A prototype of a new shape-memory nitinol knitted fabric intended for use as an active thermal insulating interlining in firefighting protective clothing was developed in the study presented in this ...paper. Weft knitted fabrics were made from commercially available cold-worked nickel titanium alloy monofils. Knits were made on a manual knitting machine from a monofil measuring 0.1 mm in diameter, while a hand-made knit was prepared from a monofil measuring 0.2 mm in diameter. Nitinol fabrics were annealed at 500 °C to achieve an austenite transition temperature of 75 °C. A special constructed mould made of a steel frame and aluminium domes measuring 30 and 20 mm in height was used to give the nitinol fabrics a new temporary shape. A two-way, shape-memory effect of the nitinol fabrics was achieved using a 15-cycle training process. The achieved shape-memory effect was tested in a heated chamber at 100 °C, where bulges measuring 12-25 mm in height occurred. NiTi knits made from finer monofil were the most successful shape-memory knits. They were machine knitted and achieved sufficiently high bulges, measuring 18 or 12 mm, that facilitated large enough air gaps for effective thermal protection. A smart textile system was prepared by inserting the trained nitinol fabric into a pocket made from two textile fabric layers sewn together. When it was exposed to environmental temperatures of 75 °C and higher, it instantly changed its form from a two-dimensional shape to a three-dimensional shape, while increasing the air gap in the pocket. A quilted fabric made from such a smart textile system could be used in firefighting protective clothing to locally improve thermal insulation and protect the human skin from overheating or burns.
The influence of chemical composition and heat treatment on the mechanical properties and formability of the selected commercial aluminium alloy EN AW 5454 was investigated. The main properties of ...alloy 5454 from the AA 5xxx series are very good corrosion resistant and has good formability. From the cast slab a 50 mm thick slice was taken in the width cross section in the slab centre. One half of the slice was homogenised for 10 hours at a temperature of 530 °C. The cast and homogenised samples were investigated using light and scanning electron microscopy. For the study of the influence of the heat treatment, samples in the as-cast state were annealed in the laboratory furnace at a temperature of 530 °C for 4, 6, 8, 10 and 12 hours. To study the influence of chemical composition, four different samples were prepared: the first without additions, the second with an addition of 1 wt% Mn, the third with 3 wt% Mg and the fourth with an addition of both elements, Mn and Mg. The XRF analyses confirmed the desired chemical composition of all four produced alloys. Half of each alloy’s sample was homogenised at the same temperature and time as the base alloy in the as-cast state. The hot deformation behaviour of the different alloys was investigated using cylindrical hot compression tests performed on a Gleeble 1500D thermo-mechanical simulator. By comparing flow curves a high influence of the thermo-mechanical parameters on the alloy formability can be seen. The alloy has good workability and with the addition of Mn and Mg, the stress values are higher than those of the base alloy.
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