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Kim, Jinwoo; Chang, Sukbok
Angewandte Chemie (International ed.), February 17, 2014, Letnik: 53, Številka: 8Journal Article
An iridium‐catalyzed direct CH amidation of weakly coordinating substrates, in particular of those bearing ester and ketone groups, under very mild conditions has been developed. The observed high reaction efficiency was achieved by the combined use of acetic acid and lithium carbonate as additives. Mild and direct: The iridium‐catalyzed direct CH amidation of weakly coordinating substrates, particularly of those with ester and ketone groups, under very mild conditions has been developed. With the aid of a combined use of acetic acid and lithium carbonate as additives, the reaction proceeded with high efficiency. Cp*=pentamethylcyclopentadienyl.
