Human memory, as a product of the mind and brain, is inherently private and personal. Yet, arising from the interaction between the organism and its ecology in the course of phylogeny and ontogeny, ...human memory is also profoundly collective and cultural. In this review, I discuss the cultural foundation of human memory. I start by briefly reflecting on the conception of memory against a historical and cultural background. I then detail a model of a culturally saturated mnemonic system in which cultural elements constitute and condition various processes of remembering, focusing on memory representation, perceptual encoding, memory function, memory reconstruction, memory expression, and memory socialization. Then I discuss research on working memory, episodic memory, and autobiographical memory as examples that further demonstrate how cultural elements shape the processes and consequences of remembering and lay the foundation for human memory. I conclude by outlining some important future directions in memory research.
Detecting emerging research topics is essential, not only for research agencies but also for individual researchers. Previous studies have created various bibliographic indicators for the ...identification of emerging research topics. However, as indicated by Rotolo et al. (Research Policy 44, 1827–1843, ), the most serious problems are the lack of an acknowledged definition of emergence and incomplete elaboration of the linkages between the definitions that are used and the indicators that are created. With these issues in mind, this study first adjusts the definition of an emerging technology that Rotolo et al. () have proposed to accommodate the analysis. Next, a set of criteria for the identification of emerging topics is proposed according to the adjusted definition and attributes of emergence. Using two sets of parameter values, several emerging research topics are identified. Finally, evaluation tests are conducted by demonstration of the proposed approach and comparison with previous studies. The strength of the present methodology lies in the fact that it is fully transparent, straightforward, and flexible.
Information encryption has become increasingly important in recent years; however, information encryption materials, especially those encrypting on a time scale, are still in fancy. Herein, a ...“time‐lock” information encryption material is developed based on a time‐dependent fluorescent hydrogel. The fluorescence color of this hydrogel can be regulated between green and yellow, with distinctive changes in intensity, on a time scale by controlling the concentration of urea/urease and HCl. By taking advantage of this feature, “time‐locked” information can be encoded. Such information self‐erases with time, and moreover, fake or even opposing information is generated during this process. The correct information can only be recognized at a specified time, i.e., using a “time‐key” to decrypt the information. This time‐dependent feature endows the material with a higher level of security and provides new insight for information encryption.
A time‐dependent fluorescent hydrogel driven by the hydrolysis of urea is developed to achieve information encryption. Information is encoded in this material that self‐erased with time, and moreover, false information is generated during the erasing process. The correct information can only be recognized at a specific time.
Although multifunctional, flexible, and wearable textiles with integrated smart electronics have attracted tremendous attention in recent years, it is still an issue to balance new functionalities ...with the inherent performances of the textile substrates. 2D early transition metal carbides/nitrides (MXenes) are considered as ideal nanosheets for fabricating multifunctional and flexible textiles on the basis of their superb intrinsic electrical conductivity, tunable surface chemistry, and layered structure. Herein, highly conductive and hydrophobic textiles with exceptional electromagnetic interference (EMI) shielding efficiency and excellent Joule heating performance are fabricated by depositing in situ polymerized polypyrrole (PPy) modified MXene sheets onto poly(ethylene terephthalate) textiles followed by a silicone coating. The resultant multifunctional textile exhibits high electrical conductivity of ≈1000 S m−1 in conjunction with an exceptional EMI shielding efficiency of ≈90 dB at a thickness of 1.3 mm. The thin silicone coating renders the hydrophilic PPy/MXene‐decorated textile hydrophobic, leading to an excellent water‐resistant feature while retaining a satisfactory air permeability of the textile. Interestingly, the multifunctional textile also exhibits an excellent moderate voltage‐driven Joule heating performance. Thus, the deposition of PPy‐modified MXene followed by silicone coating creates a multifunctional textile that holds great promise for wearable intelligent garments, EMI shielding, and personal heating applications.
An efficient and scalable dip‐coating approach for the fabrication of flexible multifunctional transition metal carbides/nitrides (MXenes)‐derived textiles by decorating polypyrrole‐modified MXene sheets onto polyethylene terephthalate textiles followed by silicone coating is reported. The highly conductive and hydrophobic textiles show exceptional electromagnetic interference shielding efficiency, outstanding water‐resistant feature, and excellent Joule heating performances.
