Despite the high theoretical capacity of lithium–sulfur batteries, their practical applications are severely hindered by a fast capacity decay, stemming from the dissolution and diffusion of lithium ...polysulfides in the electrolyte. A novel functional carbon composite (carbon‐nanotube‐interpenetrated mesoporous nitrogen‐doped carbon spheres, MNCS/CNT), which can strongly adsorb lithium polysulfides, is now reported to act as a sulfur host. The nitrogen functional groups of this composite enable the effective trapping of lithium polysulfides on electroactive sites within the cathode, leading to a much improved electrochemical performance (1200 mAh g−1 after 200 cycles). The enhancement in adsorption can be attributed to the chemical bonding of lithium ions by nitrogen functional groups in the MNCS/CNT framework. Furthermore, the micrometer‐sized spherical structure of the material yields a high areal capacity (ca. 6 mAh cm−2) with a high sulfur loading of approximately 5 mg cm−2, which is ideal for practical applications of the lithium–sulfur batteries.
A composite that consists of carbon‐nanotube‐interpenetrated mesoporous nitrogen‐doped carbon spheres (MNCS/CNT) can strongly chemisorb polysulfides and was used as a cathode material for lithium–sulfur batteries. Moreover, the highly conductive nitrogen‐doped carbon material enables direct and easy redox reactions of the adsorbed polysulfides, which leads to good electrode kinetics.
Mesostructured niobium (Nb)-doped TiO2-carbon (Nb-TiO2-C) composites are synthesized by a hydrothermal process for application as anode materials in Li-ion batteries. The composites have a ...hierarchical porous structure with the Nb-TiO2 nanoparticles homogenously distributed throughout the porous carbon matrix. The Nb content is controlled (0–10 wt%) to investigate its effect on the physico-chemical properties and electrochemical performance of the composite. While the crystalline/surface structure varied with the addition of Nb (d-spacing of TiO2: 0.34–0.36 nm), the morphology of the composite remained unaffected. The electrochemical performance (cycle stability and rate capability) of the Nb-TiO2-C composite anode with 1 wt% Nb doping improved significantly. First, a full cut-off potential (0–2.5 V vs. Li/Li+) of Nb-doped composite anode (1 wt%) provides a higher energy utilization than that of the un-doped TiO2-C anode. Second, Nb-TiO2-C composite anode (1 wt%) exhibits an excellent long-term cycle stability (100% capacity retention, 297 mAh/g at 0.5 C after 100 cycles and 221 mAh/g at 2 C after 500 cycles) and improved rate-capability (192 mAh/g at 5 C), respectively (1 C: 150 mA/g). The superior electrochemical performance of Nb-TiO2-C (1 wt%) could be attributed to the synergistic effect of improved electronic conductivity induced by optimal Nb doping (1 wt%) and lithium-ion penetration (high diffusion kinetics) through unique pore structures.
•Mesostructured porous nanocomposites of Nb-doped TiO2 and carbon are prepared.•The composites are prepared hydrothermally and used as anodes for Li-ion battery.•Highly conductive porous carbon and optimized Nb doping (1 wt%) act synergistically.•∼100% capacity retention (221 mAh/g) after 500 cycles is realized.•Good rate capability with a high capacity (192 mAh/g) at 5 C is achieved.
As an important material for many practical and research applications, porous silicon has attracted interest for decades. Conventional preparations suffer from high mass loss because of their etching ...nature. A few alternative routes have been reported, including magnesiothermic reduction; however, pre-formed porous precursors are still necessary, leading to complicated syntheses. Here we demonstrate a bottom-up synthesis of mesoporous crystalline silicon materials with high surface area and tunable primary particle/pore size via a self-templating pore formation process. The chemical synthesis utilizes salt by-products as internal self-forming templates that can be easily removed without any etchants. The advantages of these materials, such as their nanosized crystalline primary particles and high surface areas, enable increased photocatalytic hydrogen evolution rate and extended working life. These also make the mesoporous silicon a potential candidate for other applications, such as optoelectronics, drug delivery systems and even lithium-ion batteries.
