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Počkaj, Marta; Kitanovski, Nives; Čeh, Boris; Cerc-Korošec, Romana
Acta chimica Slovenica, 06/2017, Letnik: 64, Številka: 2Journal Article
Two novel isostructural coordination compounds of manganese(II) (1) and iron(II) (2) with common formulae MII(NCS)2(nia)2(OH2)2 have been prepared from water solution of appropriate metal salt, nicotinamide and KSCN. Their crystal structures were determined by means of X-ray diffraction on single crystals. The mononuclear title compounds crystallize in a triclinic P-1 space group with six monodentate octahedrally arranged ligands around the metal centre. The coordination molecules are self-assembled with an extended network of hydrogen bonds into a three-dimensional structure. Additionally, 1 and 2 were characterized with infrared spectroscopy, magnetic measurements and thermal analysis.
![[MII(NCS)2(nia)2(OH2)2]: Pr...](http://api.summon.serialssolutions.com/2.0.0/image/issn/XR4PS5YY4K/1318-0207/medium "[MII(NCS)2(nia)2(OH2)2]: Preparation, Crystal Structure and Thermal Properties (MII = Mn, Fe; nia = nicotinamide)")
