We measured maps of atmospheric water (H2O) and its deuterated form (HDO) across the martian globe, showing strong isotopic anomalies and a significant high deuterium/hydrogen (D/H) enrichment ...indicative of great water loss. The maps sample the evolution of sublimation from the north polar cap, revealing that the released water has a representative D/H value enriched by a factor of about 7 relative to Earth's ocean Vienna standard mean ocean water (VSMOW). Certain basins and orographic depressions show even higher enrichment, whereas high-altitude regions show much lower values (1 to 3 VSMOW). Our atmospheric maps indicate that water ice in the polar reservoirs is enriched in deuterium to at least 8 VSMOW, which would mean that early Mars (4.5 billion years ago) had a global equivalent water layer at least 137 meters deep.
Aims. Following the announcement of the detection of phosphine (PH3) in the cloud deck of Venus at millimeter wavelengths, we have searched for other possible signatures of this molecule in the ...infrared range.Methods. Since 2012, we have been observing Venus in the thermal infrared at various wavelengths to monitor the behavior of SO2 and H2O at the cloud top. We have identified a spectral interval recorded in March 2015 around 950 cm−1 where a PH3 transition is present.Results. From the absence of any feature at this frequency, we derive, on the disk-integrated spectrum, a 3-σ upper limit of 5 ppbv for the PH3 mixing ratio, assumed to be constant throughout the atmosphere. This limit is 4 times lower than the disk-integrated mixing ratio derived at millimeter wavelengths.Conclusions. Our result brings a strong constraint on the maximum PH3 abundance at the cloud top and in the lower mesosphere of Venus.
The VIRTIS (Visible, Infrared and Thermal Imaging Spectrometer) instrument on board the Rosetta spacecraft has provided evidence of carbon-bearing compounds on the nucleus of the comet ...67P/Churyumov-Gerasimenko. The very low reflectance of the nucleus (normal albedo of 0.060 ± 0.003 at 0.55 micrometers), the spectral slopes in visible and infrared ranges (5 to 25 and 1.5 to 5% kÅ
−1
), and the broad absorption feature in the 2.9-to-3.6–micrometer range present across the entire illuminated surface are compatible with opaque minerals associated with nonvolatile organic macromolecular materials: a complex mixture of various types of carbon-hydrogen and/or oxygen-hydrogen chemical groups, with little contribution of nitrogen-hydrogen groups. In active areas, the changes in spectral slope and absorption feature width may suggest small amounts of water-ice. However, no ice-rich patches are observed, indicating a generally dehydrated nature for the surface currently illuminated by the Sun.
•Global spectral maps of Jupiter’ s 5–20 µm thermal emission are provided by IRTF/TEXES.•Quality of retrieved maps of temperature, composition and aerosols surpass previous spacecraft ...results.•Jupiter’ s NEB hotspots are identifiable throughout the thermal-IR and tilt westward with height.•Ammonia plumes are observed at the equator, southeast of desiccated NEB hotspots.•Long-term asymmetries in phosphine, hydrocarbons and 2D wind field are detected.
