Aza‐Michael addition of 1,2‐diazoles to structurally diverse enones: Efficient methods toward β‐amino ketones

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Aza‐Michael addition of 1,2‐diazoles to structurally diverse enones: Efficient methods toward β‐amino ketones

Polina, Saibabu; Putta, V. P. Rama Kishore; Gujjarappa, Raghuram; Pujar, Prasad Pralhad; Malakar, Chandi C.

Journal of heterocyclic chemistry, April 2021, 2021-04-00, 20210401, Volume: 58, Issue: 4

Journal Article

An efficient and mild protocol was realized using 1,2‐diazoles and related heterocycles with cyclic and acyclic enones in presence of T3P (2,4,6‐tripropyl‐1,3,5,2,4,6‐trioxatriphosphorinane‐2,4,6‐trioxide) toward the regioselective formation of N‐cycloalkyl heterocycles at room temperature. The developed reaction conditions showcased good selectivity over a wide range of 1,2‐diazoles and enones by delivering N‐cycloalkyl heterocycles in excellent yields.

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Polina, Saibabu | Putta, V. P. Rama Kishore | Gujjarappa, Raghuram | Pujar, Prasad Pralhad | Malakar, Chandi C.

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