Recent developments within the topic of biomaterials has taken hold of researchers due to the mounting concern of current environmental pollution as well as scarcity resources. Amongst all compatible ...biomaterials, polycaprolactone (PCL) is deemed to be a great potential biomaterial, especially to the tissue engineering sector, due to its advantages, including its biocompatibility and low bioactivity exhibition. The commercialization of PCL is deemed as infant technology despite of all its advantages. This contributed to the disadvantages of PCL, including expensive, toxic, and complex. Therefore, the shift towards the utilization of PCL as an alternative biomaterial in the development of biocomposites has been exponentially increased in recent years. PCL-based biocomposites are unique and versatile technology equipped with several importance features. In addition, the understanding on the properties of PCL and its blend is vital as it is influenced by the application of biocomposites. The superior characteristics of PCL-based green and hybrid biocomposites has expanded their applications, such as in the biomedical field, as well as in tissue engineering and medical implants. Thus, this review is aimed to critically discuss the characteristics of PCL-based biocomposites, which cover each mechanical and thermal properties and their importance towards several applications. The emergence of nanomaterials as reinforcement agent in PCL-based biocomposites was also a tackled issue within this review. On the whole, recent developments of PCL as a potential biomaterial in recent applications is reviewed.
Nacre-mimicking nanocomposites based on colloidal cellulose nanofibrils (CNFs) and clay nanoparticles show excellent mechanical properties, yet processing typically involves preparation of two ...colloids followed by a mixing step, which is time- and energy-consuming. In this study, a facile preparation method using low energy kitchen blenders is reported in which CNF disintegration, clay exfoliation and mixing carried out in one step. Compared to composites made from the conventional method, the energy demand is reduced by about 97 %; the composites also show higher strength and work to fracture. Colloidal stability, CNF/clay nanostructure, and CNF/clay orientation are well characterized. The results suggest favorable effects from hemicellulose-rich, negatively charged pulp fibers and corresponding CNFs. CNF disintegration and colloidal stability are facilitated with substantial CNF/clay interfacial interaction. The results show a more sustainable and industrially relevant processing concept for strong CNF/clay nanocomposites.
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The present work shows the feasibility of incorporating properly treated jute strands into a polylactic acid (PLA) thermoplastic matrix. The role of lignin in the interaction between jute strands and ...PLA was assessed by means of gradually decreasing the amount of lignin and producing composites. Five different lignin contents were studied and the resulting strands were incorporated into the PLA matrix at the ratio of 30 wt%. Composites were produced in a discontinuous extruder and standard specimens were injected and characterized at tensile. It was found that as the amount of lignin was decreased, the interface between the matrix and the reinforcement was properly improved, since tensile strength was increased up to 46% and FTIR analysis revealed the existence of H-bonds however they cannot be clearly related with an interaction between both phases. Both macro and micromechanical analysis showed that jute strands with a lignin content of 4% were the most suitable to be used as PLA reinforcement, mainly due to their higher intrinsic mechanical properties, better interaction with PLA and dispersion within the matrix. Overall, it was found that it is possible to obtain high-performance bio-based and presumably biodegradable composites with potential to substitute current oil-based commodities.
In Indonesia, starch, particularly that obtained from bengkuang (Pachyrhizus erosus), is abundant and inexpensive, thereby increasing the value of bengkuang starch, which can be mixed with ...bioplastic-based starch. A biocomposite comprising nanocellulose from water hyacinth (Eichhornia crassipes) and bengkuang starch was successfully fabricated using the solution casting method. Nanocellulose content in the matrix was kept constant at 1wt%. Moreover, during fabrication, the biocomposite gel was treated in an ultrasonic bath for 0, 15, 30, and 60min. Further, thermogravimetric analysis, moisture absorption measurements, Fourier transform infrared spectroscopy, and scanning electron microscopy were performed. The biocomposite sample vibrated for 60min had the highest thermal stability and exhibited low moisture absorption. The soil burial test proved that this biocomposite, as opposed to 0-min vibrated samples, has a slower biodegradation rate. This result was supported by morphological evaluation after biodegradation, in which the 60-min vibrated samples showed a coarse surface and low porosity formation.