Global maps of Jupiter’s atmospheric temperatures, gaseous composition and aerosol opacity are derived from a programme of 5–20 µm mid-infrared spectroscopic observations using the Texas Echelon Cross Echelle Spectrograph (TEXES) on NASA’s Infrared Telescope Facility (IRTF). Image cubes from December 2014 in eight spectral channels, with spectral resolutions of R ∼2000−12,000 and spatial resolutions of 2–4° latitude, are inverted to generate 3D maps of tropospheric and stratospheric temperatures, 2D maps of upper tropospheric aerosols, phosphine and ammonia, and 2D maps of stratospheric ethane and acetylene. The results are compared to a re-analysis of Cassini Composite Infrared Spectrometer (CIRS) observations acquired during Cassini’s closest approach to Jupiter in December 2000, demonstrating that this new archive of ground-based mapping spectroscopy can match and surpass the quality of previous investigations, and will permit future studies of Jupiter’s evolving atmosphere. The visibility of cool zones and warm belts varies from channel to channel, suggesting complex vertical variations from the radiatively-controlled upper troposphere to the convective mid-troposphere. We identify mid-infrared signatures of Jupiter’s 5-µm hotspots via simultaneous M, N and Q-band observations, which are interpreted as temperature and ammonia variations in the northern Equatorial Zone and on the edge of the North Equatorial Belt (NEB). Equatorial plumes enriched in NH3 gas are located south-east of NH3-desiccated ‘hotspots’ on the edge of the NEB. Comparison of the hotspot locations in several channels across the 5–20 µm range indicate that these anomalous regions tilt westward with altitude. Aerosols and PH3 are both enriched at the equator but are not co-located with the NH3 plumes. The equatorial temperature minimum and PH3/aerosol maxima have varied in amplitude over time, possibly as a result of periodic equatorial brightenings and the fresh updrafts of disequilibrium material. Temperate mid-latitudes display a correlation between mid-IR aerosol opacity and the white albedo features in visible light (i.e., zones). We find hemispheric asymmetries in the distribution of tropospheric PH3, stratospheric hydrocarbons and the 2D wind field (estimated via the thermal-wind equation) that suggest a differing efficiency of mechanical forcing (e.g., vertical mixing and wave propagation) between the two hemispheres that we argue is driven by dynamics rather than Jupiter’s small seasonal cycle. Jupiter’s stratosphere is notably warmer at northern mid-latitudes than in the south in both 2000 and 2014, although the latter can be largely attributed to strong thermal wave activity near 30°N that dominates the 2014 stratospheric maps and may be responsible for elevated C2H2 in the northern hemisphere. A vertically-variable pattern of temperature and windshear minima and maxima associated with Jupiter’s Quasi Quadrennial Oscillation (QQO) is observed at the equator in both datasets, although the contrasts were more subdued in 2014. Large-scale equator-to-pole gradients in ethane and acetylene are superimposed on top of the mid-latitude mechanically-driven maxima, with C2H2 decreasing from equator to pole and C2H6 showing a polar enhancement, consistent with a radiatively-controlled circulation from low to high latitudes. Cold polar vortices beyond ∼60° latitude can be identified in the upper tropospheric and lower stratospheric temperature maps, suggesting enhanced radiative cooling from polar aerosols. Finally, compositional mapping of the Great Red Spot confirms the local enhancements in PH3 and aerosols, the north–south asymmetry in NH3 gas and the presence of a warm southern periphery that have been noted by previous authors.
The global D/H ratio on Mars is an important measurement for understanding the past history of water on Mars; locally, through condensation and sublimation processes, it is a possible tracer of the ...sources and sinks of water vapor on Mars. Measuring D/H as a function of longitude, latitude and season is necessary for determining the present averaged value of D/H on Mars. Following an earlier measurement in April 2014, we used the Echelon Cross Echelle Spectrograph (EXES) instrument on board the Stratospheric Observatory for Infrared Astronomy (SOFIA) facility to map D/H on Mars on two occasions, on March 24, 2016 (Ls = 127°), and January 24, 2017 (Ls = 304°), by measuring simultaneously the abundances of H2O and HDO in the 1383–1391 cm−1 range (7.2 μm). The D/H disk-integrated values are 4.0 (+0.8, −0.6) × Vienna Standard Mean Ocean Water (VSMOW) and 4.5 (+0.7, −0.6) × VSMOW, respectively, in agreement with our earlier result. The main result of this study is that there is no evidence of strong local variations in the D/H ratio nor for seasonal variations in the global D/H ratio between northern summer and southern summer.