Although flexible and multifunctional textiles are promising for wearable electronics and portable device applications, the main issue is to endow textiles with multifunctionalities while maintaining ...their innate flexible and porous features. Herein, a vacuum‐assisted layer‐by‐layer assembly technique is demonstrated to conformally deposit electrically conductive substances on textiles for developing multifunctional and flexible textiles with superb electromagnetic interference (EMI) shielding performances, superhydrophobicity, and highly sensitive humidity response. The formed leaf‐like nanostructure is composed of silver nanowires (AgNWs) as the highly conductive skeleton (vein) and transition metal carbide/carbonitride (MXene) nanosheets as the lamina. The presence of MXene protects AgNWs from oxidation and enhances the combination of AgNWs with the fabric substrate, and the transformation of its functional groups leads to self‐derived hydrophobicity. The flexible and multifunctional textile exhibits a low sheet resistance of 0.8 Ω sq−1, outstanding EMI shielding efficiency of 54 dB in the X‐band at a small thickness of 120 µm, and highly sensitive humidity responses, while retaining its satisfactory porosity and permeability. The self‐derived hydrophobicity with a large contact angle of >140° is achieved by aging the hydrophilic MXene coated silk. The wearable multifunctional textiles are highly promising for applications in intelligent garments, humidity sensors, actuators, and EMI shielding.
A biomimetic leaf‐like nanostructure composed of a 1D AgNWs skeleton (vein) and 2D MXene as the lamina is fabricated via vacuum‐assisted layer‐by‐layer assembly for electromagnetic interference (EMI) shielding, humidity monitoring, and self‐derived hydrophobicity. The (MA1)10 silk presents an exceptional EMI shielding effectiveness of ≈90 dB at 12.4 GHz at a thickness of 480 µm, and the MXene‐coated textile induces a hydrophilic‐to‐hydrophobic transition, generating a large contact angle of >140°.
Recent years have witnessed the explosive development of electronic skin. Highly sensitive pressure sensing is one of the primary abilities of electronic skin. To date, most of the reported skin‐like ...pressure sensors are based on nanomaterials and microstructured polydimethylsiloxane (PDMS) films, limiting their wide practical applications due to the unknown biotoxicity and the redundant fabrication procedure. A cost‐effective, large‐area‐capable, and biocompatible approach for fabrication of high‐performance skin‐like pressure sensors is highly desired. Silk fibroin (SF) is a natural protein that has recently drawn great attention due to its application as the substrate for flexible electronics. Here, the fabrication of skin‐like pressure sensors is demonstrated using SF‐derived active materials. Flexible and conformal pressure sensors can be fabricated using transparent carbonized silk nanofiber membranes (CSilkNM) and unstructured PDMS films through a cost‐effective and large‐scale capable approach. Due to the unique N‐doped carbon nanofiber network structure of CSilkNM, the obtained pressure sensor shows superior performance, including ultrahigh sensitivity (34.47 kPa−1) for a broad pressure range, an ultralow detection limit (0.8 Pa), rapid response time (<16.7 ms), and high durability (>10 000 cycles). Based on its superior performance, its applications in monitoring human physiological signals, sensing subtle touch, and detecting spatial distribution of pressure are demonstrated.
Using carbonized electrospun silk nanofiber membranes and planar polydimethylsiloxane films, a skin‐like ultrasensitive pressure sensor is fabricated. The sensor shows superior performance, including high sensitivity (34.47 kPa−1), an ultralow detection limit (0.8 Pa), fast response time (<16.7 ms), and high stability and durability (>10 000 cycles), enabling its wide application in real‐time biomedical monitoring and smart equipment.
Psychological health problems, especially emotional disorders, are common among adolescents. The epidemiology of emotional disorders is greatly influenced by stressful events. This study sought to ...assess the prevalence rate and socio-demographic correlates of depressive and anxiety symptoms among Chinese adolescents affected by the outbreak of COVID-19. We conducted a cross-sectional study among Chinese students aged 12–18 years during the COVID-19 epidemic period. An online survey was used to conduct rapid assessment. A total of 8079 participants were involved in the study. An online survey was used to collect demographic data, assess students’ awareness of COVID-19, and assess depressive and anxiety symptoms with the Patient Health Questionnaire (PHQ-9) and the Generalized Anxiety Disorder (GAD-7) questionnaire, respectively. The prevalence of depressive symptoms, anxiety symptoms, and a combination of depressive and anxiety symptoms was 43.7%, 37.4%, and 31.3%, respectively, among Chinese high school students during the COVID-19 outbreak. Multivariable logistic regression analysis revealed that female gender was the higher risk factor for depressive and anxiety symptoms. In terms of grades, senior high school was a risk factor for depressive and anxiety symptoms; the higher the grade, the greater the prevalence of depressive and anxiety symptoms. Our findings show there is a high prevalence of psychological health problems among adolescents, which are negatively associated with the level of awareness of COVID-19. These findings suggest that the government needs to pay more attention to psychological health among adolescents while combating COVID-19.
