•Plasma-induced current throughout contact glow discharge electrolysis could be tuned by modifying the electrolyte temperature.•A decrease of roughly 10 °C of the electrolyte temperature induces a ...current increase as high as + 130%.•This temperature-dependent effect could be exploited to both academic and industrial applications.
This study aims at disclosing the effect of small temperature drops (10–15 °C) of the electrolyte on Contact Glow Discharge Electrolysis (CGDE). In our experiments, we measure the temperature change of electrolyte and electrode as well as the change in current following on from the addition of, first, frozen and, second, boiling KOH aqueous solution (0.1 M). Quite surprisingly, only the addition of frozen KOH aqueous solution has a significant impact on current (+130%), caused by the decrease in electrolyte temperature (-11 °C). In contrast, the addition of boiling KOH aqueous solution has a negligible effect on current. A very similar behavior is recorded when frozen or boiling type III deionized water is used: the addition of ice has an even stronger impact on current (+145 %) and on electrolyte temperature (-14 °C), while adding boiling water has no measurable effect. Thus, we here demonstrated that electrolyte temperature is critical for managing the responsiveness of the CGDE system. Our results pave the way toward temperature controlled CGDE, a powerful tool for a greener and a more efficient environmental chemistry.
In the quest for a sustainable society, energy storage technology is destined to play a central role in the future energy landscape. Breakthroughs in materials and methods involving sustainable ...resources are crucial to protect humankind from the most serious consequences of climate change. Rechargeable batteries of all forms will be required to follow the path. Elements that are eligible to harmonically contribute to the development of a sustainable ecosystem and fulfil the demands of high energy density batteries include Na, K, Ca, Mg, Zn, and Al. Numerous research efforts are underway to explore new battery chemistries based on these elements and, depending on the field of application, different elements inherit different advantages and challenges. Full sustainability implies that the environmental friendliness of these systems must be characterized by a “cradle‐to‐grave” approach. In this context, the pursuit of global environmental and economical sustainability from mass production, raw materials, and technical challenges is discussed herein for the most recent battery concepts based on monovalent and multivalent metal anodes. A perspective on strategies and opportunities particularly around the development of all‐solid‐state system configurations is provided, and the most important obstacles to overcome in search of a more sustainable future for electrochemical energy storage are addressed.
This long‐term research roadmap covers large research themes and research areas that are needed to develop the sustainable post‐Li batteries of the future.
This review reports the properties of p-type semiconductors with nanostructured features employed as photocathodes in photoelectrochemical cells (PECs). Light absorption is crucial for the activation ...of the reduction processes occurring at the p-type electrode either in the pristine or in a modified/sensitized state. Beside thermodynamics, the kinetics of the electron transfer (ET) process from photocathode to a redox shuttle in the oxidized form are also crucial since the flow of electrons will take place correctly if the ET rate will overcome that one of recombination and trapping events which impede the charge separation produced by the absorption of light. Depending on the nature of the chromophore, i.e., if the semiconductor itself or the chemisorbed dye-sensitizer, different energy levels will be involved in the cathodic ET process. An analysis of the general properties and requirements of electrodic materials of p-type for being efficient photoelectrocatalysts of reduction processes in dye-sensitized solar cells (DSC) will be given. The working principle of p-type DSCs will be described and extended to other p-type PECs conceived and developed for the conversion of the solar radiation into chemical products of energetic/chemical interest like non fossil fuels or derivatives of carbon dioxide.
The investigation of innovative electrolytes based on nontoxic and nonflammable solvents is an up-to-date, intriguing challenge to push forward the environmental sustainability of dye-sensitized ...solar cells (DSSCs). Water is one of the best choices, thus 100% aqueous electrolytes are proposed in this work, which are gelled with xanthan gum. This well-known biosourced polymer matrix is able to form stable and easily processable hydrogel electrolytes based on the iodide/triiodide redox couple. An experimental strategy, also supported by the multivariate chemometric approach, is used here to study the main factors influencing DSSCs efficiency and stability, leading to an optimized system able to improve its efficiency by 20% even after a 1200 h aging test, and reaching an overall performance superior to 2.7%. In-depth photoelectrochemical investigation demonstrates that DSSCs performance based on hydrogel electrolytes depends on many factors (e.g., dipping conditions, redox mediator concentrations, etc.), that must be carefully quantified and correlated in order to optimize these hydrogels. Photovoltaic performances are also extremely reproducible and stable in an open cell filled in air atmosphere, noticeably without any vacuum treatments.
Deep Eutectic Solvent (DES)-like mixtures, based on glycerol and different halide organic and inorganic salts, are successfully exploited as new media in copper-free halodediazoniation of ...arenediazonium salts. The reactions are carried out in absence of metal-based catalysts, at room temperature and in a short time. Pure target products are obtained without the need for chromatographic separation. The solvents are fully characterized, and a computational study is presented aiming to understand the reaction mechanism.
