Problems involving discrete Markov Chains are solved mathematically using matrix methods. Recently, several research groups have demonstrated that matrix-vector multiplication can be performed ...analytically in a single time step with an electronic circuit that incorporates an open-loop memristor crossbar that is effectively a resistive random-access memory. Ielmini and co-workers have taken this a step further by demonstrating that linear algebraic systems can also be solved in a single time step using similar hardware with feedback. These two approaches can both be applied to Markov chains, in the first case using matrix-vector multiplication to compute successive updates to a discrete Markov process and in the second directly calculating the stationary distribution by solving a constrained eigenvector problem. We present circuit models for open-loop and feedback configurations, and perform detailed analyses that include memristor programming errors, thermal noise sources and element nonidealities in realistic circuit simulations to determine both the precision and accuracy of the analog solutions. We provide mathematical tools to formally describe the trade-offs in the circuit model between power consumption and the magnitude of errors. We compare the two approaches by analyzing Markov chains that lead to two different types of matrices, essentially random and ill-conditioned, and observe that ill-conditioned matrices suffer from significantly larger errors. We compare our analog results to those from digital computations and find a significant power efficiency advantage for the crossbar approach for similar precision results.
High-Speed and Low-Energy Nitride Memristors Choi, Byung Joon; Torrezan, Antonio C.; Strachan, John Paul ...
Advanced functional materials,
August 2, 2016, Letnik:
26, Številka:
29
Journal Article
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High‐performance memristors based on AlN films have been demonstrated, which exhibit ultrafast ON/OFF switching times (≈85 ps for microdevices with waveguide) and relatively low switching current ...(≈15 μA for 50 nm devices). Physical characterizations are carried out to understand the device switching mechanism, and rationalize speed and energy performance. The formation of an Al‐rich conduction channel through the AlN layer is revealed. The motion of positively charged nitrogen vacancies is likely responsible for the observed switching.
Ultrafast switching of an AlN memristor: ON switching is acheived using an 85 ps positive voltage pulse, and OFF switching using an 85 ps negative voltage pulse on the Al electrode of a Pt/AlN/Al memristor stack. A relatively low switching current (≈15 μA for 50 nm devices) has also been demonstrated in these memristors based on AlN films. The formation of an Al‐rich conduction channel through the AlN layer is revealed.
The popular dual electronic and structural transitions in VO2 are explored using X‐ray absorption spectromicroscopy with high spatial and spectral resolutions. It is found that during both heating ...and cooling, the electronic transition always precedes the structural Peierls transition. Between the two transitions, there are intermediate states that are spectrally isolated here.
A key requirement for using memristors in circuits is a predictive model for device behavior that can be used in simulations and to guide designs. We analyze one of the most promising materials, ...tantalum oxide, for high density, low power, and high-speed memory. We perform an ensemble of measurements, including time dynamics across nine decades, to deduce the underlying state equations describing the switching in Pt/TaO x /Ta memristors. A predictive, compact model is found in good agreement with the measured data. The resulting model, compatible with SPICE, is then used to understand trends in terms of switching times and energy consumption, which in turn are important for choosing device operating points and handling interactions with other circuit elements.
We illustrate novel optimization techniques via simulations for Hopfield networks constructed from manufacturable three-terminal Silicon-Oxide-Nitride-Oxide-Silicon (SONOS) synaptic circuit elements. ...We first present a computationally-light, memristor-based, highly accurate static compact model for the SONOS synapses used in our simulations. We then show how to exploit analog errors in programming resistances and current leakage, and the continuous tunability of the SONOS synapses to enable transient chaotic group dynamics, to accelerate the convergence of a Hopfield network. We project improvements in energy consumption and time to solution relative to existing CPUs and GPUs by at least 4 orders of magnitude, and also exceed the projected performance of two-terminal memristor-based crossbars in addition to a 100-fold increase in error-resilient array size (i.e. problem size).
