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A metal-organic polyhedron based on dibenzothiophene ligand: Gas adsorption and reductive propertiesMa, Sha; Niu, Yanfei; Zhao, Xiaoli; Duan, Zhiming
Inorganic chemistry communications, August 2016, 2016-08-00, Letnik: 70Journal Article
A new metal–organic polyhedron Cu-MOP with octahedral geometry was constructed by 2,8-dibenzothiophenedicarboxylic acid and dicopper paddlewheel. Cu-MOP exhibited H2 and CO2 sorption behavior. Furthermore, Cu-MOP revealed reductive properties towards TCNQ, DDQ, CR and MB due to the electron-donating nature of DBT ligand. A new metal organic polyhedron Cu-MOP based on a dibenzothiophene ligand showing gas sorption and reductive properties. Display omitted •A new metal organic polyhedron Cu-MOP based on a dibenzothiophene ligand has been synthesized and characterized.•Cu-MOP showed H2 and CO2 sorption behavior over N2.•TCNQ, DDQ, CR and MB could be reduced in the presence of Cu-MOP.
