MBene, a layered metal boride similar to MXene, has garnered significant attention in recent times. Nevertheless, there is still a lack of comprehensive understanding regarding their structure and properties, necessitating further research and investigation. In this study, theoretical calculations were employed first to study the binding energy, band structures and density of states of three MBenes, namely MoB, MgB2, and ZrB2, providing insights into their electronic characteristics. In addition, open circuit voltage (OCV) and adsorption energy were also conducted using the three MBenes as cathode materials for zinc ion batteries, indicating their low ion migration barrier and potential in energy storage application. Subsequently, MoB, MgB2, and ZrB2 were experimentally synthesized using etching or exfoliation method and utilized as cathode materials for zinc ion batteries. Results demonstrates that the specific capacity of MoB is 60 mAh g-1 at 0.1 A g-1. Systematic investigation including kinetics simulation and ex situ XRD suggests the cation insertion mechanism of the MoB electrodes. Building upon these findings, attempts were made to enhance the performance of MoB through the incorporation of 1 T-MoS2 composites, urea molecular intercalation. Notably, the modified composite exhibited a specific capacity exceeding 150 mAh g-1 at 0.1 A g-1, with a stable Coulombic efficiency of 100% after 100 cycles. This study provides novel directions and insights for the research of MBene in the context of aqueous zinc-ion batteries. Display omitted •Theoretical calculations indicate the low ion migration barrier of MBenes.•MoB, MgB2, and ZrB2 were synthesized and utilized as cathode materials.•Ex-situ XRD and kinetic simulations indicate the Zn2+ insertion mechanism of MoB.•Performance is enhanced via urea intercalation and 1 T-MoS2 composites.