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Liu, Lixin; Pan, Neng; Sheng, Wei; Su, Lebin; Liu, Long; Dong, Jianyu; Zhou, Yongbo; Yin, Shuang‐Feng
Advanced synthesis & catalysis, September 3, 2019, Letnik: 361, Številka: 17Journal Article
With sunlight or blue LEDs irradiation, regioselective decarboxylative alkylation of various non‐aromatic heterocycles has been realized via C(sp3)‐centered radical C(sp2)−C(sp3) bond formation under oxidant‐free conditions at room temperature. This reaction readily incorporates various functional alkyl groups into heterocyclic compounds without observation of any alkyl radical rearrangement and represents a mild and general tool for the preparation of valuable alkyl group‐functionalized heterocyclic compounds.
