by the thermodynamic models "MELTS" and "Comagmat" shows that neither model predicts the experimental phase relations with sufficient accuracy. PUBLICATION ABSTRACT
The Godzilla Megamullion, located in the Parece Vela Backarc Basin of the Izu–Bonin–Mariana (IBM) system, is the largest known example of an Oceanic Core Complex (OCC). Peridotites recovered from the ...megamullion are divided petrographically into fertile (e.g. lherzolites), depleted (e.g. harzburgites), and plagioclase-bearing groups (Ohara et al., 2003a). A total of 151 thin sections were studied from the Kairei KR03-01, Hakuho Maru KH07-02, and Yokosuka YK09-05 cruises. Melt stagnation is studied via the incidence of plagioclase-bearing peridotites and the major element chemistry of Cr-spinels in the plag-bearing samples. A distinct trend in melt stagnation is evident along the length of the megamullion representing a secular evolution in the entrapment of melts rising through the lithosphere. The distal (furthest from the termination of spreading), depleted portion of the mullion represents a robust mantle section that was still producing abundant melt and can be compared to typical oceanic spreading with its relatively “normal” percentage of plagioclase peridotites and average spinel Cr# of 0.35. The medial, fertile portion of the mullion represents a steep falloff in melt productivity represented by fertile spinel compositions (i.e. Cr# <0.25) and the presence of plagioclase-free lherzolites. The proximal (closest to termination of spreading), heavily plagioclase impregnated portion (with spinel Cr#s covering nearly the entire range of abyssal peridotite spinel compositions) of the mullion then represents a period of increasing stagnation of melt into a lithosphere that was undergoing progressive thickening. We infer that the processes of mantle evolution through melt stagnation and impregnation, as evidenced by the systematic variations in plag–peridotites along Godzilla Megamullion, represent a possibly common way in which the mantle reacts to OCC formation. In this case, Godzilla Megamullion may represent an extreme endmember in OCC formation.
•The Godzilla Mullion (GM) is a backarc Oceanic Core Complex.•It is overabundant in plagioclase–peridotite, indicating large degrees of melt stagnation.•Plag–peridotites are concentrated toward the termination of the OCC.•Plag–peridotite at the termination suggests that it played a role in forming GM.
The Earth's mantle beneath ocean ridges is widely thought to be depleted by previous melt extraction, but well homogenized by convective stirring. This inference of homogeneity has been complicated ...by the occurrence of portions enriched in incompatible elements. Here we show that some refractory abyssal peridotites from the ultraslow-spreading Gakkel ridge (Arctic Ocean) have very depleted 187Os/188Os ratios with model ages up to 2 billion years, implying the long-term preservation of refractory domains in the asthenospheric mantle rather than their erasure by mantle convection. The refractory domains would not be sampled by mid-ocean-ridge basalts because they contribute little to the genesis of magmas. We thus suggest that the upwelling mantle beneath mid-ocean ridges is highly heterogeneous, which makes it difficult to constrain its composition by mid-ocean-ridge basalts alone. Furthermore, the existence of ancient domains in oceanic mantle suggests that using osmium model ages to constrain the evolution of continental lithosphere should be approached with caution.
Li isotopic compositions of magmatic rocks have gained considerable attention recently as probes of mantle-scale processes. However, the concentrations and isotopic composition of Li in mantle ...minerals from mid-ocean ridges remain relatively unconstrained. This is largely because of the general presence of seawater alteration in abyssal peridotites. Lithium elemental and isotopic compositions for mineral separates of coexisting olivine, clinopyroxene, orthopyroxene and bulk rocks of serpentine-free Gakkel Ridge peridotites were investigated. Bulk rocks have Li contents of 1.6 to 2.7ppm and δ7Li values of 3 to 5‰, which fall within the range of reported normal pristine “MORB mantle” values. Lithium concentrations vary in the order cpx (2.1–4.7ppm)>opx (0.9–1.7ppm)≥olivine (0.4–0.9ppm), the opposite found in “equilibrated” mantle peridotite xenoliths (Seitz and Woodland, 2000). The Li isotopic compositions indicate a systematic mineral variation with δ7Liolivine (7.14‰–15.09‰)>δ7Liopx (1.81‰–3.66‰)>δ7Licpx (−2.43‰−−0.39‰). The δ7Li values of cpx are negatively correlated with their Li concentrations with the lightest value for the most enriched cpx grains. There is a first order negative linear correlation between Δolivine–cpx (δ7Liolivine−δ7Licpx) and ol/cpxD (Liolivine/Licpx).
