This paper proposes on-driving experience sharing algorithms at junctions in infrastructure-assisted vehicles-to-everything networks. For the purpose, a millimeter-wave (mmWave) technology is used because it provides multi-Gbps data rates which is helpful for handling users' short stay times at junctions and spatial reuse due to high beam directionality which is helpful for interference-avoidance among densely deployed vehicles at junctions. To realize on-driving experience sharing, the proposed algorithms focus on joint resource allocation and scheduling for 3GPP-compliant multiple unicast vehicle-to-vehicle (V2V) communications where the vehicles are group leaders (GLs) in 3GPP Mode 4(d). The resource allocation stands for the roadside unit (RSU) allocation to scheduled V2V GL links where RSU is essentially required for overcoming blockage by establishing two-hop relaying. Because vehicles stay for short times at junctions, this paper designs two algorithms without or with delay considerations. Without delay considerations, the joint optimization of RSU allocation and scheduling was originally formulated as mixed 0-1 non-convex optimization. However our proposed algorithm reformulates the problem into mixed 0-1 convex optimization, which is computationally easier to solve. With delay considerations, our proposed algorithm dynamically controls video contents frame rates for time-average on-driving video sharing quality maximization subject to delay constraints, inspired by Lyapunov optimization. Extensive simulation results demonstrate that our algorithms can significantly outperform in a variety of scenarios. Furthermore, we conduct the cost analysis for the proposed algorithms in terms of capital expenditure (CAPEX) and operating expenditure (OPEX).