In order to correct the monitoring data of the miniature air quality detector, an air quality prediction model fusing Principal Component Regression (PCR), Support Vector Regression (SVR) machine, and Autoregressive Moving Average (ARMA) model was proposed to improve the prediction accuracy of the six types of pollutants in the air. First, the main information of factors affecting air quality is extracted by principal component analysis, and then principal component regression is used to give the predicted values of six types of pollutants. Second, the support vector regression machine is used to regress the predicted value of principal component regression and various influencing factors. Finally, the autoregressive moving average model is used to correct the residual items, and finally the predicted values of six types of pollutants are obtained. The experimental results showed that the proposed combination prediction model of PCR-SVR-ARMA had a better prediction effect than the artificial neural network, the standard support vector regression machine, the principal component regression, and PCR-SVR method. The Root Mean Square Error (RMSE), Mean Absolute Error (MAE), and relative Mean Absolute Percent Error (MAPE) are used as evaluation indicators to evaluate the PCR-SVR-ARMA model. This model can increase the accuracy of self-built points by 72.6% to 93.2%, and the model has excellent prediction effects in the training set and detection set, indicating that the model has good generalization ability. This model can play an active role scientific arrangement and promotion of miniature air quality detectors and grid-based monitoring of the concentration of various pollutants.