Numerical simulations indicate that the observed systematic inter-mineral variations of Li concentrations and isotopic compositions could be explained by a cooling driven diffusive redistribution between minerals in a closed system if there is a temperature dependent partitioning of Li between olivine and clinopyroxene. The studied Gakkel Ridge abyssal peridotites may alternatively have cooled under a variable cooling rate with a rapid cooling before the Li system was closed, which is less likely given the tectonic setting. Our calculations confirm that Li systematics in minerals, especially in coexisting mineral phases could potentially be used as a mantle geospeedometer, even for slowly cooled mantle rocks.
▶ Lithium elemental and isotopic compositions for Gakkel Ridge peridotites and their major component mineral phases. ▶ Numerical modelling of the effects of cooling driven diffusive Li isotope fractionation. ▶ Temperature dependent of Li partitioning and isotope fractionation between olivine and clinopyroxene. ▶ Lithium systems to be used as geospeedometer for slowly cooled mantle rocks.
Multiple generations of amphibole may form in the lower crust due to magmatism and metamorphism during the development of oceanic core complexes. We investigated the occurrence and chemical ...compositions of amphibole in gabbro mylonites from the medial area of the Godzilla Megamullion along the Parece Vela Rift in the Philippine Sea. The samples contain brown and green amphiboles with a variety of different textures that may have different origins. The brown amphibole occurs mainly as blebs in clinopyroxene porphyroclasts (Bleb amphibole), the rims around clinopyroxene porphyroclasts (Coronitic amphibole), and as porphyroclasts and fine-grained amphibole within the matrix (Matrix amphibole). The trace element and Cl contents of the bleb and green amphiboles indicate magmatic and metamoprhic origins, respectively. The bleb amphibole is interpreted to have crystallized from a hydrous silicate melt derived from an oxide gabbro-forming melt prior to retrograde metamorphism. In contrast, the compositions of the coronitic amphibole and matrix amphibole vary between those of typical magmatic and metamorphic amphiboles, suggesting that the amphibole-forming reactions were continuously retrogressive. Retrograde metamorphism is generally interpreted to have involved seawater-derived fluids, but the trace element contents of the coronitic and matrix amphiboles do not differ significantly from those of the original minerals (i.e., clinopyroxene and plagioclase). One sample of gabbro mylonite (KH07–02-D18–1) contains amphiboles with high concentrations of light rare earth elements, indicating a large influx of externally derived LREE-enriched fluids. These fluids are interpreted to have formed from an interaction between hydrous silicate melt with LREE-enriched composition and seawater-derived fluid. Our results suggest that multiple phases of melt–fluid infiltration occurred during the development of the detachment fault at the Godzilla Megamullion.
•Multiple melt–fluid infiltration events occurred along detachment shear zones within the medial area of the GM.•The gabbro mylonites from the medial area are interpreted to have been deformed in a melt-bearing environment.•Two features of the metamorphic reactions during shear deformation under hydrous condition can be identified.•Retrograde metamorphic reaction with a low water/rock ratio occurs within detachment shear zones.•Metamorphic reaction with LREE-enriched fluids may reflect a large influx of fluids or significant water–rock interaction.
Rocks in the Earth's uppermost sub-oceanic mantle, known as abyssal peridotites, have lost variable but generally large amounts of basaltic melt, which subsequently forms the oceanic crust. This ...process preferentially removes from the peridotite some major constituents such as aluminium, as well as trace elements that are incompatible in mantle minerals (that is, prefer to enter the basaltic melt), such as the rare-earth elements. A quantitative understanding of this important differentiation process has been hampered by the lack of correlation generally observed between major- and trace-element depletions in such peridotites. Here we show that the heavy rare-earth elements in abyssal clinopyroxenes that are moderately incompatible are highly correlated with the Cr/(Cr + Al) ratios of coexisting spinels. This correlation deteriorates only for the most highly incompatible elements-probably owing to late metasomatic processes. Using electron- and ion-microprobe data from residual abyssal peridotites collected on the central Indian ridge, along with previously published data, we develop a quantitative melting indicator for mantle residues. This procedure should prove useful for relating partial melting in peridotites to geodynamic variables such as spreading rate and mantle temperature.
