Herein, a sponge membrane bioreactor (Sponge-MBR) combined with ozonation process was performed to remove the antibiotics which frequently existed in the hospital wastewater. Whilst seven antibiotics ...i.e., norfloxacin, ciprofloxacin, ofloxacin, sulfamethoxazole, erythromycin, tetracycline and trimethoprim were widely used in medications, this integration was applied for the evaluation of treatment performance under different fluxes. As the results, whilst the antibiotics were eliminated about 45–93%, the tetracycline was completely removed (100%) using Sponge-MBR operated at the flux of 10 LMH. For enhancement of antibiotics removal, the ozonation process was introduced to treat the membrane permeate. Overall efficiencies were 97 ± 2% (trimethoprim), 92 ± 4% (norfloxacin), 90 ± 1% (erythromycin), 88 ± 4% (ofloxacin), 83 ± 7 (ciprofloxacin) and 66 ± 1% (sulfamethoxazole). These results demonstrated Sponge-MBR coupled with ozonation could be a prospective technology for the hospital wastewater treatment.
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•Sponge membrane bioreactor-ozonation was introduced to antibiotics removal.•High removal efficiencies were achieved for antibiotics, except sulfamethoxazole.•Ozonation enhanced sulfamethoxazole removal efficiency up to 66%.•Organics and nitrogen were significantly eliminated by Sponge membrane bioreactor.
In this study, biochar derived from spent coffee grounds (SCGB) was used to adsorb norfloxacin (NOR) in water. The biochar properties were interpreted by analysis of the specific surface area, ...morphology, structure, thermal stability, and functional groups. The impacts of pH, NOR, and ion's present on SCGB performance were examined. The NOR adsorption mode of SCGB is best suited to the Langmuir model (R2 = 0.974) with maximum absorption capacity (69.8 mg g−1). By using a Response Surface Method (RSM), optimal adsorption was also found at pH of 6.26, NOR of 24.69 mg L−1, and SCGB of 1.32 g L−1. Compared with biochars derived from agriculture such as corn stalks, willow branches, potato stem, reed stalks, cauliflower roots, wheat straw, the NOR adsorption capacity of SCGB was 2–30 times higher, but less than 3–4 times for biochars made from Salix mongolica, luffa sponge and polydopamine microspheres. These findings reveal that spent coffee grounds biochar could effectively remove NOR from aqueous solutions. Approaching biochar derived from coffee grounds would be a promising eco-friendly solution because it utilizes solid waste, saves costs, and creates adsorbents to deal with emerging pollutants like antibiotics.
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•Norfloxacin was removed using biochar derived from spent coffee grounds (SCGB).•pH significantly influenced the Norfloxacin (NOR) adsorption of the SCGB.•Based on Langmuir model, the maximum absorption capacity was 69.8 mg g−1 at pH 6.•The adsorption process was optimized by using the response surface methodology.•Optimal adsorption conditions were achieved at pH of 6.26 and SCGB of 1.32 g L−1.
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•The SCG derived biochars pyrolyzed at 300 and 500 °C had the lowest PAHs levels.•The PAHs levels in all biochars and pyrolysis oil met the related regulations.•The SCG 500 showed the ...highest tetracycline adsorption capacity.•pH affected tetracycline adsorption.•Surface interactions were major adsorption reactions.
The main objective of this study was to evaluate the effect of different pyrolysis temperatures on the formation of polycyclicaromatichydrocarbons (PAHs) in biochar originated spent coffee ground (SCG) and the tetracycline (TC) adsorption behavior of biochar in water. The results showed that biochar synthesized at 500 °C (SCG 500) contained low PAHs (600 µg kg−1) and the highest TC adsorption efficiency. In addition, the characteristics, influencing factors on TC adsorption, and the related mechanisms of SCG 500 were comprehensively investigated. The results showed that the highest efficiency was observed at pH of 7 and the presence of ions in salinity solution reduced the adsorption capacity of SCG 500. The electrostatic interaction, hydrogen bonding, and π-EDA were the major adsorption mechanisms. Safety PAHs level, low-cost, widely material sources and high TC removal capacity suggested that SCG 500 was a promising environmentally friendly effective absorbent.
In this work, we proposed a facile approach to fabricate a superhydrophobic surface for anti-icing performance in terms of adhesive strength and freezing time. A hierarchical structure was generated ...on as-received Al plates using a wet etching method and followed with a low energy chemical compound coating. Surfaces after treatment exhibited the great water repellent properties with a high contact angle and extremely low sliding angle. An anti-icing investigation was carried out by using a custom-built apparatus and demonstrated the expected low adhesion and freezing time for icephobic applications. In addition, we proposed a model for calculating the freezing time. The experimented results were compared with theoretical calculation and demonstrated the good agreement, illustrating the importance of theoretical contribution in design icephobic surfaces. Therefore, this study provides a guideline for the understanding of icing phenomena and designing of icephobic surfaces.
