ABSTRACT We report the first detection in the interstellar medium (ISM) of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of ...Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Centre quiescent molecular cloud G + 0.693. The Z-isomer has a column density of (2.0 ± 0.6) × 1014 cm−2 and an abundance of 1.5 × 10−9. The relative abundance ratio between the isomers is Z/E∼6. This value cannot be explained by the two chemical formation routes previously proposed (gas phase and grain surface), which predicts abundances ratios between 0.9 and 1.5. The observed Z/E ratio is in good agreement with thermodynamic equilibrium at the gas kinetic temperature (130−210 K). Since isomerization is not possible in the ISM, the two species may be formed at high temperature. New chemical models, including surface chemistry on dust grains and gas-phase reactions, should be explored to explain our findings. Whatever the formation mechanism, the high abundance of Z-HNCHCN shows that precursors of adenine are efficiently formed in the ISM.
ABSTRACT
We present SiO J = 2–1 maps of the Sgr B2 molecular cloud, which show shocked gas with a turbulent substructure comprising at least three cavities at velocities of $10,40\, \rm km\, s^{-1}$ ...and an arc at velocities of $-20,10\, \rm km\, s^{-1}$. The spatial anticorrelation of shocked gas at low and high velocities, and the presence of bridging features in position-velocity diagrams suggest that these structures formed in a cloud–cloud collision. Some of the known compact H ii regions spatially overlap with sites of strong SiO emission at velocities of $40,85\, \rm km\, s^{-1}$, and are between or along the edges of SiO gas features at $100,120\, \rm km\, s^{-1}$, suggesting that the stars responsible for ionizing the compact H ii regions formed in compressed gas due to this collision. We find gas densities and kinetic temperatures of the order of $n_{\rm H_2}\sim 10^5\, \rm cm^{-3}$ and $\sim 30\, \rm K$, respectively, towards three positions of Sgr B2. The average values of the SiO relative abundances, integrated line intensities, and line widths are ∼10−9, $\sim 11\, \rm K\, km\, s^{-1}$, and $\sim 31\, \rm km\, s^{-1}$, respectively. These values agree with those obtained with chemical models that mimic grain sputtering by C-type shocks. A comparison of our observations with hydrodynamical simulations shows that a cloud–cloud collision that took place $\lesssim 0.5\, \rm Myr$ ago can explain the density distribution with a mean column density of $\bar{N}_{\rm H_2}\gtrsim 5\times 10^{22}\, \rm cm^{-2}$, and the morphology and kinematics of shocked gas in different velocity channels. Colliding clouds are efficient at producing internal shocks with velocities $\sim 5\!-\!50\, \rm km\, s^{-1}$. High-velocity shocks are produced during the early stages of the collision and can readily ignite star formation, while moderate- and low-velocity shocks are important over longer time-scales and can explain the widespread SiO emission in Sgr B2.
Broad-line region clouds orbiting an AGN sample Armijos-Abendaño, J; López, E; Llerena, M ...
Monthly Notices of the Royal Astronomical Society,
07/2022, Letnik:
514, Številka:
1
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ABSTRACT
We present a spectral and temporal analysis of XMM–Newton data from a sample of six galaxies (NGC 3783, Mrk 279, Mrk 766, NGC 3227, NGC 7314, and NGC 3516). Using the hardness-ratio curves, ...we identify time intervals in which clouds are eclipsing the central X-ray source in five of the six sources. We detect three occultations in NGC 3227 and one occultation in NGC 3783, NGC 7314, and NGC 3516, together with the well-known occultations in Mrk 766. We estimate the physical properties of the eclipsing clouds. The derived physical size of the X-ray sources (∼(3–28) × 1013 cm) is less than that of the eclipsing clouds with column densities of ∼1022–1023 cm−2, thus a single cloud may block the X-ray source, leading to notorious temporal variability of the X-ray flux. The eclipsing clouds in Mrk 766, NGC 3227, NGC 7314, and NGC 3516 with distances from the X-ray source of ∼(0.3–3.6) $\times 10^4\, R_\mathrm{ g}$ are moving at Keplerian velocities >1122 km s−1, typical parameters of broad-line region clouds, while the eclipsing cloud in NGC 3783 is likely located in the dusty torus. We also find a good anticorrelation with a slope of −187 ± 62 between the known masses of the supermassive black hole in the centre of the galaxies with the equivalent width (EW) of the 6.4 keV Fe line for the five type 1 Seyfert galaxies of our sample, while the type 2 Seyfert galaxy NGC 7314 shows an average EW value of 100 ± 11 eV inconsistent with the above anticorrelation.
