Emerging concern regarding the remediation of environmental pollution has expanded tremendously in recent years. Pharmaceutical industries and agricultural sectors release an enormous amount of residues containing toxic pollutants at trace levels which poses a serious impact on the environment and human health. To cope with the effect of hazardous and toxic contaminants, numerous methodologies have been developed for the treatment of effluents released from the agrochemical and pharmaceutical industries. Amongst them, photocatalysis has gained much more attention for the degradation of pollutants due to its low cost, higher capability, green and eco-friendly approaches. Photocatalysts are the substrate that plays a key role in pollutant removal through photocatalysis by accelerating the necessary chemical reactions using a light source. In this review, the recent progress on photocatalysis and its fundamental mechanism in agrochemicals and pharmaceutical pollutant degradation was summarized. This review concisely discusses the incorporation of various metal oxides and nanomaterials into semiconductors for the effective degradation of contaminants. The current status and future research on different sectors and the difficulties in the photocatalytic removal of agrochemical and pharmaceutical pollutants are also reviewed in detail.