Dye‐sensitized solar cells (DSSCs) have become a strong reality in the field of hybrid photovoltaics. Their ability to operate in diffused light conditions and the possibility of fabrication of ...modules bearing different colors make these cells attractive for different applications, for example, wearable electronics, building integration, etc. This review focuses on one of the compounds rather often studied for DSSCs, namely, poly(3,4‐ethylenedioxythiophene) (PEDOT). It has been introduced both as a substitute for liquid electrolytes, in order to facilitate cells fabrication and increase their durability, and as an alternative to platinum for counter electrodes. The literature counts many studies on PEDOT and this manuscript collects them following a classification criterion based on applications, functionalization/doping strategies, and deposition methods. In addition to comparing the performance obtained for PEDOT‐based systems with those of traditional cells (i.e., assembled with liquid iodine‐based electrolytes and platinum cathodes), the manuscript also offers a brief analysis of costs and sustainability aspects, built up on experimental data found in the literature; this latter is expected to constitute a precious resource to catalyze the attention of the scientific community on relevant and preliminary aspects when figuring out the industrial scalability of newly proposed cell components.
This review highlights the promising characteristics of poly(3,4‐ethylenedioxythiophene) for dye‐sensitized solar cells, with the ambitious challenge of replacing liquid electrolytes based on organic solvents and cathodes made up of metallic platinum. Literature analysis shows encouraging performance for lab‐scale solar cells, but the aspects related to large‐scale processability, long‐term stability, and sustainability still need to be thoroughly investigated.
Inositol has been used as a supplement in treating several pathologies such as PCOS, metabolic syndrome, and gestational diabetes. Both myo-inositol and its isomer d-chiro-inositol showed insulin ...mimetic effects in conditions of insulin resistance. Type 2 diabetes (T2DM) is a condition typically caused by insulin resistance. There is a lack of evidence of inositol use in T2DM. We evaluated the effectiveness and safety of myo-inositol and d-chiro-inositol treatment in T2DM. This was a pilot study involving a consecutive sample of patients with T2DM with suboptimal glycemic control (HbA1c 7.0–10.0%) already treated with glucose-lowering agents. Patients (23.1% males, mean age of 60.8 ± 11.7 years) took for three months a combination of myo-inositol (550 mg) and d-chiro-inositol (13.8 mg) orally twice a day as add-on supplement to their glucose-lowering drugs. Possible occurrence of side effects was investigated. After three months of treatment fasting blood glucose ( 192.6 ± 60.2 versus 160.9 ± 36.4 ; p = 0.02 ) and HbA1c levels ( 8.6 ± 0.9 versus 7.7 ± 0.9 ; p = 0.02 ) significantly decreased compared to baseline. There was no significant difference in blood pressure, lipid profile, and BMI levels. None of the participants reported side effects. In conclusion, a supplementation with a combination of myo- and d-chiro-inositol is an effective and safe strategy for improving glycemic control in T2DM.
A chiral glycerol derivative, namely 3-amino-1,2-propanediol, was employed for as the hydrogen bond donor (HBD) in the design of a new deep eutectic solvent (DES) with choline chloride acting as the ...hydrogen bond acceptor (HBA). The novel mixture was characterized and unambiguously classified as a DES. Furthermore, its synthetic usefulness was demonstrated in the room-temperature
-butyllithium-addition under air to carbonyl compounds and benzyl chloride. In some cases, pure products (100% conversion) were obtained by a simple extractive work-up in up to 72% isolated yield, thus suggesting the potential practical usefulness of this procedure as a green alternative to the classical Schenk procedure in volatile organic solvents for the synthesis of tertiary alcohols. The chirality of the HBD, bearing an interesting basic primary amino group, is an intriguing feature currently under investigation for further exploitation.
The cost-effective production of chemicals in electrolytic cells and the conversion of the radiation energy into electrical energy in photoelectrochemical cells (PECs) require the use of electrodes ...with large surface area, which possess either electrocatalytic or photoelectrocatalytic properties. In this context nanostructured semiconductors are electrodic materials of great relevance because of the possibility of varying their photoelectrocatalytic properties in a controlled fashion via doping, dye-sensitization or modification of the conditions of deposition. Among semiconductors for electrolysers and PECs the class of the transition metal oxides (TMOs) with a particular focus on NiO interests for the chemical-physical inertness in ambient conditions and the intrinsic electroactivity in the solid state. The latter aspect implies the existence of capacitive properties in TMO and NiO electrodes which thus act as charge storage systems. After a comparative analysis of the (photo)electrochemical properties of nanostructured TMO electrodes in the configuration of thin film the use of NiO and analogs for the specific applications of water photoelectrolysis and, secondly, photoelectrochemical conversion of carbon dioxide will be discussed.
Deep Eutectic Solvents have gained a lot of attention in the last few years because of their vast applicability in a large number of technological processes, the simplicity of their preparation and ...their high biocompatibility and harmlessness. One of the fields where DES prove to be particularly valuable is the synthesis and modification of inorganic materials-in particular, nanoparticles. In this field, the inherent structural inhomogeneity of DES results in a marked templating effect, which has led to an increasing number of studies focusing on exploiting these new reaction media to prepare nanomaterials. This review aims to provide a summary of the numerous and most recent achievements made in this area, reporting several examples of the newest mixtures obtained by mixing molecules originating from natural feedstocks, as well as linking them to the more consolidated methods that use "classical" DES, such as reline.
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