Central Technological Library of the University of Ljubljana (CTK)
13.
Aplikacija inverzne plinske kromatografije v polimerni kemiji in pri formulacijah premaznih sredstev
Kunaver, Matjaž ; Guthrie, James T... ; Kamin, Franc
Običajna plinska kromatografija uporablja stacionarno fazo za analizo substanc, ki so v mobilni fazi. Pri inverzni plinski kromatografiji pa uporabljamo znane substance, ki so v mobilni fazi, za ...karakterizacijo stacionarne faze. Ta pa je lahko polimer, pigment, utrjen premazni sistem ali karkoli, s čimer lahko napolnimo kromatografsko kolono. S to metodo lahko določamo različne termodinamske lastnosti, Lewisovo kislost ali bazičnost, predvsem pa nam omogoča vpogled v naravo in velikost medsebojnih interakcij v sistemu polimer - pigment. Vse to je v premazni industriji osnova za formuliranje premaznih sredstev, je pa tudi metoda za študij adhezije, adsorpcije, temperature steklastega prehoda, interakcijskega parametra polimer - topilo, polimer - polimer, kislo - bazičnih interakcij itd. Predvsem te pa imajo lahko izredno močan vpliv na mnoge lastnosti premaznega sredstva.
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