Silicon has been intensively pursued as the most promising anode material for Li‐ion batteries due to its high theoretical capacity of 3579 mAh/g. Micro‐sized Si–C composites composed of nanoscale ...primary building blocks are attractive Si‐based anodes for practical application because they not only achieve excellent cycling stability, but also offer both gravimetric and volumetric capacity. However, the effects of key parameters in designing such materials on their electrochemical performance are unknown and how to optimize them thus remains to be explored. Herein, the influence of Si nanoscale building block size and carbon coating on the electrochemical performance of the micro‐sized Si–C composites is investigated. It is found that the critical Si building block size is 15 nm, which enables a high capacity without compromising the cycling stability, and that carbon coating at higher temperature improves the first cycle coulombic efficiency (CE) and the rate capability. Corresponding reasons underlying electrochemical performance are revealed by various characterizations. Combining both optimized Si building block size and carbon coating temperature, the resultant composite can sustain 600 cycles at 1.2 A/g with a fixed lithiation capacity of 1200 mAh/g, the best cycling performance with such a high capacity for micro‐sized Si‐based anodes.
The Si building block size and carbon coating significantly influnce the electrochemical performance of micro‐sized Si–C composite Li‐ion anodes. The critical Si building block size is found to be 15 nm, which strikes a delicate balance between cycling stability and reversible capacity. Carbon coating at higher temperature helps to improve the first cycle coulombic efficiency and the rate capability by reducing more SiOx (0 < x < 2) and forming higher quality carbon.
Lithium–sulfur (Li–S) batteries offer theoretical energy density much higher than that of lithium-ion batteries, but their development faces significant challenges. Mesoporous carbon–sulfur composite ...microspheres are successfully synthesized by combining emulsion polymerization and the evaporation-induced self-assembly (EISA) process. Such materials not only exhibit high sulfur-specific capacity and excellent retention as Li–S cathodes but also afford much improved tap density, sulfur content, and areal capacity necessary for practical development of high-energy-density Li–S batteries. In addition, when incorporated with carbon nanotubes (CNTs) to form mesoporous carbon–CNT–sulfur composite microspheres, the material demonstrated superb battery performance even at a high current density of 2.8 mA/cm2, with a reversible capacity over 700 mAh/g after 200 cycles.
Abstract
Glycerol is a low-cost byproduct of the biodiesel manufacturing process, which can be used to synthesize various value-added chemicals. Among them, 1,2-propanediol (1,2-PDO) is of great ...interest because it can be used as an intermediate and additive in many applications. This work investigated the hydrogenolysis of glycerol to 1,2-PDO over Co–Cu bimetallic catalysts supported on TiO
2
(denoted as CoCu/TiO
2
) in aqueous media. The catalysts were prepared using the co-impregnation method and their physicochemical properties were characterized using several techniques. The addition of appropriate Cu increased the glycerol conversion and the 1,2-PDO yield. The highest 1,2-PDO yield was achieved over a 15Co0.5Cu/TiO
2
catalyst at 69.5% (glycerol conversion of 95.2% and 1,2-PDO selectivity of 73.0%). In the study on the effects of operating conditions, increasing the reaction temperature, initial pressure, and reaction time increased the glycerol conversion but decreased the selectivity to 1,2-PDO due to the degradation of formed 1,2-PDO to lower alcohols (1-propanol and 2-propanol). The reaction conditions to obtain the maximum 1,2-PDO yield were a catalyst-to-glycerol ratio of 0.028, a reaction temperature of 250 °C, an initial H
2
pressure of 4 MPa, and a reaction time of 4 h.
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•Avian influenza virus biosensor composed of DNA 3 W J on hollow Au spike-like nanoparticle was developed.•The multi-functional DNA was rolled to recognition, signal enhancement and ...immobilization.•Hollow Au nanospike was prepared to LSPR measurement.•This study showed the label-free LSPR detection elements for avian influenza virus detection.