The lines of HOC+, HCO, and CO+ are considered good tracers of photon-dominated regions (PDRs) and X-ray-dominated regions. We study these tracers toward regions of the Sgr B2 cloud selected to be ...affected by different heating mechanisms. We find the lowest values of the column density ratios of HCO+ versus HOC+, HCO, and CO+ in dense H ii gas, where UV photons dominate the heating and chemistry of the gas. The HOC+, HCO, and CO+ abundances and the above ratios are compared with those of chemical modeling, finding that high-temperature chemistry, a cosmic-ray ionization rate of 10−16 s−1, and timescales >105.0 yr explain well the HOC+ abundances in quiescent Sgr B2 regions, while shocks are also needed to explain the highest HCO abundances derived for these regions. The CO+ is mainly formed in PDRs, since the highest CO+ abundances of ∼(6-10) × 10−10 are found in H ii regions with electron densities >540 cm−3 and CO+ emission is undetected in quiescent gas. Among the ratios, the HCO+/HCO ratio is sensitive to the electron density, as it shows different values in dense and diffuse H ii regions. We compare SiO J = 2-1 emission maps of Sgr B2 with X-ray maps from 2004 and 2012. One known spot shown on the 2012 X-ray map is likely associated with molecular gas at velocities of 15-25 km s−1. We also derive the X-ray ionization rate of ∼10−19 s−1 for Sgr B2 regions pervaded by X-rays in 2004, which is quite low to affect the chemistry of the molecular gas.
Phosphorus-bearing molecules in the Galactic Center Rivilla, V M; Jiménez-Serra, I; Zeng, S ...
Monthly Notices of the Royal Astronomical Society Letters,
03/2018, Letnik:
475, Številka:
1
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Abstract
Phosphorus (P) is one of the essential elements for life due to its central role in biochemical processes. Recent searches have shown that P-bearing molecules (in particular PN and PO) are ...present in star-forming regions, although their formation routes remain poorly understood. In this letter, we report observations of PN and PO towards seven molecular clouds located in the Galactic Center, which are characterized by different types of chemistry. PN is detected in five out of seven sources, whose chemistry is thought to be shock-dominated. The two sources with PN non-detections correspond to clouds exposed to intense UV/X-rays/cosmic ray (CR) radiation. PO is detected only towards the cloud G+0.693−0.03, with a PO/PN abundance ratio of ∼1.5. We conclude that P-bearing molecules likely form in shocked gas as a result of dust grain sputtering, while are destroyed by intense UV/X-ray/CR radiation.
We present the results of two Mopra 3-mm spectral line surveys of the lines of sight (LOS) towards the Galactic Centre (GC) molecular complexes Sgr B2 (LOS+0.693) and Sgr A (LOS-0.11). The spectra ...covered the frequency ranges of similar to 77-93 GHz and similar to 105-113 GHz. We have detected 38 molecular species and 25 isotopologues. The isotopic ratios derived from column density ratios are consistent with the canonical values, indicating that chemical isotopic fractionation and/or selective photodissociation can be considered negligible (<10 per cent) for the GC physical conditions. The derived abundances and rotational temperatures are very similar for both LOSs, indicating very similar chemical and excitation conditions for the molecular gas in the GC. The excitation conditions are also very similar to those found for the nucleus of the starburst galaxy NGC 253. We report for the first time the detection of HCO and HOC+ emission in LOS+0.693. Our comparison of the abundance ratios between CS, HCO, HOC+ and HCO+ found in the two LOSs with those in typical Galactic photodissociation regions (PDRs) and starbursts galaxies does not show any clear trend to distinguish between ultraviolet- and X-ray-induced chemistries. We propose that the CS/HOC+ ratio could be used as a tracer of the PDR components in the molecular clouds in the nuclei of galaxies.
Aims. We study the spatial distribution and kinematics of water emission in a ~8 × 8 pc2 region of the Galactic center (GC) that covers the main molecular features around the supermassive black hole ...Sagittarius A* (Sgr A*). We also analyze the water excitation to derive the physical conditions and water abundances in the circumnuclear disk (CND) and the “quiescent clouds”. Methods. We presented the integrated line intensity maps of the ortho 110 − 101, and para 202 − 111 and 111 − 000 water transitions observed using the On the Fly mapping mode with the Heterodyne Instrument for the Far Infrared (HIFI) on board Herschel. To study the water excitation, we used HIFI observations of the ground state ortho and para H 218 $_2^{18}$ 218 O transitions toward three selected positions in the vicinity of Sgr A*. In our study, we also used dust continuum measurements of the CND, obtained with the Spectral and Photometric Imaging REceiver (SPIRE) instrument. Using a non-local thermodynamical equilibrium (LTE) radiative transfer code, the water line profiles and dust continuum were modeled, deriving H2O abundances ( XH2O $X_{\textrm{H}_2\textrm{O}}$XH2O ), turbulent velocities (V t), and dust temperatures (Td). We also used a rotating ring model to reproduce the CND kinematics represented by the position velocity (PV) diagram derived from para 202 − 111 H2O lines. Results. In our H2O maps we identify the emission associated with known features around Sgr A*: CND, the Western Streamer, and the 20 and 50 km s−1 clouds. The ground-state ortho water maps show absorption structures in the velocity range of −220,10 km s−1 associated with foreground sources. The PV diagram reveals that the 202 − 111 H2O emission traces the CND also observed in other high-dipole molecules such as SiO, HCN, and CN. Using the non-LTE code, we derive high XH2O $X_{\textrm{H}_2\textrm{O}}$XH2O of ~(0.1–1.3) × 10−5, V t of 14–23 km s−1 , and Td of 15–45 K for the CND, and the lower XH2O $X_{\textrm{H}_2\textrm{O}}$XH2O of 4 × 10−8 and V t of 9 km s−1 for the 20 km s−1 cloud. Collisional excitation and dust effects are responsible for the water excitation in the southwest lobe of the CND and the 20 km s−1 cloud, whereas only collisions can account for the water excitation in the northeast lobe of the CND. We propose that the water vapor in the CND is produced by grain sputtering by shocks of 10–20 km s−1, with some contribution of high temperature and cosmic-ray chemistries plus a photon-dominated region chemistry, whereas the low XH2O $X_{\textrm{H}_2\textrm{O}}$XH2O derived for the 20 km s−1 cloud could be partially a consequence of the water freeze-out on grains.
