We measured maps of atmospheric water (H2O) and its deuterated form (HDO) across the martian globe, showing strong isotopic anomalies and a significant high deuterium/hydrogen (D/H) enrichment ...indicative of great water loss. The maps sample the evolution of sublimation from the north polar cap, revealing that the released water has a representative D/H value enriched by a factor of about 7 relative to Earth's ocean Vienna standard mean ocean water (VSMOW). Certain basins and orographic depressions show even higher enrichment, whereas high-altitude regions show much lower values (1 to 3 VSMOW). Our atmospheric maps indicate that water ice in the polar reservoirs is enriched in deuterium to at least 8 VSMOW, which would mean that early Mars (4.5 billion years ago) had a global equivalent water layer at least 137 meters deep.
Aims. Following the announcement of the detection of phosphine (PH3) in the cloud deck of Venus at millimeter wavelengths, we have searched for other possible signatures of this molecule in the ...infrared range.Methods. Since 2012, we have been observing Venus in the thermal infrared at various wavelengths to monitor the behavior of SO2 and H2O at the cloud top. We have identified a spectral interval recorded in March 2015 around 950 cm−1 where a PH3 transition is present.Results. From the absence of any feature at this frequency, we derive, on the disk-integrated spectrum, a 3-σ upper limit of 5 ppbv for the PH3 mixing ratio, assumed to be constant throughout the atmosphere. This limit is 4 times lower than the disk-integrated mixing ratio derived at millimeter wavelengths.Conclusions. Our result brings a strong constraint on the maximum PH3 abundance at the cloud top and in the lower mesosphere of Venus.
The VIRTIS (Visible, Infrared and Thermal Imaging Spectrometer) instrument on board the Rosetta spacecraft has provided evidence of carbon-bearing compounds on the nucleus of the comet ...67P/Churyumov-Gerasimenko. The very low reflectance of the nucleus (normal albedo of 0.060 ± 0.003 at 0.55 micrometers), the spectral slopes in visible and infrared ranges (5 to 25 and 1.5 to 5% kÅ
−1
), and the broad absorption feature in the 2.9-to-3.6–micrometer range present across the entire illuminated surface are compatible with opaque minerals associated with nonvolatile organic macromolecular materials: a complex mixture of various types of carbon-hydrogen and/or oxygen-hydrogen chemical groups, with little contribution of nitrogen-hydrogen groups. In active areas, the changes in spectral slope and absorption feature width may suggest small amounts of water-ice. However, no ice-rich patches are observed, indicating a generally dehydrated nature for the surface currently illuminated by the Sun.
The global D/H ratio on Mars is an important measurement for understanding the past history of water on Mars; locally, through condensation and sublimation processes, it is a possible tracer of the ...sources and sinks of water vapor on Mars. Measuring D/H as a function of longitude, latitude and season is necessary for determining the present averaged value of D/H on Mars. Following an earlier measurement in April 2014, we used the Echelon Cross Echelle Spectrograph (EXES) instrument on board the Stratospheric Observatory for Infrared Astronomy (SOFIA) facility to map D/H on Mars on two occasions, on March 24, 2016 (Ls = 127°), and January 24, 2017 (Ls = 304°), by measuring simultaneously the abundances of H2O and HDO in the 1383–1391 cm−1 range (7.2 μm). The D/H disk-integrated values are 4.0 (+0.8, −0.6) × Vienna Standard Mean Ocean Water (VSMOW) and 4.5 (+0.7, −0.6) × VSMOW, respectively, in agreement with our earlier result. The main result of this study is that there is no evidence of strong local variations in the D/H ratio nor for seasonal variations in the global D/H ratio between northern summer and southern summer.
General Circulation Models with interactive physical and chemistry processes are the state-of-the-art tools for an integrated view and understanding of the Martian atmosphere and climate system. The ...GEM-Mars model currently includes 16 tracers for chemical composition and applies a fully online, interactive calculation of the photo- and gas phase chemistry of carbon dioxide (CO2) and water vapor (H2O). These species largely control the chemical composition of the neutral Mars atmosphere through their photolysis products and their subsequent interactions. Water vapor undergoes a complex cycle on Mars as it is transported and interacts with ice reservoirs both at the planet's surface and at water ice clouds, which in turn provide radiative feedbacks. In the photochemical cycles involving CO2 and H2O, the abundances of 5 species have been reported by previous investigations with significant spatio-temporal coverage: CO2, H2O, CO, O3 and H2O2. This paper presents the current status of the atmospheric chemistry simulations in GEM-Mars by comparing them to a selection of these observational datasets as well as to oxygen dayglow emission from O2(a1∆g). The results are consistent with previous model-data comparisons and illustrate that the water cycle and the photochemistry are well implemented in the model. In particular, the simulation of the key reservoir species H2O2 provides a good match to the available data. Model-data biases for ozone columns and oxygen airglow are related to the simulated water vapor vertical profile, as these species have important column contributions from vertical layers at the top of the hygropause.
