E-viri
Recenzirano
-
Hu, Mao-Lin; Morsali, Ali; Aboutorabi, Leila
Coordination chemistry reviews, 12/2011, Letnik: 255, Številka: 23Journal Article
► This review shows the variety coordination modes of carboxylate groups increase the strength and stability of the resulting architectures. ► It was found that carboxylate groups in many of lead(II) coordination polymers form more than one type coordination mode. ► And among all of these modes maximum number is belonged to chelating (η 2) mode. In recent years, the chemistry of metal-coordination polymers has been advanced due to their diverse topologies and potential applications in smart optoelectronic, magnetic, microporous and biomimetic materials with specific structures, properties, and reactivities. Metal carboxylates have emerged as a large family of open framework materials. Recently, metal carboxylate chemistry has enhanced because of the increasing importance of hybrid inorganic–organic compounds with potential applications in separation, catalysis, and gas storage. So far, research on coordination polymers has considerably been concentrated on incorporation of s-, d-, and even f-block metal ions as coordination centers. As a heavy p-block metal ion, lead(II), with its large radius, flexible coordination environment, and variable stereo-chemical activity, is suitable for formation of unusual network topologies with interesting properties. This review provides an overview of all lead(II) carboxylate supramolecular compounds reported since 1990 and an investigation of their coordination modes, properties and structures. The variety of coordination modes of carboxylate groups increase the strength and stability of the resulting architectures. These modes include (η 1), (μ 2-η 1:η 1), (η 2), (μ 2-η 2), (μ 3-η 1:η 2), (μ 3-η 1:η 2), (μ 2-η 2:η 1), (μ 3-η 1:η 2:η 1) and (μ 4-η 2:η 2) that have created multiplicity polymeric structures with different dimensions. In this study it was found that carboxylate groups in many of lead(II) coordination polymers form more than a single type of coordination mode and among all of these modes maximum number belonged to chelating (η 2) mode.
![loading ... loading ...](themes/default/img/ajax-loading.gif)
Vnos na polico
Trajna povezava
- URL:
Faktor vpliva
Dostop do baze podatkov JCR je dovoljen samo uporabnikom iz Slovenije. Vaš trenutni IP-naslov ni na seznamu dovoljenih za dostop, zato je potrebna avtentikacija z ustreznim računom AAI.
Leto | Faktor vpliva | Izdaja | Kategorija | Razvrstitev | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Baze podatkov, v katerih je revija indeksirana
Ime baze podatkov | Področje | Leto |
---|
Povezave do osebnih bibliografij avtorjev | Povezave do podatkov o raziskovalcih v sistemu SICRIS |
---|
Vir: Osebne bibliografije
in: SICRIS
To gradivo vam je dostopno v celotnem besedilu. Če kljub temu želite naročiti gradivo, kliknite gumb Nadaljuj.