UNI-MB - logo
UMNIK - logo
 
E-viri
Celotno besedilo
Recenzirano
  • Emission color tunability o...
    Far, Ljubica Đačanin; Dramićanin, Tatjana; Medić, Mina; Ristić, Zoran; Periša, Jovana; Đorđević, Vesna; Antić, Željka; Dramićanin, Miroslav D.

    Applied physics. A, Materials science & processing, 02/2024, Letnik: 130, Številka: 2
    Journal Article

    Herein, we demonstrate the photoluminescence properties of Dy 3+ -activated YNbO 4 , LuNbO 4, and mixed Y x Lu 1− x NbO 4 :Dy 3+  ( x  = 0.25, 0.5, 0.75) phosphors. For this purpose, five samples with a fixed Dy 3+ concentration (2 mol%) were prepared by the solid-state reaction method. X-ray diffraction measurements showed that all phosphors crystallize in a monoclinic fergusonite-beta-(Y) structure with a C2/c space group. Scanning electron microscopy clearly shows that samples are composed of dense, well-developed micron-sized, cube-shaped grains with rounded edges. The photoluminescent emission spectra feature Dy 3+ peaks at standard positions corresponding to transitions from the 4 F 9/2 excited emitting level to the 6 H J ( J  = 15/2; 13/2; 11/2 and 9/2) lower levels with two dominant emission bands placed in the blue (~ 479 nm, B) and yellow (~ 576 nm, Y) spectral region. It is observed that with Lu increase in the host lattice Y/B ratio decreases toward the desired ratio of unity to obtain white light. To evaluate the suitability of these phosphors for use in solid-state lighting, their photoluminescence emission was analyzed in detail by calculating CIE coordinates, correlated color temperature (CCT) and Delta u,v (DUV). It is shown that CIE chromaticity coordinates of all Dy 3+ -activated Y x Lu 1− x NbO 4 samples ( x  = 0, 0.25, 0.5, 0.75, and 1) fall into the white portion of the diagram and that with the increase of Lu in the host lattice color becomes whiter. CCT values for all samples are in the cooler 4000–4500 K range with positive DUVs indicating that color points are placed above the black body curve. The average lifetime of 4 F 9/2 level is calculated to be ~ 0.2 ms for all Dy 3+ -activated Y x Lu 1−x NbO 4 samples, indicating that there is no influence of the Y-to-Lu ratio in the host niobate material on the luminescence kinetics.