The composition of cometary ices Bockelée-Morvan, D.; Biver, N.
Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences,
07/2017, Letnik:
375, Številka:
2097
Journal Article
Recenzirano
Odprti dostop
The chemical composition of cometary ices provides clues for the conditions of formation and evolution of the early Solar System. A large number of molecules have been identified in cometary ...atmospheres, from both ground-based observations and space, including in situ investigations. This includes large organic molecules, which are also observed in star-forming regions. This paper presents a review of molecular abundances measured in cometary atmospheres from remote sensing observations with ground-based and space-based telescopes. The diversity of composition observed in comet populations is presented and discussed.
This article is part of the themed issue ‘Cometary science after Rosetta’.
We present a multi-wavelength study of comet C/2016 R2 (PanSTARRS). This comet was observed on 23 and 24 January 2018 with the IRAM 30 m telescope, and in January to March 2018 with the Nançay radio ...telescope. Visible spectroscopy was performed in December 2017 and February 2018 with small amateur telescopes. We report on measurements of CO, CH3OH, H2CO and HCN production rates, and on the determination of the N2/CO abundance ratio. Several other species, especially OH, were searched for but not detected. The inferred relative abundances, including upper limits for sulfur species, are compared to those measured in other comets at about the same heliocentric distance of ~2.8 AU. The coma composition of comet C/2016 R2 is very different from all other comets observed so far, being rich in N2 and CO and dust poor. This suggests that this comet might belong to a very rare group of comets formed beyond the N2 ice line. Alternatively, comet C/2016 R2 (PanSTARRS) could be the fragment of a large and differentiated transneptunian object, with properties characteristic of volatile-enriched layers.
We present the analysis of ≈100 molecular maps of the coma of comet 67P/Churyumov-Gerasimenko that were obtained with the MIRO submillimeter radiotelescope on board the Rosetta spacecraft. From the ...spectral line mapping of H 216 $_2^{16}$ 216 O, H 218 $_2^{18}$218 O, H 217 $_2^{17}$217 O, CH3OH, NH3, and CO and some fixed nadir pointings, we retrieved the outgassing pattern and total production rates for these species. The analysis covers the period from July 2014, inbound to perihelion, to June 2016, outbound, and heliocentric distances rh = 1.24–3.65 AU. A steep evolution of the outgassing rates with heliocentric distance is observed, typically in rh−16 $r_{\textrm{h}}^{-6}$rh−6 , with significant differences between molecules (e.g. steeper variation for H2O post-perihelion than for methanol). As a consequence, the abundances relative to water in the coma vary. The CH3OH and CO abundances increase after perihelion, while the NH3 abundance peaks around perihelion and then decreases. Outgassing patterns have been modeled as 2D Gaussian jets. The width of these jets is maximum around the equinoxes when the bulk of the outgassing is located near the equator. From July 2014 to February 2015, the outgassing is mostly restricted to a narrower jet (full width at half-maximum ≈80°) originating from high northern latitudes, while around perihelion, most of the gaseous production comes from the southernmost regions ( − 80 ± 5° cometocentric latitude) and forms a 100°–130° (full width at half-maximum) wide fan. We find a peak production of water of 0.8 × 1028 molec. s−1, 2.5 times lower than measured by the ROSINA experiment, and place an upper limit to a 50% additional production that could come from the sublimation of icy grains. We estimate the total loss of ices during this perihelion passage to be 4.18 ± 0.18 × 109 kg. We derive a dust-to-gas ratio in the lost material of 0.7–2.3 (including all sources of errors) based on the nucleus mass loss of 10.5 ± 3.4 × 109 kg estimated by the RSI experiment. We also obtain an estimate of the H 218 $_2^{18}$218 O/H 217 $_2^{17}$217 O ratio of 5.6 ± 0.8.
Aims. Using spectroscopic and continuum data measured by the MIRO instrument on board Rosetta of comet 67P/Churyumov-Gerasimenko, it is possible to derive and track the change in the water production ...rate, to learn how the outgassing evolves with heliocentric distance. The MIRO data are well suited to investigate the evolution of 67P, in unprecedented spatial and temporal detail. Methods. To obtain estimates of the local effective Haser production rates we developed an efficient and reliable retrieval approach with precalculated lookup tables. We employed line area ratios (H216O/H218O) from pure nadir observations as the key variable, along with the Doppler shift velocity, and continuum temperature. This method was applied to the MIRO data from August 2014 until April 2016. Perihelion occurred on August 13, 2015 when the comet was 1.24 AU from the Sun. Results. During the perihelion approach, the water production rates increased by an order of magnitude, and from the observations, the derived maximum for a single observation on August 29, 2015 is (1.42 ± 0.51) ×1028. Modeling the data indicates that there is an offset in the peak outgassing, occurring 34 ± 10 days after perihelion. During the pre-perihelion phase, the production rate changes with heliocentric distance as rh−3.8±0.2; during post-perihelion, the dependence is rh−4.3±0.2. The comet is calculated to have lost 0.12 ± 0.06 % of its mass during the perihelion passage, considering only water ice sublimation. Additionally, this method provides well sampled data to determine the spatial distribution of outgassing versus heliocentric distance. The time evolution is definitely not uniform across the surface. Pre- and post-perihelion, the surface temperature on the southern hemisphere changes rapidly, as does the sublimation rate with an exponent of ~−6. There is a strong latitudinal dependence on the rh exponent with significant variation between northern and southern hemispheres, and so the average over the comet surface may only be of limited importance. We present more detailed regional variation in the outgassing, demonstrating that the highest derived production rates originate from the Wosret, Neith and Bes regions during perihelion.
