Bio-char has the ability to isolate carbon in soils and concurrently improve plant growth and soil quality, high energy density and also it can be used as an adsorbent for water treatment. In the ...current work, the characteristics of four different types of bio-chars, obtained from slow pyrolysis at 375 °C, produced from hard-, medium-, thin- and paper-shelled walnut residues have been studied. Bio-char properties such as proximate, ultimate analysis, heating values, surface area, pH values, thermal degradation behavior, morphological and crystalline nature and functional characterization using FTIR were determined. The pyrolytic behavior of bio-char is studied using thermogravimetric analysis (TGA) in an oxidizing atmosphere. SEM analysis confirmed morphological change and showed heterogeneous and rough texture structure. Crystalline nature of the bio-chars is established by X-ray powder diffraction (XRD) analysis. The maximum higher heating values (HHV), high fixed carbon content and surface area obtained for walnut shells (WS) samples are found as ~ 18.4 MJ kg−1, >80% and 58 m2/g, respectively. Improvement in HHV and decrease of O/C and H/C ratios lead the bio-char samples to fall into the category of coal and confirmed their hydrophobic, carbonized and aromatized nature. From the Fourier transform infra-red spectroscopy (FTIR), it is observed that there is alteration in functional groups with increase in temperature, and illustrated higher aromaticity. This showed that bio-chars have high potential to be used as solid fuel either for direct combustion or for thermal conversion processes in boilers, kilns and furnace. Further, from surface area and pH analysis of bio-chars, it is found that WS bio-chars have similar characteristics of adsorbents used for water purifications, retention of essential elements in soil and carbon sequestration.
Various thermal spraying approaches, such as air/atmospheric plasma spraying (APS) and high-velocity oxy-fuel (HVOF) spraying, are widely employed by plants owing to their flexibility, low costs and ...the high surface quality of the manufactured product. This study focuses on the corrosion behavior of a Ni superalloy coated with powder Cr3C2-25NiCr through APS and HVOF at 950 °C under air oxidation and Na2SO4 + 0.6V2O5 molten salt environments (MSE). The results show that HVOF-deposited Ni superalloys have higher hardness and bond strength than the respective APS coating. The thermo-gravimetric probe reveals that the Ni superalloys exposed to an oxidizing air environment has a minor mass gain compared to those under the MSE domain for both non-coated and coated samples, in line with the parabola curvature rate oxidizing law. The Ni superalloys show good corrosion resistance but poor oxidation resistance in APS-deposited Ni superalloys under the MSE. HVOF-coated Ni superalloys in both environments exhibit better corrosion resistance and lower mass gain than APS-coated superalloys. The excellent coating characteristics of HVOF-coated Ni superalloys lead to their better high-temperature corrosion performance than APS.
As it increases the pressure and temperature of incoming steam and decreases CO2 emissions, oxidation is crucial for materials used in power plants to increase their efficiency. Compound composite ...(Cr2O3 + YSZ) coatings applied to Inconel 718 (EN8) substrates using the Atmosphere Plasma Spray technique are anticipated to increase structural resistance when subjected to high pressure and temperature oxidation conditions of service. The nickel-based superalloys EN8 and EN8/Yttria (8% Y2O3) Stabilized Zirconia (YSZ)/Cr2O3 were subjected to high-temperature oxidation tests in the open air at 1050 °C for approximately 12, 24, 48, and 100 h. EN8 is not appropriate for prolonged use at 1050 °C as can be seen from scanned electron microscope and energy dispersive X-ray spectroscopy analyses on isothermally oxidized samples. The findings demonstrated that the EN8 alloy exhibited more significant weight variations over 48 h at high temperatures because its chromia oxide scale was continuously smaller. With phase dispersion in the microstructure, coated EN8 exhibits a higher performance under more prolonged exposure than the EN8 alloy. Additionally, the synthesis of outer chromium oxide, YSZ, and Cr2O3 on a substrate at 1050 °C for 100 h improved the outstanding oxidation resistance while maintaining the integrity of the chromium oxide layer.
The fuel consumption of high-density automobiles has increased in recent years. Aluminum (Al) alloy is a suitable material for weight reduction in vehicles with high ductility and low weight. To ...address environmental problems in aircraft and maritime applications, in particular rust development and corrosion, the current study assesses the corrosion behavior during friction stir welding (FSW) of two dissimilar Al alloys (AA6061 and AA8011) in various corrosive conditions using salt spraying and submersion tests. Two acidic solutions and one alkaline solution are used in these tests, which are performed at room temperature. The two specimens (AA6061 and AA8011) and the weld region are suspended in a salt spraying chamber and a 5 wt.% NaCl solution is continually sprayed using the circulation pump for 60 h, with the specimens being weighed every 15 h to determine the corrosion rates. According to the salt spraying data, the weld zone has a higher corrosion resistance than the core components. For twenty-eight days, individual specimens are submerged in 3.5 wt.% HCl + H
O and H
SO
+ H
O solutions and seawater. The weld area specimens exhibit stronger corrosion resistance than the base material specimens, and weight loss in the saltwater medium is lower when compared to the other test solutions, according to the corrosion analysis. The scanning electron microscope (SEM) analysis demonstrates that the base metal AA8011 is considerably corroded on its surface.
