California's climate is characterized by the largest precipitation and streamflow variability observed within the conterminous US This, combined with chronic groundwater overdraft of 0.6-3.5 km3 ...yr−1, creates the need to identify additional surface water sources available for groundwater recharge using methods such as agricultural groundwater banking, aquifer storage and recovery, and spreading basins. High-magnitude streamflow, i.e. flow above the 90th percentile, that exceeds environmental flow requirements and current surface water allocations under California water rights, could be a viable source of surface water for groundwater banking. Here, we present a comprehensive analysis of the magnitude, frequency, duration and timing of high-magnitude streamflow (HMF) for 93 stream gauges covering the Sacramento, San Joaquin and Tulare basins in California. The results show that in an average year with HMF approximately 3.2 km3 of high-magnitude flow is exported from the entire Central Valley to the Sacramento-San Joaquin Delta often at times when environmental flow requirements of the Delta and major rivers are exceeded. High-magnitude flow occurs, on average, during 7 and 4.7 out of 10 years in the Sacramento River and the San Joaquin-Tulare Basins, respectively, from just a few storm events (5-7 1-day peak events) lasting for 25-30 days between November and April. The results suggest that there is sufficient unmanaged surface water physically available to mitigate long-term groundwater overdraft in the Central Valley.
Assessing groundwater resources in the arid and semiarid borderlands of the United States and Mexico represents a challenge for land and water managers, particularly in the Transboundary Santa Cruz ...Aquifer (TSCA). Population growth, residential construction, and industrial activities have increased groundwater demand in the TSCA, in addition to wastewater treatment and sanitation demands. These activities, coupled with climate variability, influence the hydrology of the TSCA and emphasize the need for groundwater assessment tools for decision‐making purposes. This study assesses the impacts of changes in groundwater demand, effluent discharge, and climate uncertainties within the TSCA from downstream of the Nogales International Wastewater Treatment Plant to the northern boundary of the Santa Cruz Active Management Area. We use a conceptual water budget model to analyze the long‐term impact of the different components of potential recharge and water losses within the aquifer. Modeling results project a future that ranges from severe long‐term drying to positive wetting. This research improves the understanding of the impact of natural and anthropogenic variables on water sustainability, with an accessible methodology that can be globally applied.
Research Impact Statement: Conceptual water budget models are useful to guide and improve decision‐making processes in transboundary settings.
Population growth and unpredictable climate changes will pose high demands on water resources in the future. Even at present, surface water is certainly not enough to cope with the water requirement ...for agricultural, industrial, recreational and drinking purposes. In this context, the usage of ground water has become essential, therefore, their quality and quantity has to be carefully managed. Regarding quantity, artificial recharge can guarantee a sustainable level of ground water, whilst the strict quality control of the waters intended for recharge will minimize contamination of both the ground water and aquifer area. However, all water resources in the planet are threatened by multiple sources of contamination coming from the extended use of chemicals worldwide. In this respect, the environmental occurrence of organic micropollutants such as pesticides, pharmaceuticals, industrial chemicals and their metabolites has experienced fast growing interest.
In this paper an overview of the priority and emerging organic micropollutants in the different source waters used for artificial aquifer recharge purposes and in the recovered water is presented. Besides, some considerations regarding fate and removal of such compounds are also addressed.
Water is an essential entity of life, and its major sources are surface and groundwater. However, surface water is excluded long ago for drinking purposes due to high contamination through different ...human activities such as the common release of domestic and industrial wastewater into nearby running water sources. No doubt industries are the economic backbone of any country; however, due to the lack of proper waste disposal policies in under-developing and developing countries, their common activity is disposing of wastewater into nearby surface water sources. This is causing great harm to not only the surface water but also the groundwater resources since the major source of groundwater recharge is through these surface waters. Rawat Industrial State is the second-largest industrial zone in Pakistan. Due to poor waste disposal policies, their wastewater is released into nearby streams. To check the linkage of surface water as a recharging source of groundwater, we applied an electrical resistivity survey including 12 profiles throughout the waste release zone and collected 18 water samples to find the maximum affective depth of these contaminants. Our results have confirmed that all the major aquifers in the study area are receiving their recharge through these contaminated streams, and it is polluting the groundwater up to the sampled depth of 350 ft.