Context.
In this Letter we aim to explore whether gas is also expected in the Kuiper belt (KB) in our Solar System.
Aims.
To quantify the gas release in our Solar System, we use models for gas ...release that have been applied to extrasolar planetary systems as well as a physical model that accounts for gas released due to the progressive internal warming of large planetesimals.
Methods.
We find that only bodies larger than about 4 km can still contain CO ice after 4.6 Gyr of evolution. This finding may provide a clue as to why Jupiter-family comets, thought to originate in the KB, are deficient in CO compared to Oort cloud comets. We predict that gas is still currently being produced in the KB at a rate of 2 × 10
−8
M
⊕
Myr
−1
for CO and that this rate was orders of magnitude higher when the Sun was younger. Once released, the gas is quickly pushed out by the solar wind. Therefore, we predict a gas wind in our Solar System starting at the KB location and extending far beyond with regards to the heliosphere, with a current total CO mass of ∼2 × 10
−12
M
⊕
(i.e., 20 times the CO quantity that was lost by the Hale-Bopp comet during its 1997 passage) and CO density in the belt of 3 × 10
−7
cm
−3
. We also predict the existence of a slightly more massive atomic gas wind made of carbon and oxygen (neutral and ionized), with a mass of ∼10
−11
M
⊕
.
Results.
We predict that gas is currently present in our Solar System beyond the KB and that, although it cannot be detected with current instrumentation, it could be observed in the future with an in situ mission using an instrument similar to Alice on New Horizons but with larger detectors. Our model of gas release due to slow heating may also work for exoplanetary systems and provide the first real physical mechanism for the gas observations. Lastly, our model shows that the amount of gas in the young Solar System should have been orders of magnitude greater and that it may have played an important role in, for example, planetary atmosphere formation.
Context. The recently announced Oort-cloud comet C/2014 UN271 (Bernardinelli-Bernstein) is remarkable in at least three respects: (i) it was discovered inbound as far as ∼29 au from the Sun (with ...prediscovery images up to ∼34 au); (ii) it already showed cometary activity at almost 24 au; and (iii) its nuclear magnitude (Hr ∼ 8.0) indicates an exceptionally large object. Detection of gases is expected in the upcoming years as the comet heads toward a perihelion of ∼11 au in 2031.Aims. The goal is to determine the object’s diameter and albedo from thermal measurements.Methods. We used ALMA in extended configuration (resolution ∼0.064″) to measure the 1287 μm (233 GHz) continuum flux of the comet. Observations were performed on August 8, 2021, at a 20.0 au distance from the Sun. The high spatial resolution was chosen in order to filter out any dust contribution. We also used a recently published Afρ value to estimate the dust production rate and the expected dust thermal signal for various assumptions on particle size distribution.Results. We detected the thermal emission of the object at ∼10σ, with a flux of 0.128 ± 0.012 mJy. Based on observational constraints and our theoretical estimates of the dust contribution, the entirety of the measured flux can be attributed to the nucleus. From NEATM modeling combined with the Hr magnitude, we determine a surface-equivalent diameter of 137 ± 17 km and a red geometric albedo of 5.3 ± 1.2%. This confirms that C/2014 UN271 is by far the largest Oort-cloud object ever found (almost twice as large as comet C/1995 O1 Hale-Bopp) and, except for the Centaur 95P/Chiron, which shows outburst-like activity, the largest known comet in the Solar System. On the other hand, the C/2014 UN271 albedo is typical of comets, adding credence to a “universal” comet nucleus albedo.Conclusions. With its distant perihelion and uniquely large size, C/2014 UN271 (Bernardinelli-Bernstein) is the prominent archetype of distant comets whose activity is driven by hypervolatiles. Monitoring of dust and gas emission as the comet approaches and passes perihelion will permit its activity time pattern to be studied and compared to the distant (outbound) activity of Hale-Bopp. Post-perihelion thermal measurements will permit the study of possible albedo changes, such as a surface brightening compared to pre-perihelion, as was observed for Hale-Bopp.
