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  • Tracing the ingredients for...
    Bergin, Edwin A; Geoffrey A. Blake; Fred Ciesla; Marc M. Hirschmann; Jie Li

    Proceedings of the National Academy of Sciences - PNAS, 07/2015, Letnik: 112, Številka: 29
    Journal Article

    We use the C/N ratio as a monitor of the delivery of key ingredients of life to nascent terrestrial worlds. Total elemental C and N contents, and their ratio, are examined for the interstellar medium, comets, chondritic meteorites, and terrestrial planets; we include an updated estimate for the bulk silicate Earth (C/N = 49.0 ± 9.3). Using a kinetic model of disk chemistry, and the sublimation/condensation temperatures of primitive molecules, we suggest that organic ices and macromolecular (refractory or carbonaceous dust) organic material are the likely initial C and N carriers. Chemical reactions in the disk can produce nebular C/N ratios of ∼1–12, comparable to those of comets and the low end estimated for planetesimals. An increase of the C/N ratio is traced between volatile-rich pristine bodies and larger volatile-depleted objects subjected to thermal/accretional metamorphism. The C/N ratios of the dominant materials accreted to terrestrial planets should therefore be higher than those seen in carbonaceous chondrites or comets. During planetary formation, we explore scenarios leading to further volatile loss and associated C/N variations owing to core formation and atmospheric escape. Key processes include relative enrichment of nitrogen in the atmosphere and preferential sequestration of carbon by the core. The high C/N bulk silicate Earth ratio therefore is best satisfied by accretion of thermally processed objects followed by large-scale atmospheric loss. These two effects must be more profound if volatile sequestration in the core is effective. The stochastic nature of these processes hints that the surface/atmospheric abundances of biosphere-essential materials will likely be variable. With the rapid pace at which exoplanets are being discovered, many efforts have now been dedicated to identifying which planets are expected to have the ingredients necessary for the development of life. In this work we explore the relative disposition of the essential elements carbon and nitrogen in each stage of star and planet formation, using the Earth and our solar system as grounding data. Our results suggest that planets like the Earth are readily supplied with these key elements, but their relative amounts on the surface and in the atmosphere will be highly variable.