Low-to-medium temperature geothermal fluids in the granite regions of southeastern China are an important renewable energy resource, but they are also a source of contamination containing highly ...toxic elements such as fluoride and arsenic. This study analyzed the origin of the geothermal fluids in a regional-scale hydrogeological unit in the city of Xiamen, China, based on isotope and hydrochemical analyses. The Br/Cl ratios suggested that the inland geothermal fluid is merely recharged by rainwater from the mountain edge, while the coastal geothermal fluid is originally recharged by the seawater and later mixed with rain-derived groundwater. The geothermal water featured high SiO
2
and detectable Zn concentrations. The former reflects the significant water–granite interaction along the flow path, and the latter indicates the active hydraulic connection between surface waters, shallow aquifers and deep geothermal fluids. High radon content was detected near the deep conductive fault adjacent to a geothermal well, demonstrating that the fault damage zone acts as a major conduit for upward transport of the deep geothermal fluid. As a result, the fault damage zones developed in the granite are necessary for the formation of geothermal water, which leads to the uneven distribution of geothermal water in the subsurface. High-temperature geothermal water can be found in those regions with fairly sparse fault damage zones. In contrast, in the region with high-density fault activities, the active communication between shallow cool water and deep geothermal fluids can decrease the water temperature.
Irrigation water quality is important to sustain agricultural productivity. The primary irrigation water sources in Al-Ahsa Oasis, KSA, are groundwater wells, mixed with treated wastewater and ...agricultural drainage. This study sought to evaluate irrigation water quality in Al-Ahsa Oasis with the aid of using irrigation water quality indices (IWQIs). One hundred and forty-eight different water samples were collected from various irrigation water resources throughout Al-Ahsa Oasis. The investigated physiochemical characteristics include pH, temperature, TDS, EC, turbidity, free chlorine, total hardness, cations (Na, K, Ca, Mg), anions (Cl, CO3, HCO3, SO4), organic matter indices (DO, BOD, COD), and nutrients (NH4, NO3, PO4). The IWQIs used in this study include salinity hazard, sodium adsorption ratio (SAR), Kelly’s ratio (KR), soluble sodium percentage (SSP), Permeability index (PI), residual sodium carbonate (RSC), and magnesium hazard (MH). The results indicated that treated wastewater mixed with groundwater is acceptable for irrigation. Spatial variations in irrigation water quality throughout Al-Ahsa are associated with water resources. For instance, groundwater mixed with agricultural drainage has the highest values of TDS, cations, and anions, whereas the lowest values were reported for treated wastewater, reflecting the good efficiency of wastewater treatment plants. The IWQI results revealed that 4.1% and 62.1% of the investigated irrigation water samples were considered good (class III) and satisfactory (class IV) for irrigation, respectively, whereas 33.8% of the collected water samples fall within the severe irrigation restrictions. Moreover, 79.7% of the investigated water samples were classified to have high to very high salinity hazards (C3, C4) and medium to high sodium hazards (S2, S3). Regular monitoring and assessment of treated water quality and wastewater treatment plant efficiency are important factors in achieving the sustainability of treated wastewater reuse in irrigation and consequently food security.
In the arid landscape south of the Grand Canyon, natural springs and seeps are a critical resource for endemic species and Native American tribes. Groundwater is potentially threatened by expanding ...populations, tourism, and mineral extraction activities. Environmental tracers, including noble gases, stable isotopes of hydrogen and oxygen in water, tritium, and carbon-14, were used to characterize recharge sources and flow paths in South Rim aquifers. Results confirm the regional Redwall-Muav aquifer is the primary groundwater source to springs. However, a second local recharge source is required to explain the detection of tritium. Probable sources are: (1) low-elevation infiltration of surface run-off with warm recharge temperatures and high excess air determined from noble gas models, and relatively low fractions of winter recharge, and (2) high-elevation plateau recharge with cool recharge temperatures, low excess air, and fraction of winter recharge of approximately 1. Previous investigators have linked spring occurrence with regional faults and fractures. Such features also likely control the chemical mixing between the regional and local groundwater sources, the transport of deeply sourced and local recharge fluids, groundwater age, and thus the relative vulnerability of groundwater to depletion and contamination. The new conceptual model of groundwater sources and flow paths suggests that many South Rim springs may respond on the order of tens to hundreds of years to groundwater depletion and contamination, even though the majority of groundwater flow is along longer flow paths with longer lag times. The magnitude of response to short-term changes in the flow system remains unclear.