The electrochemical nitrogen reduction reaction (NRR) offers an energy‐saving and environmentally friendly approach to produce ammonia under ambient conditions. However, traditional catalysts have ...extremely poor NRR performances because of their low activity and the competitive hydrogen evolution reaction. The high catalytic activity of nanoporous gold (NPG) and the hydrophobicity and molecular concentrating effect of the zeolitic imidazolate framework‐8 (ZIF‐8) were incorporated in the NPG@ZIF‐8 nanocomposite so that the ZIF‐8 shell could weaken hydrogen evolution and retard reactant diffusion. A highest Faradaic efficiency of 44 % and an excellent rate of ammonia production of (28.7±0.9) μg h−1 cm−2 were achieved, which are superior to traditional gold nanoparticles and NPG. Moreover, the composite catalyst shows high electrochemical stability and selectivity (98 %). The superior NRR performance makes NPG@ZIF‐8 one of the most promising water‐based NRR electrocatalysts for ammonia production.
Being efficient: A core–shell structure composite of nanoporous gold embedded in a ZIF‐8 shell has been developed. The high catalytic activity of the nanoporous gold and the hydrophobic porous shell of ZIF‐8 results in a superior enhancement of electrochemical nitrogen fixation compared to traditional electrocatalysts, as shown by a Faradaic efficiency of 44 % (see picture, scale bar: 300 nm).
Exploiting anion–π interactions in catalyst design is a fascinating direction to develop new and fundamental catalysis. For the appealing yet flexible π‐face activation, can two or more π‐acidic ...surfaces be manipulated for cooperative activation to achieve efficient transformation and particularly selectivity control is highly desirable. Here, we demonstrate a supramolecular π‐catalysis strategy by establishing cooperative π‐face activation in a confined electron‐deficient cage cavity. The catalysts have a triazine based prism‐like cage core and pendant chiral base sites. Only 2 mol % of cage catalyst efficiently catalyzed the decarboxylate Mannich reactions of sulfamate‐headed cyclic aldimines and a series of malonic acid half thioesters in nearly quantitative yields and up to 97 % ee, enabling an unprecedent organocatalytic approach. The supramolecular π‐cavity is essential in harnessing cooperative anion–π interactions for the efficient activation and excellent selectivity control.
A strategy by building cooperative anion–π interactions in a confined cage cavity to drive efficient and selective catalysis was established. Only 2 mol % of easily made chiral cages enabled excellent conversions and up to 97 % ee in catalyzing a class of decarboxylate Mannich reactions, which was unrealized with conventional organocatalysts.
Change detection (CD) is an important application of remote sensing, which provides timely change information about large-scale Earth surface. With the emergence of hyperspectral imagery, CD ...technology has been greatly promoted, as hyperspectral data with high spectral resolution are capable of detecting finer changes than using the traditional multispectral imagery. Nevertheless, the high dimension of the hyperspectral data makes it difficult to implement traditional CD algorithms. Besides, endmember abundance information at subpixel level is often not fully utilized. In order to better handle high-dimension problem and explore abundance information, this paper presents a general end-to-end 2-D convolutional neural network (CNN) framework for hyperspectral image CD (HSI-CD). The main contributions of this paper are threefold: 1) mixed-affinity matrix that integrates subpixel representation is introduced to mine more cross-channel gradient features and fuse multisource information; 2) 2-D CNN is designed to learn the discriminative features effectively from the multisource data at a higher level and enhance the generalization ability of the proposed CD algorithm; and 3) the new HSI-CD data set is designed for objective comparison of different methods. Experimental results on real hyperspectral data sets demonstrate that the proposed method outperforms most of the state of the arts.