The occurrence of arsenic (As) in groundwater (drilled well water) that were used for drinking, cooking, and personal hygiene and its risks to human health in Long An and Tien Giang provinces (Mekong ...delta, Vietnam) were evaluated in this study. The average As concentrations were 15.92 ± 11.4 μg/L (
n
= 24, Long An) and 4.95 ± 4.7 μg/L (
n
= 24, Tien Giang). The average concentrations of As in Long An had not reached the WHO and QCVN 01: 2009/BYT healthy drinking water standard (10 μg/L). When used as a source of water for drinking and daily activities, arsenic-contaminated groundwater may have a direct impact on human health. The risk assessment from groundwater established by the US Environmental Protection Agency (USEPA) was conducted. The risk assessment showed that the average cancer risk (CR) values were 8.68 × 10
−4
(adults) and 2.39 × 10
−3
(children) for Long An, and 2.70 × 10
−4
(adults) and 7.43 × 10
−4
(children) for Tien Giang. These results were significantly higher than the CR (1 × 10
−4
) proposed by the USEPA. The adverse health effect was therefore specifically warned by the use of arsenic-contaminated groundwater. This research offers valuable knowledge for efficient water management approaches to guarantee local communities’ health protection.
For years, agrochemical fertilizers have been used in agriculture for crop production. However, intensive utilization of chemical fertilizers is not an ecological and environmental choice since they ...are destroying soil health and causing an emerging threat to agricultural production on a global scale. Under the circumstances of the increasing utilization of chemical fertilizers, cultivating microalgae to produce biofertilizers would be a wise solution since desired environmental targets will be obtained including (1) replacing chemical fertilizer while improving crop yields and soil health; (2) reducing the harvest of non-renewable elements from limited natural resources for chemical fertilizers production, and (3) mitigating negative influences of climate change through CO2 capture through microalgae cultivation. Recent improvements in microalgae-derived-biofertilizer-applied agriculture will be summarized in this review article. At last, the recent challenges of applying biofertilizers will be discussed as well as the perspective regarding the concept of circular bio-economy and sustainable development goals (SDGs).
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•Microalgae-based biofertilizer is an alternative solution to sustainable agriculture.•Microalgae-based biofertilizer could enhance the crop productivity and soil quality.•CO2 capture could be solved through microalgae-based application processes.•The production cost of a large-scale biofertilizer should be considered.
Biochar usage in soil remediation has turned out to be an enticing topic recently. Biochar, a product formed by pyrolysis of organic waste, which is rich in carbon, has the aptitude to ameliorate ...climate change by sequestering carbon while also enhancing soil quality and crop yields. Two-edged implications of biochar on soil amendment are still being discussed yet, clarity on the long-term implications of biochar on soil health and the environment is not yet achieved. As a result, it is crucial to systematically uncover the pertinent information regarding biochar remediation, as this can serve as a roadmap for future research on using biochar to remediate contaminated soils in mining regions. This review endeavors to bring forth run thoroughly the latest state of research on the use of biochar in soil remediation, along with its potential benefits, limitations, challenges, and future scope. By synthesizing existing literature on biochar soil remediation, this review aims to provide insights into the potential of biochar as a sustainable solution for soil remediation. Specifically, this review will highlight the key factors that influence the effectiveness of biochar for soil remediation and the potential risks associated with its use, as well as the current gaps in knowledge and future research directions.
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•Biochar has a positive impact on soil remediation and carbon sequestration.•Biochar effectively remediate both organic and inorganic pollutants in soil.•Biochar efficacy in soil remediation depends on its properties and soil type.•Biochar for remediation is promising but requires case-specific risk evaluation.
Due to global demand, millions of tons of plastics have been widely consumed, resulting in the widespread entry of vast amounts of microplastic particles into the environment. The presence of ...microplastics (MPs) in water supplies, including bottled water, has undergone systematic review, assessing the potential impacts of MPs on humans through exposure assessment. The main challenges associated with current technologies lie in their ability to effectively treat and completely remove MPs from drinking and supply water. While the risks posed by MPs upon entering the human body have not yet been fully revealed, there is a predicted certainty of negative impacts. This review encompasses a range of current technologies, spanning from basic to advanced treatments and varying in scale. However, given the frequent detection of MPs in drinking and bottled water, it becomes imperative to implement comprehensive management strategies to address this issue effectively. Consequently, integrating current technologies with management options such as life-cycle assessment, circular economy principles, and machine learning is crucial to eliminating this pervasive problem.
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•A range of current technologies from basic to advanced treatments were examined.•Life-cycle assessment and circular economy were integrated with current technologies.•This review delved into the presence of microplastics (MPs) in water supply sources.•Potential adverse effects of MPs on human health were limited in literature review.•It is urgent for an enhanced comprehension of the potential health hazards.
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