Memristor crossbars were fabricated at 40 nm half-pitch, using nanoimprint lithography on the same substrate with Si metaloxide-semiconductor field effect transistor (MOS FET) arrays to form fully ...integrated hybrid memory resistor (memristor)/transistor circuits. The digitally configured memristor crossbars were used to perform logic functions, to serve as a routing fabric for interconnecting the FETs and as the target for storing information. As an illustrative demonstration, the compound Boolean logic operation (C AND D) OR (C AND D) was performed with kilohertz frequency inputs, using resistor-based logic in a memristor crossbar with FET inverter/amplifier outputs. By routing the output signal of a logic operation back onto a target memristor inside the array, the crossbar was conditionally configured by setting the state of a nonvolatile switch. Such conditional programming illuminates the way for a variety of self-programmed logic arrays, and for electronic synaptic computing.
Hybrid reconfigurable logic circuits were fabricated by integrating memristor-based crossbars onto a foundry-built CMOS (complementary metal−oxide−semiconductor) platform using nanoimprint ...lithography, as well as materials and processes that were compatible with the CMOS. Titanium dioxide thin-film memristors served as the configuration bits and switches in a data routing network and were connected to gate-level CMOS components that acted as logic elements, in a manner similar to a field programmable gate array. We analyzed the chips using a purpose-built testing system, and demonstrated the ability to configure individual devices, use them to wire up various logic gates and a flip-flop, and then reconfigure devices.
Here we demonstrate a molecular trap structure that can be formed to capture analyte molecules in solution for detection and identification. The structure is based on gold-coated nanoscale polymer ...fingers made by nanoimprinting technique. The nanofingers are flexible and their tips can be brought together to trap molecules, while at the same time the gold-coated fingertips form a reliable Raman hot spot for molecule detection and identification based on surface enhanced Raman spectroscopy (SERS). The molecule self-limiting gap size control between fingertips ensures ultimate SERS enhancement for sensitive molecule detection. Furthermore, these type of structures, resulting from top-down meeting self-assembly, can be generalized for other applications, such as plasmonics, meta-materials, and other nanophotonic systems.
Multiparticle assemblies of nanoscale structures are the fundamental building blocks for powerful plasmonic devices. Here we show the controlled formation of polygonal metal nanostructure assemblies, ...including digon, trigon, tetragon, pentagon, and hexagon arrays, which were formed on top of predefined flexible polymer pillars that undergo self-coalescence, analogous to finger closing, with the aid of microcapillary forces. This hybrid approach of combining top-down fabrication with self-assembly enables the formation of complex nanoplasmonic structures with sub-nanometer gaps between gold nanoparticles. On comparison of the polygon-shaped assemblies, the symmetry dependence of the nanoplasmonic structures was determined for application to surface enhanced Raman spectroscopy (SERS), with the pentagonal assembly having the largest Raman enhancement for the tested molecules. Electromagnetic simulations of the polygonal structures were performed to visualize the field enhancements of the hot spots so as to guide the rational design of optimal SERS structures.
Abstract While digital computers rely on software-generated pseudo-random number generators, hardware-based true random number generators (TRNGs), which employ the natural physics of the underlying ...hardware, provide true stochasticity, and power and area efficiency. Research into TRNGs has extensively relied on the unpredictability in phase transitions, but such phase transitions are difficult to control given their often abrupt and narrow parameter ranges (e.g., occurring in a small temperature window). Here we demonstrate a TRNG based on self-oscillations in LaCoO 3 that is electrically biased within its spin crossover regime. The LaCoO 3 TRNG passes all standard tests of true stochasticity and uses only half the number of components compared to prior TRNGs. Assisted by phase field modeling, we show how spin crossovers are fundamentally better in producing true stochasticity compared to traditional phase transitions. As a validation, by probabilistically solving the NP-hard max-cut problem in a memristor crossbar array using our TRNG as a source of the required stochasticity, we demonstrate solution quality exceeding that using software-generated randomness.