In the present study, we fabricated a label-free avian influenza (AIV H5N1) detection biosensor composed of a multi-functional DNA 3 way-Junction (3 W J) on a hollow Au spike-like nanoparticle (hAuSN) using a localized surface plasmon resonance (LSPR) method. To construct the multi-functional DNA (MF-DNA) as a bioprobe, the 3 W J was introduced. The proposed AIV detection bioprobe should contain three functionalities: target recognition, signal amplification, and connection to substrate. To achieve this goal, each piece of the DNA 3 W J was tailored to a hemagglutinin (HA) binding aptamer, FAM dye and thiol group, respectively. The assembly of each DNA 3 W J functional fragment was then confirmed by TBM-Native PAGE. Moreover, the hAuSN was immobilized on the indium-tin-oxide (ITO) substrate for LSPR measurement. The DNA 3 W J was immobilized onto the hAuSN electrode through the thiol-group of DNA 3 W J. The fabricated DNA 3 W J/hAuSN heterolayer on the ITO substrate was investigated by field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). LSPR experiments were conducted to confirm HA protein binding to the DNA 3 W J/ hAuSN -modified electrode. The proposed biosensor can detected the HA protein in PBS buffer (LOD: 1 pM) as well as in the diluted chicken serum (LOD: 1 pM). The present study details a label-free, simple fabrication method consisted of DNA 3 W J/ hAuSN heterolayer that uses easy-to-tailor elements to detect not only AIV but also various viruses detection platform easily.
Zika virus (ZV) infection causes fatal hemorrhagic fever. Most patients are unaware of their symptoms; therefore, a rapid diagnostic tool is required to detect ZV infection. To solve this problem, we ...developed a rapid electrical biosensor composed of a truncated DNA aptamer immobilized on an interdigitated gold micro-gap electrode and alternating current electrothermal flow (ACEF) technique. The truncated ZV aptamer (T-ZV apt) was prepared to reduce the manufacturing cost for biosensor fabrication, and it showed binding affinity similar to that of the original ZV aptamer. This pulse-voltammetry-based biosensor was composed of a T-ZV apt immobilized on an interdigitated micro-gap electrode. Atomic force microscopy was used to confirm the biosensor fabrication. In addition, the optimal biosensor performance conditions were investigated using pulse voltammetry. ACEF promoted aptamer-target binding, and the target virus envelope protein was detected in the diluted serum within 10 min. The biosensor waveform increased linearly as the concentration of the Zika envelope in the serum increased, and the detection limit was 90.1 pM. Our results suggest that the fabricated biosensor is a significant milestone for rapid virus detection.
Hierarchically porous graphite particles are synthesized using a continuous, scalable aerosol approach. The unique porous graphite architecture provides the particles with high surface area, fast ion ...transportation, and good electronic conductivity, which endows the resulting supercapacitors with high energy and power densities. This work provides a new material platform for high‐performance supercapacitors with high packing density, and is adaptable to battery electrodes, fuel‐cell catalyst supports, and other applications.
With increasing technological demand for portable electronic and photovoltaic devices, it has become critical to ensure the electrical and mechano-electric reliability of electrodes in such devices. ...However, the limited flexibility and high processing costs of traditional electrodes based on indium tin oxide undermine their application in flexible devices. Among various alternative materials for flexible electrodes, such as metallic/carbon nanowires or meshes, silver nanowire (Ag NW) networks are regarded as promising candidates owing to their excellent electrical, optical, and mechano-electric properties. In this context, there have been tremendous studies on the physico-chemical and mechano-electric properties of Ag NW networks. At the same time, it has been a crucial job to maximize the device performance (or their mechano-electric performance) by reconciliation of various properties. This review discusses the properties and device applications of Ag NW networks under dynamic motion by focusing on notable findings and cases in the recent literature. Initially, we introduce the fabrication (deposition process) of Ag NW network-based electrodes from solution-based coating processes (drop casting, spray coating, spin coating, etc.) to commercial processes (slot-die and roll-to-roll coating). We also discuss the electrical/optical properties of Ag NW networks, which are governed by percolation, and their electrical contacts. Second, the mechano-electric properties of Ag NW networks are reviewed by describing individual and combined properties of NW networks with dynamic motion under cyclic loading. The improved mechano-electric properties of Ag NW network-based flexible electrodes are also discussed by presenting various approaches, including post-treatment and hybridization. Third, various Ag NW-based flexible devices (electronic and optoelectronic devices) are introduced by discussing their operation principles, performance, and challenges. Finally, we offer remarks on the challenges facing the current studies and discuss the direction of research in this field, as well as forthcoming issues to be overcome to achieve integration into commercial devices.