This study is focused on the effects of pH on the production of volatile fatty acids (VFAs) and their distribution through the acidogenic fermentation of source-sorted organic fraction of municipal ...solid waste (OFMSW) from a mechanical-biological treatment (MBT) plant, and food waste (FW) from a university canteen. In semi-continuous lab-scale digesters using OFMSW at a hydraulic retention time (HRT) of 3.5 days under acidic conditions (pH 6.0), the VFA concentration in the effluent increased to 9.8–11.5 g L
−1
(VS content of the feedstock between 4.2 and 5.2%
w
/
w
), while its individual VFA profiling was similar to the influent which was already pre-fermented (namely, C
2
35–41%, C
3
18–22%, C
4
17–21%, and C
5
9–12%). When working with the same conditions but using FW as feedstock, an effluent with a VFA concentration up to 11.5 g VFA L
−1
(FW with a VS content of 5.5%
w
/
w
) and a stable distribution of C
2
and C
4
acids (up to 60.3% and 12.9%, respectively) but with very low quantities of C
3
and C
5
acids (lower than 1.8 and 2.7%, respectively) was obtained. Anaerobic batch tests using FW revealed that alkaline pH near 9 could lead to higher VFA production with high acetic acid content when compared to pH 6. In the semi-continuous fermenters working at alkaline conditions (pH 9.5–10) using OFMSW and FW, an enhanced solubilization of organic matter was registered with respect to the fermenters working under acidic conditions. This fact was not reflected in a higher VFA production when using OFMSW as feedstock, probably due to free ammonia inhibition, since OFMSW was mixed in the MBT plant with supernatant from anaerobic digestion of this biowaste. However, when using FW, alkaline conditions lead to an enhanced VFA production with respect to the reactor working under acidic conditions, being acetic acid the predominant product, which represented up to 91% of the VFA spectrum obtained.
Food waste (FW) collected from a university canteen was treated in acidogenic fermenters to produce volatile fatty acids (VFA) under biological pretreatment with mature compost. Batch assays working ...at pH 6 revealed an increment of 9.0%, 7.9%, and 4.1% (on COD basis) of VFA concentration when adding 2.5%, 3.5%, and 4.5%
/
of mature compost, respectively, even though the volatile solids (VS) concentration of food waste was lower in the tests with increasing doses of mature compost. For batch tests at pH 7, this VFA generation improvement was lower, even though enhanced COD solubilization was recorded. Operating in semi-continuous conditions at 35 °C, pH of 6, and hydraulic retention time (HRT) of 3.5 days, the addition of 2.5%
/
of mature compost led to a VFA concentration up to 51.2 ± 12.3% more (on VS basis) when compared to a reference reactor without compost addition. Moreover, the percentage of butyric acid on VS basis in the fermentation broth working at a pH of 6 increased from up to 12.2 ± 1.9% (0% compost addition) to up to 23.5 ± 2.7% (2.5% compost addition). The VFA production was not improved when a higher percentage of mature compost was used (3.5% instead of 2.5%
/
), and it slightly decreased when mature compost addition was lowered to 1.5%
/
. When working at a pH of 7 in the semi-continuous fermenters with the addition of 2.5%
/
mature compost at an HRT of 3.5 days, an improvement of 79% and 104% of the VFA concentration (on VS basis) were recorded as compared to fermenters working at a pH of 6 with 2.5% and 0%
/
of mature compost addition, respectively. At a pH of 7, higher production of propionic and valeric acids was found with respect to the reactor working at a pH of 6. The effect of pH on VFA generation was estimated to have greater contribution than that of only biological pretreatment using mature compost. At a pH of 7, the VFA yield was higher for the fermenter working with 2.5%
/
mature compost but at a pH of 7 and HRT of 5 days, the effect of mature compost on VFA production improvement was lower than that obtained at a pH of 6. Moreover, higher solubilization in terms of soluble chemical oxygen demand and total ammonium was detected when biological pretreatment using mature compost was applied at both a pH of 6 and a pH of 7, which indicates enhanced hydrolysis in both conditions.
Circular economy implementations tend to decrease the human pressure on the environment, but not all produce footprint reductions. That observation brings the need for tools for the evaluation of ...recycling processes. Based on the Exergy Footprint concept, the presented work formulates a procedure for its application to industrial chemical recycling processes. It illustrates its application in the example of cotton waste recycling. This includes the evaluation of the entire process chain of polyethylene synthesis by recycling cotton waste. The chemical recycling stages are identified and used to construct the entire flowsheet that eliminates the cotton waste and its footprints at the expense of additional exergy input. The exergy performance of the process is evaluated. The identified exergy assets and liabilities are 138 MJ/kg ethylene and 153 MJ/kg ethylene, reducing the Exergy Footprint by 75% and the greenhouse gas footprint by 43% compared to the linear pattern of polyethylene production. The exergy requirements for producing raw cotton constitute a large fraction of the liabilities, while the polyethylene degradation provides the main asset in the reduction of the Exergy Footprint.
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