Gas-phase molecules in cometary atmospheres (comae) originate primarily from (1) outgassing by the nucleus, (2) sublimation of icy grains in the near-nucleus coma, and (3) coma (photo)chemical ...processes. However, the majority of cometary gases observed at radio wavelengths have yet to be mapped, so their production/release mechanisms remain uncertain. Here we present observations of six molecular species toward comet 46P/Wirtanen, obtained using the Atacama Large Millimeter/submillimeter Array during the comet's unusually close (∼0.1 au) approach to Earth in 2018 December. Interferometric maps of HCN, CH3OH, CH3CN, H2CO, CS, and HNC were obtained at an unprecedented sky-projected spatial resolution of up to 25 km, enabling the nucleus and coma sources of these molecules to be accurately quantified. The HCN, CH3OH, and CH3CN spatial distributions are consistent with production by direct outgassing from (or very close to) the nucleus, with a significant proportion of the observed CH3OH originating from sublimation of icy grains in the near-nucleus coma (at a scale length Lp = 36 ± 7 km). On the other hand, H2CO, CS, and HNC originate primarily from distributed coma sources (with Lp values in the range 550–16,000 km), the identities of which remain to be established. The HCN, CH3OH, and HNC abundances in 46P are consistent with the average values previously observed in comets, whereas the H2CO, CH3CN, and CS abundances are relatively low.
Context. Studying the coma environment of comet 67P/Churyumov-Gerasimenko (67P) is one of the primary scientific goals of the VIRTIS experiment on the ESA Rosetta mission. Aims. The distribution and ...variability of water vapour and carbon dioxide in the comet’s coma are needed to estimate their production rate, abundances in the nucleus, and the spatial distribution of the active regions. Methods. Infrared emission lines from vibrational bands of water and carbon dioxide at 2.67 and 4.27 μm, respectively, were observed by the VIRTIS-M imaging channel and mapped from close to the nucleus up to ~10 km altitude with a resolution of ~40 m/px. A dataset consisting of 74 observations in the 1−5 μm spectral range acquired from 8 to 14 April 2015 when 67P was at a heliocentric distance of 1.9 AU is analysed in this work. A statistical correlation between the gas distribution and the surface’s active regions was performed. Results. The maximum H2O emission is observed within 3 km from the nucleus and is mainly concentrated above two active regions, Aten-Babi and Seth-Hapi, while the CO2 distribution appears more uniform with significant emissions coming from both the “head” and southern latitude regions. In the equatorial region, the column densities of both species decrease with altitude, although CO2 decreases more rapidly than H2O. The calculated CO2/H2O column density ratios above Aten-Babi and Seth-Hapi are 2.4 ± 0.6% and 3.0 ± 0.7%, respectively. A value equal to 3.9 ± 1.0% is observed at equatorial latitudes in the region encompassing Imothep. Conclusions. VIRTIS-M has mapped the distribution of water vapour and carbon dioxide around the nucleus of 67P with unprecedented spatial resolution. The different water and carbon dioxide outgassing above the surface, seen in the VIRTIS-M data, might be indicative of a different thermal history of the northern and southern hemispheres of 67P.
Context.
Abundance ratios of the nuclear-spin isomers of H
2
O and NH
3
have been measured in about two dozen comets, with a mean value corresponding to a nuclear-spin temperature of ~30 K. The real ...meaning of these unequilibrated nuclear-spin abundance ratios is still debated. However, an equilibrated water ortho-to-para ratio of 3 is also commonly observed.
Aims.
The H channel of the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS-H) on board Rosetta provided high-resolution 2.5–2.9 μm spectra of H
2
O vapour in the coma of comet 67P/Churyumov-Gerasimenko (67P), which are suitable for the determination of the ortho-to-para ratio (OPR) of water in this comet.
Methods.
A large dataset of VIRTIS-H spectra obtained in limb-sounding viewing geometry was analysed, covering heliocentric distances from 1.24 to 2.73 au and altitudes from a few hundred metres to > 100 km. The OPR, together with the H
2
O rotational temperature and column density, were derived for each spectra using a database of fluorescence synthetic spectra that include both fundamental and hot vibrational water bands. The weak lines of the
v
1
,
v
1
+
v
3
−
v
1
and
v
2
+
v
3
−
v
2
bands in the 2.774–2.910 μm range were used to calculate by how much the strong
v
3
band centred at 2.67 μm is attenuated due to optical depth effects, expressed by the attenuation factor
f
atten
.
Results.
Most ortho-to-para ratio determinations are strongly affected by opacity effects, as demonstrated by the observed anti-correlation between the OPR and the column density, and the correlation between the OPR and attenuation factor
f
atten
. Based on both radiative transfer calculations and OPR values obtained in low-opacity conditions, we derive an OPR of 2.94 ± 0.06 for comet 67P. Measured water rotational temperatures show a decrease in gas kinetic temperature with increasing altitude caused by adiabatic cooling. Heliocentric variations are also observed, with warmer temperatures near perihelion.
Conclusions.
The water ortho-to-para ratio measured in the coma of 67P is consistent with laboratory experiments showing that water vapour that has thermally desorbed from water ice has a statistical value of 3, regardless of the past formation process of water ice.
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