•GEM-Mars is a global Mars atmospheric model with online atmospheric chemistry.•Comparisons to a broad set of observations show good performance.•Good simulation of CO2, CO, H2O, H2O2, O3 and O2(a1∆g) airglow•Model-data bias for O3 relates to biases in the simulated water vertical profile.•Middle-atmospheric water excess related to excessive heating by water ice clouds
Context. Carbon monoxide (CO) has been detected in all giant planets and its origin is both internal and external in Jupiter and Neptune. Despite its first detection in Uranus a decade ago, the ...magnitude of its internal and external sources remains unconstrained. Aims. We targeted CO lines in Uranus in the submillimeter range to constrain its origin. Methods. We recorded the disk-averaged spectrum of Uranus with very high spectral resolution at the frequencies of CO rotational lines in the submillimeter range in 2011−2012. We used empirical and diffusion models of the atmosphere of Uranus to constrain the origin of CO. We also used a thermochemical model of its troposphere to derive an upper limit on the oxygen-to-hydrogen (O/H) ratio in the deep atmosphere of Uranus. Results. We have detected the CO(8−7) rotational line for the first time with Herschel-HIFI. Both empirical and diffusion models results show that CO has an external origin. An empirical profile in which CO is constant above the 100 mbar level with a mole fraction of 7.1−9.0 × 10-9, depending on the adopted stratospheric thermal structure, reproduces the data. Sporadic and steady source models cannot be differentiated with our data. Taking the internal source model upper limit of a mole fraction of 2.1 × 10-9 we find, based on our thermochemical computations, that the deep O/H ratio of Uranus is less than 500 times solar. Conclusions. Our work shows that the average mole fraction of CO decreases from the stratosphere to the troposphere and thus strongly advocates for an external source of CO in Uranus. Photochemical modeling of oxygen species in the atmosphere of Uranus and more sensitive observations are needed to reveal the nature of the external source.
The Atmospheric Chemistry Suite (ACS) package is an element of the Russian contribution to the ESA-Roscosmos ExoMars 2016 Trace Gas Orbiter (TGO) mission. ACS consists of three separate infrared ...spectrometers, sharing common mechanical, electrical, and thermal interfaces. This ensemble of spectrometers has been designed and developed in response to the Trace Gas Orbiter mission objectives that specifically address the requirement of high sensitivity instruments to enable the unambiguous detection of trace gases of potential geophysical or biological interest. For this reason, ACS embarks a set of instruments achieving simultaneously very high accuracy (ppt level), very high resolving power (>10,000) and large spectral coverage (0.7 to 17 μm—the visible to thermal infrared range). The near-infrared (NIR) channel is a versatile spectrometer covering the 0.7–1.6 μm spectral range with a resolving power of ∼20,000. NIR employs the combination of an echelle grating with an AOTF (Acousto-Optical Tunable Filter) as diffraction order selector. This channel will be mainly operated in solar occultation and nadir, and can also perform limb observations. The scientific goals of NIR are the measurements of water vapor, aerosols, and dayside or night side airglows. The mid-infrared (MIR) channel is a cross-dispersion echelle instrument dedicated to solar occultation measurements in the 2.2–4.4 μm range. MIR achieves a resolving power of >50,000. It has been designed to accomplish the most sensitive measurements ever of the trace gases present in the Martian atmosphere. The thermal-infrared channel (TIRVIM) is a 2-inch double pendulum Fourier-transform spectrometer encompassing the spectral range of 1.7–17 μm with apodized resolution varying from 0.2 to 1.3 cm
−1
. TIRVIM is primarily dedicated to profiling temperature from the surface up to ∼60 km and to monitor aerosol abundance in nadir. TIRVIM also has a limb and solar occultation capability. The technical concept of the instrument, its accommodation on the spacecraft, the optical designs as well as some of the calibrations, and the expected performances for its three channels are described.
