The snowpack is an important source of water for many Andean communities. Because of its importance, elemental and mineralogical composition analysis of the Andean snow is a worthwhile effort. In ...this study, we conducted a chemical composition analysis (major and trace elements, mineralogy, and chemical enrichment) of surface snow sampled at 21 sites across a transect of about 2,500 km in the Chilean Andes (18-41°S). Our results enabled us to identify five depositional environments: (i) sites 1-3 (in the Atacama Desert, 18-26°S) with relatively high concentrations of metals, high abundance of quartz and low presence of arsenates, (ii) sites 4-8 (in northern Chile, 29-32°S) with relatively high abundance of quartz and low presence of metals and arsenates, (iii) sites 9-12 (in central Chile, 33-35°S) with anthropogenic enrichment of metals, relatively high values of quartz and low abundance of arsenates, (iv) sites 13-14 (also in central Chile, 35-37°S) with relatively high values of quartz and low presence of metals and arsenates, and v) sites 15-21 (in southern Chile, 37-41°S) with relatively high abundance of arsenates and low presence of metals and quartz. We found significant anthropogenic enrichment at sites close to Santiago (a major city of 6 million inhabitants) and in the Atacama Desert (that hosts several major copper mines).
Predicting radiative forcing due to Antarctic stratospheric ozone recovery requires detecting changes in the ozone vertical distribution. In this endeavor, the Limb Profiler of the Ozone Mapping and ...Profiler Suite (OMPS-LP), aboard the Suomi NPP satellite, has played a key role providing ozone profiles over Antarctica since 2011. Here, we compare ozone profiles derived from OMPS-LP data (version 2.5 algorithm) with balloon-borne ozonesondes launched from 8 Antarctic stations over the period 2012-2020. Comparisons focus on the layer from 12.5 to 27.5 km and include ozone profiles retrieved during the Sudden Stratospheric Warming (SSW) event registered in Spring 2019. We found that, over the period December-January-February-March, the root mean square error (RMSE) tends to be larger (about 20%) in the lower stratosphere (12.5-17.5 km) and smaller (about 10%) within higher layers (17.5-27.5 km). During the ozone hole season (September-October-November), RMSE values rise up to 40% within the layer from 12.5 to 22 km. Nevertheless, relative to balloon-borne measurements, the mean bias error of OMPS-derived Antarctic ozone profiles is generally lower than 0.3 ppmv, regardless of the season.
Abstract
The Antarctic Peninsula (AP) experienced a new extreme warm event and record-high surface melt in February 2022, rivaling the recent temperature records from 2015 and 2020, and contributing ...to the alarming series of extreme warm events over this region showing stronger warming compared to the rest of Antarctica. Here, the drivers and impacts of the event are analyzed in detail using a range of observational and modeling data. The northern/northwestern AP was directly impacted by an intense atmospheric river (AR) attaining category 3 on the AR scale, which brought anomalous heat and rainfall, while the AR-enhanced foehn effect further warmed its northeastern side. The event was triggered by multiple large-scale atmospheric circulation patterns linking the AR formation to tropical convection anomalies and stationary Rossby waves, with an anomalous Amundsen Sea Low and a record-breaking high-pressure system east of the AP. This multivariate and spatial compound event culminated in widespread and intense surface melt across the AP. Circulation analog analysis shows that global warming played a role in the amplification and increased probability of the event. Increasing frequency of such events can undermine the stability of the AP ice shelves, with multiple local to global impacts, including acceleration of the AP ice mass loss and changes in sensitive ecosystems.
The Year of Polar Prediction in the Southern Hemisphere (YOPP-SH) had a special observing period (SOP) that ran from 16 November 2018 to 15 February 2019, a period chosen to span the austral warm ...season months of greatest operational activity in the Antarctic. Some 2,200 additional radiosondes were launched during the 3-month SOP, roughly doubling the routine program, and the network of drifting buoys in the Southern Ocean was enhanced. An evaluation of global model forecasts during the SOP and using its data has confirmed that extratropical Southern Hemisphere forecast skill lags behind that in the Northern Hemisphere with the contrast being greatest between the southern and northern polar regions. Reflecting the application of the SOP data, early results from observing system experiments show that the additional radiosondes yield the greatest forecast improvement for deep cyclones near the Antarctic coast. The SOP data have been applied to provide insights on an atmospheric river event during the YOPP-SH SOP that presented a challenging forecast and that impacted southern South America and the Antarctic Peninsula. YOPP-SH data have also been applied in determinations that seasonal predictions by coupled atmosphere–ocean–sea ice models struggle to capture the spatial and temporal characteristics of the Antarctic sea ice minimum. Education, outreach, and communication activities have supported the YOPP-SH SOP efforts. Based on the success of this Antarctic summer YOPP-SH SOP, a winter YOPP-SH SOP is being organized to support explorations of Antarctic atmospheric predictability in the austral cold season when the southern sea ice cover is rapidly expanding.
We have sampled both the downwelling and upwelling radiance distributions at a camp located in the southern Ellsworth Mountains on the broad expanse of Union Glacier (700 m altitude, 79° 46' S, 82° ...52' W). The measurements (at 320-440 nm wavelength range) were carried out under cloudless conditions by using a sky scanner system, during a campaign (in December, 2012) meant to assess the effects of the high albedo on the radiance distribution. The angular variations observed in both the downwelling and upwelling radiance distributions increase with the wavelength. However, these variations were considerably greater in the case of the downwelling radiance than in the case of the upwelling radiance. Indeed, we found that downwelling radiance tends to be less isotropic than the corresponding upwelling radiance. Regardless of the solar zenith angle and the wavelength, the minima of the downwelling and the upwelling radiance distributions were measured close to the zenith and to the nadir, respectively. The downwelling (upwelling) radiance increased nearly monotonically toward the horizon and peaked at zenith (nadir) angles that ranged from 75° to 90°. Comparisons with the UVSPEC radiative transfer model were used to weight up the response of the downwelling radiance distribution to changes in the albedo.