Aims. We aim to better understand the imprints that the nuclear activity in galaxies leaves in the molecular gas. Methods. We used the IRAM 30 m telescope to observe the frequency range ~86−116 GHz ...towards the central regions of the starburst galaxies M 83, M 82, and NGC 253, the galaxies hosting an active galactic nucleus (AGN) M 51, NGC 1068, and NGC 7469, and the ultra-luminous infrared galaxies (ULIRGs) Arp 220 and Mrk 231. Assuming local thermodynamic equilibrium (LTE), we calculated the column densities of 27 molecules and 10 isotopologues (or their upper limits in case of non-detections). Results. Among others, we report the first tentative detections of CH3CHO, HNCO, and NS in M 82 and, for the first time in the extragalactic medium, HC5N in NGC 253. Hα recombination lines were only found in M 82 and NGC 253. Vibrationally excited lines of HC3N were only detected in Arp 220. CH3CCH emission is only seen in the starburst-dominated galaxies. By comparison of the fractional abundances among the galaxies, we looked for the molecules that are best suited to characterise the chemistry of each group of galaxies (starbursts, AGNs and ULIRGs), as well as the differences among galaxies within the same group. Conclusions. Suitable species for characterising and comparing starburst galaxies are CH3OH and HNCO as tracers of large-scale shocks, which dominate early to intermediate starburst stages, and CH3CCH, c-C3H2, and HCO as tracers of UV fields, which control the intermediate-to-old or post starburst phases. M 83 shows signs of a shock-dominated environment. NGC 253 is characterised by both strong shocks and some UV fields. M 82 stands out for its bright photo-dissociated region tracers, which indicate an UV field-dominated environment. Regarding AGNs, the abundances of HCN and CN (previously claimed as enhanced in AGNs) in M 51 are similar to those in starburst galaxies, while the HCN/HCO+ ratio is high in M 51 and NGC 1068, but not in NGC 7469. We did not find a correlation between the HCN/CS ratio (recently claimed as a possible starburst/AGN discriminator) and the AGN activity. However, a high enough spatial resolution to separate their circumnuclear disks from the surrounding star-forming regions is needed to find molecular abundance trends in AGNs. High abundances of H13CN and HC3N, as well as a similarity between the column densities of 13CO and C18O, are representative of the molecular interstellar medium in the ULIRGs. Furthermore, the chemistry of Arp 220 points towards a more starburst-dominated environment, while that of Mrk 231 more resembles the AGNs of our sample.
Abstract
We present a study of diffuse extended ionized gas towards three clouds located in the Galactic Centre (GC). One line of sight (LOS) is towards the 20 km s−1 cloud (LOS−0.11) in the Sgr A ...region, another LOS is towards the 50 km s−1 cloud (LOS−0.02), also in Sgr A, while the third is towards the Sgr B2 cloud (LOS+0.693). The emission from the ionized gas is detected from Hnα and Hmβ radio recombination lines (RRLs). Henα and Hemβ RRL emission is detected with the same n and m as those from the hydrogen RRLs only towards LOS+0.693. RRLs probe gas with positive and negative velocities towards the two Sgr A sources. The Hmβ to Hnα ratios reveal that the ionized gas is emitted under local thermodynamic equilibrium conditions in these regions. We find a He to H mass fraction of 0.29±0.01 consistent with the typical GC value, supporting the idea that massive stars have increased the He abundance compared to its primordial value. Physical properties are derived for the studied sources. We propose that the negative velocity component of both Sgr A sources is part of gas streams considered previously to model the GC cloud kinematics. Associated massive stars with what are presumably the closest H ii regions to LOS−0.11 (positive velocity gas), LOS−0.02, and LOS+0.693 could be the main sources of ultraviolet photons ionizing the gas. The negative velocity components of both Sgr A sources might be ionized by the same massive stars, but only if they are in the same gas stream.
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