The so‐called unknown absorber in the clouds of Venus is an important absorber of solar energy, but its vertical distribution remains poorly quantified. We analyze the 283 and 365 nm phase curves of ...the disk‐integrated albedo measured by Akatsuki. Based on our models, we find that the unknown absorber can exist either well mixed over the entire upper cloud or within a thin layer. The necessary condition to explain the 365 nm phase curve is that the unknown absorber must absorb efficiently within the cloud scale height immediately below the cloud top. Using this constraint, we attempt to extract the SO2 abundance from the 283 nm phase curve. However, we cannot disentangle the absorption by SO2 and by the unknown absorber. Considering previous SO2 abundance measurements at midinfrared wavelengths, the required absorption coefficient of the unknown absorber at 283 nm must be more than twice that at 365 nm.
Plain Language Summary
There is an unknown absorber in the clouds of Venus. It absorbs solar energy effectively at ultraviolet (UV) and blue wavelengths, but its vertical location, either above or below the cloud top level (about 70 km altitude), remains unclear. This uncertainty affects our understanding of the vertical deposition of solar energy in the atmosphere. We investigate the vertical distribution of the unknown absorber using the dependence of the full‐disk brightness on the scattering direction (the Sun‐Venus‐spacecraft angle) at 365 nm, with data from JAXA's Akatsuki spacecraft over 3 years. We find that the unknown absorber could exist in the entire cloud, or as a thin layer near but below the cloud top. Using these constraints on the vertical distribution of the unknown absorber, we analyze the 283 nm full‐disk brightness. At this shorter wavelength, the SO2 gas and the unknown absorber are both effective absorbers. We attempt to quantify the SO2 abundance, and find that the brightness dependence on the scattering direction alone is insufficient to separate the contribution from the two absorbers at 283 nm. Further analysis with spectral phase curve observations will better define the SO2 abundance.
Key Points
The vertical distribution of the unknown absorber is investigated with the aid of full‐disk phase curves at wavelengths of 283 and 365 nm
First time the 283 nm full‐disk brightness phase curve of Venus is analyzed over a broad phase angle range
The unknown absorber must result in sufficient absorption within the cloud scale height immediately below the cloud top
Context. Water vapor and sulfur compounds are key species in the photochemistry of Venus mesosphere. These species, together with mesospheric temperatures, exhibit drastic temporal variations, both ...on short timescales (diurnal and day-to-day) as well on long timescales, far from being understood. Aims. We targeted CO, SO, HDO and SO2 transitions in the submillimeter range using the Atacama Large Millimeter Array (ALMA) to study their spatial and temporal variations. Methods. Four sets of observations were acquired on different dates in November 2011 during the first ALMA Early Science observation Cycle 0. Venus angular diameter was about 11′′ with an illumination factor of 92%, so that mostly the day side of the planet was mapped. Assuming a nominal CO abundance profile, we retrieved vertical temperature profiles over the entire disk as a function of latitude and local time. Temperature profiles were later used to retrieve SO, SO2, and H2O. We used HDO as a tracer for water assuming a D/H enrichment of 200 times the terrestrial value. Results. We derived 3D maps of mesospheric temperatures in the altitude range 70−105 km. SO, SO2, and H2O are characterized by a negligible abundance below ~ 85 km followed by an increase with altitude in the upper mesosphere. Disk-averaged SO abundances present a maximum mixing ratio of 15.0 ± 3.1 ppb on November 26 followed the next day by a minimum value of 9.9 ± 1.2 ppb. Due to a very low S/N, SO2 could only be derived from the disk-averaged spectrum on the first day of observation revealing an abundance of 16.5 ± 4.6 ppb. We found a SO2/SO ratio of 1.5 ± 0.4. Global maps of SO reveal strong variations both with latitude and local time and from day to day with abundance ranging from < 1 to 15 ppb. H2O disk-averages retrievals reveal a steady decrease from November 14 to 27, with the abundance varying from 3.6 ± 0.6 ppm on the first day to 2.9 ± 0.7 ppm on the last day. H2O maps reveal a slightly higher abundance on the evening side compared to the morning side and a strong depletion between the first and the second day of observation.