Agglomerations of nanoparticles in a polymer matrix can drastically reduce the mechanical properties of a polymer nanocomposite, especially its strength. The grafting of nanoparticle surfaces with ...suitable functional groups can provide improved dispersion and stronger interfacial bonding, improving the fracture resistance of the nanocomposite. In this study, calcium-deficient nanohydroxyapatite (nHA) particles were functionalized with an amino acid-based urethane methacrylate (lysine urethane methacrylate, LUM) and subsequently reacted with hydroxyethyl methacrylate. We mixed these functionalized nHA particles with resin, composed of methacrylated acrylated epoxidized soybean oil, methacrylated isosorbide, and triethylene glycol dimethacrylate, and 3D-printed nanocomposites using masked stereolithography. We hypothesized that the functionalized nanoparticles would enhance the mechanical performance of the 3D-printed nanocomposites due to the greater dispersion and stronger interface. Flexural, tensile, compression and Mode-I fracture toughness test specimens were fabricated using a mSLA printer and tested following ASTM standards. The LUM functionalization of nHA improved the dispersion and increased the viscosity of the uncured nanocomposite ink. The flexural fracture strength, yield strength, and mode-I fracture toughness values were increased by 10 %, 30 %, and 11 %, respectively. The LUM improved the strength and fracture toughness by providing a stronger, more stable interface, resisting debonding between the matrix and particles, allowing for greater plastic deformation.
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Bio-based composites can mitigate the pollution issues linked to petroleum-based materials due to their eco-friendly properties. On the other hand, bio-based functionalized metal-organic frameworks ...have gained attention in the field of flame retardants due to their multi-pathway flame retardant mechanism and environmentally friendly synthesis process. However, its application in wood industry is less. In this work, a novel functional adhesive and coating (ACS-MACS/PA-UiO66-NH2) was developed by using phosphorus-rich biomass phytate functionalized metal-organic framework (MOF) PA-UiO66-NH2 as a flame retardant and mixed with modified chitosan. Furthermore, using ACS-MACS/PA-UiO66-NH2 and three-layer wooden boards, a tight cross-linked network was formed through hot pressing dehydration and condensation reactions to prepare multifunctional wood composites. The experimental results indicated that the mechanical properties of the multifunctional wood composites are excellent. Additionally, these wood composites exhibit high levels of charring and graphitization, leading to excellent flame retardancy. The preparation process of these multifunctional wood composites is straightforward, and their excellent properties provide a foundation for the development of high-performance green composite materials.
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•A novel functional adhesive was prepared by crosslinking chitosan-based polymers with phytic acid functionalized UiO-66-NH2.•The multifunctional wood composites were prepared through hot pressing dehydration using the functional adhesive.•The multifunctional wood composites have boiling water resistance and good flame retardant properties.
Natural products have a long history of success in treating bacterial infections, making them a promising source for novel antibacterial medications. Curcumin, an essential component of turmeric, has ...shown potential in treating bacterial infections and in this study, we covalently immobilized curcumin (Cur) onto chitosan (CS) using glutaraldehyde and tannic acid (TA), resulting in the fabrication of novel biocomposites with varying CS/Cur/TA ratios. Comprehensive characterization of these ternary biocomposites was conducted using FTIR, SEM, XPS, and XRD to assess their morphology, functional groups, and chemical structures. The inhibitory efficacy of these novel biocomposites (n = 4) against the growth and viability of Pseudomonas aeruginosa (ATCC27853) and Chromobacterium violaceum (ATCC12472) was evaluated and the most promising composite (C3) was investigated for its impact on quorum sensing (QS) and biofilm formation in these bacteria. Remarkably, this biocomposite significantly disrupted QS circuits and effectively curtailed biofilm formation in the tested pathogens without inducing appreciable toxicity. These findings underscore its potential for future in vivo studies, positioning it as a promising candidate for the development of biofilm disrupting antibacterial agents.
Novel biocomposites disrupt quorum sensing and biofilm formation in pathogenic bacteria Display omitted
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•Encapsulation of proteins, carbohydrates, nucleic acids, and cells & virus in MOFs.•Bioentities@MOF as drug delivery systems.•Biopreservation properties of bioentities@MOF ...composites.•Applications of bioentities@MOF composites in biosensing.•Use of bioentities@MOF composites in virus and cell manipulation.
Metal–organic frameworks (MOFs) combined with biomacromolecules, viruses and cells have emerged as novel biocomposites for application to drug delivery, biosensing, biospecimen preservation, and cell and virus manipulation. The integration of biological entities into MOF matrices generates MOF biocomposites with functional characteristics that cannot be observed in the separate components, such as enhanced chemical and thermal stability, resistance to proteases, MOF-conferred selectivity, and controlled release. In this review, we will discuss these functional properties and applications of the biocomposites obtained by the encapsulation of (i) proteins, (ii) carbohydrates, (iii) nucleic acids, and (iv) viruses or cells in a MOF matrix. Finally, we review the post functionalization of MOF-based drug carriers with lipids as a potential route to enhance the dispersion, stability in biological fluids, and blood circulation time of MOF-based drug delivery systems.
This journal review provides a comprehensive examination of recent research and developments in the domain of jute fiber epoxy composite reinforced polymer bio composites. These bio composites have ...garnered significant attention in recent years due to their sustainability, lightweight properties, and potential applications across various industries. This review synthesizes the current state of knowledge regarding their fabrication techniques, mechanical properties, and applications.
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