E-resources
Peer reviewed
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Vodnala, Nagaraju; Kaldhi, Dhananjaya; Polina, Saibabu; Putta, V.P. Rama Kishore; Gupta, Richa; Promily, S.C. Pinky; Linthoinganbi, R.K.; Singh, Virender; Malakar, Chandi C.
Tetrahedron letters, 12/2016, Volume: 57, Issue: 50Journal Article
Display omitted •Rarely explored substrates have been investigated towards saturated N-heterocycles.•Developed method exclude the use of P(III) reagents for reductive cyclization.•Alternate source of molecular carbon monoxide has been used as sole reducing agent. Using Pd/HCOOCs as a surrogate reagents synthesis of saturated N-heterocycles was described from nitroaromatics as starting materials. The developed new reaction conditions exclude the generally used toxic reagents like carbon monoxide as deoxygenative agent. The developed protocol permits the synthesis privileged bioactive N-heterocyclic scaffolds in good yields and selectivity.