In this study, we explored the connection between anomalies in springtime Antarctic ozone and all-year precipitation in the Southern Hemisphere by using observations from 1960–2018 and coupled ...simulations for 1960–2050. The observations showed that this correlation was enhanced during the last several decades, when a simultaneously increased coupling between ozone and Southern Annular Mode (SAM) anomalies became broader, covering most of the following summer and part of the previous winter. For eastern Australia, the ozone–precipitation connection shows a greater persistence toward the following summer than for other regions. On the other hand, for South America, the ozone–precipitation correlation seems more robust, especially in the early summer. There, the correlation also covers part of the previous winter, suggesting that winter planetary waves could affect both parameters. Further, we estimated the sensitivity of precipitation to changes in Antarctic ozone. In both observations and simulations, we found comparable sensitivity values during the spring–summer period. Overall, our results indicate that ozone anomalies can be understood as a tracer of stratospheric circulation. However, simulations indicate that stratospheric ozone chemistry still contributes to strengthening the interannual relationship between ozone and surface climate. Because simulations reproduced most of the observed connections, we suggest that including ozone variability in seasonal forecasting systems can potentially improve predictions.
Recent changes in the near-surface air temperature (nSAT) in the Antarctic Peninsula (AP) suggests that the absence of 21st century warming on Antarctic Peninsula may be coming to end. To examine ...this, the long-term annual and seasonal variability of the nSAT at eight Antarctic stations located in the AP are analyzed using available data from the SCAR Reader database, complemented with data from the Chilean Weather Service (Frei and O'Higgins). An exponential filter was applied to the original annual and seasonal mean series to obtain a decadal-like variation of the nSAT. A stacked and the standardized anomaly of the nSAT record was constructed to examine the average regional behavior in the AP. Cumulative sum (CUSUM) and changepoint analysis were applied through the stacked nSAT series to highlight significant changes caused by variation in weather and climate. The CUSUM and bootstrapping analysis revealed two statistically significant breaking points during the 1978–2020 period. The first one occurred in the late nineties ending a warming period and making the beginning of a cooling period; the second one may have taken place in the mid-2010s and could mark the end of the warming pause. These trends appear to be consistent with the changes observed in the large-scale climate modes (i.e., the Antarctic Annular Mode – AAO).
We report on the surface UV index (UVI) variations in Santiago (Chile) a city with high air pollution and complex surrounding topography. Ground-based UV measurements were continuously carried out ...between January 1995 and December 2011, by using a multi-channel filter radiometer (PUV-510). Ground-based measurements and satellite-derived data retrieved from the Total Ozone Mapping Spectrometer (TOMS), the Ozone Monitoring Instrument (OMI), and the Scanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY), were compared. We found that satellite-derived UVI products largely overestimate surface UVI. Our ground-based UVI measurements were significantly lower than TOMS-derived UVI data: (46.1±6.3)% (in the period 1997–2003), and OMI-derived UVI data: (47.0±6.3)% (in the period 2005–2007). Clear-sky SCIAMACHY-derived UVI were found to be also nearly systematically greater than ground-based UVI measurements in the period 2002–2011. An exceptionally long period of clear skies between December 2010 and January 2011 was used to test further satellite-derived UVI data; in the whole period, OMI and SCIAMACHY data were 53.1% and 38.3% greater than our ground-based measurements, respectively. These differences are presumably due to aerosol load associated with the local pollution and the complex topography surrounding Santiago. In addition, linear regression allowed us to estimate trends that we use for forecasting. Methodological details are provided below.
Variability in the chemistry of the upper stratosphere/lower mesosphere region has been analyzed focusing on high latitudes during the boreal winter in 2009 characterized by the strong sudden ...stratospheric warming (SSW) on 24 January. Data from Michelson Interferometer for Passive Atmospheric Sounding aboard Envisat and the Microwave Limb Sounder on Aura have been used to exemplify these changes. Record high (low) values of O3 and ClO (temperature and HCl) for the winters of 2005–2012, coupled with a simultaneous enhancement of ClONO2, have been observed in February 2009. This suggests that the very low temperatures favor a more effective ozone production and a greater O3/O ratio. The latter is the main factor controlling active chlorine partitioning. Increases of ClO lead to high ClONO2 concentrations in the upper stratosphere at high latitudes, where its photodissociation rate is smaller. Since this increase of ClONO2 happens at the expense of HCl, the region of high ClONO2 roughly coincides with the region of low HCl. Although this period was characterized by an elevated stratopause event, the investigated region was not influenced by the descent of mesospheric air rich in NOx. Some limited enhancements in NOx at ~1 hPa occurred at latitudes greater than 80°N after about 20 February, but they became consistent only in March. Intrusion of midlatitude air mostly occurred between the SSW and early February. Then, the sum of volume mixing ratios of ClONO2 + ClO + HCl remained approximately constant and close to the values of the other years. In contrast, it was up to 0.2 ppbv lower during the SSW period. These atypical chemical conditions occurred also in February 2006, but 2009 stands out for its long‐lasting effects, which persisted until late March.
Key Points
Record high (low) values of O3 and ClO (T and HCl) in February 2009Low temperatures favored greater O3 production and O3/O ratioClONO3+ClO+HCl remained approximately constant
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