Synthesis of monodisperse Ce^sub x^Zr^sub 1-x^O2 nanocrystals and the size-dependent enhancement of their properties

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Synthesis of monodisperse Ce^sub x^Zr^sub 1-x^O2 nanocrystals and the size-dependent enhancement of their properties

Zhang, Yuewei; Wen, Jing; Wang, Jun; Pan, Daocheng; Shen, Meiqing; Lu, Yunfeng

Nano research, 05/2011, Volume: 4, Issue: 5

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Monodisperse Ce^sub 1-x^Zr^sub x^O2 nanocrystals have been synthesized using a simple two-phase approach; adjusting the ratio of precursors used, amount of capping agent used, reaction time and temperature affords precise control over their composition, structure and size. Size-dependent enhancement of oxygen-storage capacity and kinetics of oxygen storage and release were observed. Systematic studies were conducted in order to understand the size-dependent enhancement of these properties. This work provides important insights into the synthesis and fundamental understanding of multi-component nanocrystals with a large variety of applications.PUBLICATION ABSTRACT

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