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Preuss, Marco D.; Schnitzer, Tobias; Jansen, Stef A. H.; Meskers, Stefan C. J.; Kuster, Tom H. R.; Lou, Xianwen; Meijer, E. W.; Vantomme, Ghislaine
Angewandte Chemie, June 10, 2024, Letnik: 136, Številka: 24Journal Article
Molecular scaffolds that enable the combinatorial synthesis of new supramolecular building blocks are promising targets for the construction of functional molecular systems. Here, we report a supramolecular scaffold based on boroxine that enables the formation of chiral and ordered 1D supramolecular polymers, which can be easily functionalized for circularly polarized luminescence. The boroxine monomers are quantitatively synthesized in situ, both in bulk and in solution, from boronic acid precursors and cooperatively polymerize into 1D helical aggregates stabilized by threefold hydrogen‐bonding and π–π stacking. We then demonstrate amplification of asymmetry in the co‐assembly of chiral/achiral monomers and the co‐condensation of chiral/achiral precursors in classical and in situ sergeant‐and‐soldiers experiments, respectively, showing fast boronic acid exchange reactions occurring in the system. Remarkably, co‐condensation of pyrene boronic acid with a hydrogen‐bonding chiral boronic acid results in chiral pyrene aggregation with circularly polarized excimer emission and g‐values in the order of 10−3. Yet, the electron deficiency of boron in boroxine makes them chemically addressable by nucleophiles, but also sensitive to hydrolysis. With this sensitivity in mind, we provide first insights into the prospects offered by boroxine‐based supramolecular polymers to make chemically addressable, functional, and adaptive systems. Boronic acid self‐condensation provides ready access to boroxine‐based, C3‐symmetrical monomer architectures that can cooperatively assemble into helical supramolecular polymers. The dynamic boroxine scaffold enables fast intermolecular exchange of boronic acid between different monomers and facilitates the introduction of functionality into assembled structures by co‐condensation with functional boronic acids.
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