Embedded in a theoretically founded process model (termed Dynamics of Motive Satisfaction, ‘DynaMoS’), the present study examined the links between the implicit dispositional communion motive, everyday motivational dynamics, and relationship outcomes in couples. Within‐subject processes are proposed to explain between‐subject associations of dispositional motives and relationship satisfaction. For an empirical test of the model, data on the dispositional partner‐related need for communion and global relationship satisfaction were obtained from 152 individuals in heterosexual relationships. In an extensive experience sampling spanning 2 weeks, a subsample of 130 individuals answered questions about their current motivational states, mood, state relationship satisfaction, and experiences with their partner five times a day. The results were largely consistent with the DynaMoS model: (1) individuals with a strong dispositional implicit communion motive reported more often to be in a communal motivational state; (2) communally motivated individuals were more likely to engage in subsequent instrumental behaviour; and (3) relationship experiences that potentially satisfy communion motivation led to more positive relationship outcomes when individuals were motivated before compared with when they were not. It is discussed how these results and the experience sampling method can foster our understanding of how dispositional characteristics translate into everyday processes and shape relationship outcomes. Copyright © 2018 European Association of Personality Psychology