Reinforced composite materials have many applications in the aerospace, marine, and petroleum industries. Glass fiber-reinforced pipes are of considerable importance as pressurized vessels, ...infrastructure materials, and petroleum wastewater pipelines. The stress intensity factor due to through-thickness discontinuities is a major parameter in fracture mechanics to understand the failure mechanisms in glass fiber-composite pipes. The stress intensity factor is calculated for a composite cylinder subjected to internal pressure using the linear extended finite element method based on the law of energy release evaluation of surface damage. The analytical model needs two material properties; they are the tensile strength and the fracture toughness; therefore, a standard tensile test was carried out on a standard specimen taken from the pipe’s wall thickness. Moreover, the compact tension test specimen was manufactured from the pipe’s wall thickness to obtain the fracture toughness. The average tensile strength was measured as 21.5 MPa with a standard deviation of 5.59 MPa, moreover, the average Young’s modulus was measured as 32.75 GPa with a standard deviation of 6.64 GPa. The fracture toughness was measured as 2322 (MPa m) with a standard deviation of 142.5 (MPa m), whereas the average surface release energy (GIC) was 153.6 kJ/m2 with a standard deviation of 22.53 kJ/m2. A valuable design equation was extracted from the finite element model to measure the effect of cracks on the hoop stress of the cylinder wall thickness based on a nonlinear model. Moreover, an acceptable equation was used to calculate the correction and shape factor of a cylinder with movable and unmovable through-thickness cracks. This study provides useful tools and guidance for the design and analysis of composite cylinders.
The role of rapid tooling (RT) in additive manufacturing (AM) seems essential in improving and spreading out the vista of manufacturing proficiency. In this article, attempts were made to discover ...the feasibility and the accomplishments of the RT electrode in the field of electro-discharge machining (EDM). Fused deposition modeling (FDM) is one of the AM processes adopted to fabricate the EDM electrode prototype by coating with copper. The copper is deposited on FDM-built ABS plastic component for about 1 mm through thick electroplating. The copper-coated FDM (CCF) and solid copper (SC) electrodes are used to conduct experiments on a die-sinking EDM machine using tool alloy steel as a workpiece. The CCF polymer electrode can be efficiently used in EDM operations as the build time of any complex shape was substantially reduced. However, the material removal rate (MRR) is far less than that of the SC electrode. It is recommended that the CCF electrode is used for semifinishing and finishing operations in which MRR happens to be less. However, CCF can get spoiled as high temperatures are generated on the machining tool, and the plastic core hardly sustains such high temperatures.
The present paper describes the structural analysis performed on a preloaded bolted joint. The first joint modeled was comprised of a conventional cylindrical flange that was sliced to simplify the ...analysis for two bolts in lieu of four. This involved an L-shaped flat segment flange. Parametric studies were performed using elastic, large-deformation, non-linear finite element analysis to determine the influence of several factors on the bolted-joint response. The factors considered included bolt preload, contact surfaces, edge boundary conditions, and joint segment length in this first approach. The second model applied the previous preloaded torque on a complex flange to study the flange lift off. Joint response is reported in terms of displacements, gap opening, and surface strains. Most of the factors studied were determined to have minimal effect on the bolted joint response.
Aluminum alloy (AA6061)-based hybrid metal matrix composites (HMMCs) are manufactured using a dual stir casting method, with varying volume percentages of B4C (5%, 10%, and 15%) and Gr (10%, 15%, and ...20%) incorporated. The resulting HMMC and reinforcement elements are uniformly dispersed within the main matrix, forming a mechanically mixed layer with interfacial reactions. This layer reduces wear loss and friction coefficient compared to AA6061, especially with higher amounts of B4C and Gr, as they demonstrate little aggregation of reinforced material. The presence of Gr particles enabled the impact of different wear parameters (applied load, sliding speed, and distance) to be combined. Micro-hardness studies demonstrate that the hardness of HMMC increases as the volume fraction of reinforced particles and sliding distance increase. The compression test revealed a 22% improvement over AA6061. As a result, adding reinforcing materials to the matrix contributes to inducing greater strength by increasing wear resistance with a Gr-imparted lubrication effect.