The main objective of this paper is to analyze the impact of climate change on water resources management and groundwater quantity and quality in the coastal agricultural Almyros Basin, in Greece. ...Intensive groundwater abstractions for irrigation and nitrogen fertilization for crop production maximization, have caused a large water deficit, nitrate pollution, as well as seawater intrusion in the Almyros aquifer system. Multi-model climate projections for Representative Concentration Pathways (RCPs 4.5 and 8.5) from the Med-CORDEX database for precipitation and temperature have been used to evaluate the impacts of climate change on the study area. The multi-model climate projections have been bias-corrected with Delta, Delta change of Mean and Variance, Quantile Delta Change, Quantile Empirical Mapping, and Quantile Gamma Mapping methods, and statistically tested to find the best GCM/RCM multi-model ensemble. Simulation of coastal water resources has been performed using an Integrated Modelling System (IMS) that contains connected models of surface hydrology (UTHBAL), groundwater hydrology (MODFLOW), nitrate leaching/crop growth (REPIC), nitrate pollution (MT3DMS), and seawater intrusion (SEAWAT). The results indicate that the best climate multi-model ensemble consists of three (3) climate models for both RCP4.5 and RCP8.5 using the Quantile Empirical Mapping bias-correction method. The IMS was applied for historical and future periods with observed and simulated meteorological inputs (e.g. precipitation and temperature) and various irrigation and agronomic scenarios and water storage works development (i.e. reservoirs). The results indicate that at least deficit irrigation and deficit irrigation along with rain-fed cultivation schemes, combined with or without the development and operation of reservoirs, should be applied to overcome the degradation of groundwater quality and quantity in the study basin. Based on the findings of this work, the water resources management should be adaptive to tackle the water resources problems of the Almyros Basin.
A warmer climate increases evaporative demand. However, response to warming depends on water availability. Existing earth system models represent soil moisture but simplify groundwater connections, a ...primary control on soil moisture. Here we apply an integrated surface-groundwater hydrologic model to evaluate the sensitivity of shallow groundwater to warming across the majority of the US. We show that as warming shifts the balance between water supply and demand, shallow groundwater storage can buffer plant water stress; but only where shallow groundwater connections are present, and not indefinitely. As warming persists, storage can be depleted and connections lost. Similarly, in the arid western US warming does not result in significant groundwater changes because this area is already largely water limited. The direct response of shallow groundwater storage to warming demonstrates the strong and early effect that low to moderate warming may have on groundwater storage and evapotranspiration.
As the world human population and industrialization keep growing, the water availability issue has forced scientists, engineers, and legislators of water supply industries to better manage water ...resources. Pollutant removals from wastewaters are crucial to ensure qualities of available water resources (including natural water bodies or reclaimed waters). Diverse techniques have been developed to deal with water quality concerns. Carbon based nanomaterials, especially carbon nanotubes (CNTs) with their high specific surface area and associated adsorption sites, have drawn a special focus in environmental applications, especially water and wastewater treatment. This critical review summarizes recent developments and adsorption behaviors of CNTs used to remove organics or heavy metal ions from contaminated waters via adsorption and inactivation of biological species associated with CNTs. Foci include CNTs synthesis, purification, and surface modifications or functionalization, followed by their characterization methods and the effect of water chemistry on adsorption capacities and removal mechanisms. Functionalized CNTs have been proven to be promising nanomaterials for the decontamination of waters due to their high adsorption capacity. However, most of the functional CNT applications are limited to lab-scale experiments only. Feasibility of their large-scale/industrial applications with cost-effective ways of synthesis and assessments of their toxicity with better simulating adsorption mechanisms still need to be studied.
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