E-resources
Peer reviewed
-
Rai, Dhanpat; Yui, Mikazu; Kitamura, Akira; Yoshikawa, Hideki; Felmy, A
Journal of solution chemistry, 08/2013, Volume: 42, Issue: 7Journal Article
The major objective of this study, based on critical review and experimental studies, was to develop a reliable thermodynamic model for the NdaF system at 25 degree C. The SIT model was used to convert concentration constants reported in the literature to constants at zero ionic strengths for cross comparison and selection of reliable values. The critically evaluated thermodynamic constants for the formation of NdF2+ and NdF 2 + were then used to interpret the extensive NdF3(cr) solubility data in NaF and NH4F solutions, ranging in concentrations from extremely low values to as high as 1.0 molADTkga1, equilibrated for different periods ranging up to as long as 72 days. These efforts have resulted in $ \log_{10} \beta_{n}0} $ log 10 I2 n 0 for the reaction Nd3+ + nFa a NdF n 3an of (3.81 A- 0.10), (5.89 A- 0.77), and <12.48 for n values of 1a3, respectively. The $ \log_{10} K_{\text{sp}}0} $ log 10 K sp 0 for the solubility of NdF3(cr) (NdF3(cr) a Nd3+ + 3Fa) was determined to be (a20.49 A- 0.37). Because (1) Nd is an excellent analog for trivalent actinidesaAn(III) (i.e., Pu(III), Am(III), and Cm(III)), and (2) the available data for the An(III)aF system, especially the solubility products of AnF3(cr), are of extremely poor quality, the critical literature review in combination with the experimental NdaF system data have been used to assign thermodynamic constants for the An(III)aF reactions until good quality specific data for them becomes available.
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.