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  • Stereospecific Couplings of...
    Leonori, Daniele; Aggarwal, Varinder K.

    Angewandte Chemie (International ed.), January 19, 2015, Letnik: 54, Številka: 4
    Journal Article

    This Minireview highlights advances in the Suzuki–Miyaura cross‐coupling of secondary boron reagents for the creation of CC bonds with control of stereochemistry. It also includes non‐transition‐metal coupling of secondary and tertiary boronic esters to electron‐rich aromatics. Just couple it: In the past decade, highly efficient protocols have been developed to allow the stereospecific arylation of chiral organoborons. This Minireview documents the rapid development of this area, thus providing a clear overview of the various processes available together with mechanisms, as well as their scope and limitations.