General Circulation Models with interactive physical and chemistry processes are the state-of-the-art tools for an integrated view and understanding of the Martian atmosphere and climate system. The ...GEM-Mars model currently includes 16 tracers for chemical composition and applies a fully online, interactive calculation of the photo- and gas phase chemistry of carbon dioxide (CO2) and water vapor (H2O). These species largely control the chemical composition of the neutral Mars atmosphere through their photolysis products and their subsequent interactions. Water vapor undergoes a complex cycle on Mars as it is transported and interacts with ice reservoirs both at the planet's surface and at water ice clouds, which in turn provide radiative feedbacks. In the photochemical cycles involving CO2 and H2O, the abundances of 5 species have been reported by previous investigations with significant spatio-temporal coverage: CO2, H2O, CO, O3 and H2O2. This paper presents the current status of the atmospheric chemistry simulations in GEM-Mars by comparing them to a selection of these observational datasets as well as to oxygen dayglow emission from O2(a1∆g). The results are consistent with previous model-data comparisons and illustrate that the water cycle and the photochemistry are well implemented in the model. In particular, the simulation of the key reservoir species H2O2 provides a good match to the available data. Model-data biases for ozone columns and oxygen airglow are related to the simulated water vapor vertical profile, as these species have important column contributions from vertical layers at the top of the hygropause.
•GEM-Mars is a global Mars atmospheric model with online atmospheric chemistry.•Comparisons to a broad set of observations show good performance.•Good simulation of CO2, CO, H2O, H2O2, O3 and O2(a1∆g) airglow•Model-data bias for O3 relates to biases in the simulated water vertical profile.•Middle-atmospheric water excess related to excessive heating by water ice clouds
► A comprehensive search for organics and trace species on Mars. ► For most of the targeted species we derived the most stringent upper limits ever obtained. ► We sampled the same regions where ...plumes of methane have been recently observed.
Is Mars actively releasing organic and other minor gases into the atmosphere? We present a comprehensive search for trace species on Mars, targeting multiple volatile organic species (CH4, CH3OH, H2CO, C2H6, C2H2, C2H4), hydroperoxyl (HO2), several nitrogen compounds (N2O, NH3, HCN), and two chlorine species (HCl, CH3Cl) through their rovibrational spectra in the 2.8–3.7μm spectral region. The data were acquired over a period of 4years (2006–2010) using powerful infrared high-resolution spectrometers (CRIRES, NIRSPEC, CSHELL) at high-altitude observatories (VLT, Keck-2, NASA-IRTF), and span a broad range of seasons, Doppler shifts and spatial coverage. Here, we present results from a selection of high-quality spectra obtained on four separate dates, representing a fraction of our search space. For most of these species we derived the most stringent upper limits ever obtained, and because the targeted gases have substantially different resident lifetimes in the Martian atmosphere (from hours to centuries), our measurements not only test for current release but also provide stringent limits on the quiescent levels. In particular, we sampled the same regions where plumes of methane have been recently observed (e.g., Syrtis Major and Valles Marineris), allowing us to test for seasonal and temporal variability.
Context. Carbon monoxide (CO) has been detected in all giant planets and its origin is both internal and external in Jupiter and Neptune. Despite its first detection in Uranus a decade ago, the ...magnitude of its internal and external sources remains unconstrained. Aims. We targeted CO lines in Uranus in the submillimeter range to constrain its origin. Methods. We recorded the disk-averaged spectrum of Uranus with very high spectral resolution at the frequencies of CO rotational lines in the submillimeter range in 2011−2012. We used empirical and diffusion models of the atmosphere of Uranus to constrain the origin of CO. We also used a thermochemical model of its troposphere to derive an upper limit on the oxygen-to-hydrogen (O/H) ratio in the deep atmosphere of Uranus. Results. We have detected the CO(8−7) rotational line for the first time with Herschel-HIFI. Both empirical and diffusion models results show that CO has an external origin. An empirical profile in which CO is constant above the 100 mbar level with a mole fraction of 7.1−9.0 × 10-9, depending on the adopted stratospheric thermal structure, reproduces the data. Sporadic and steady source models cannot be differentiated with our data. Taking the internal source model upper limit of a mole fraction of 2.1 × 10-9 we find, based on our thermochemical computations, that the deep O/H ratio of Uranus is less than 500 times solar. Conclusions. Our work shows that the average mole fraction of CO decreases from the stratosphere to the troposphere and thus strongly advocates for an external source of CO in Uranus. Photochemical modeling of oxygen species in the atmosphere of Uranus and more sensitive observations are needed to reveal the nature of the external source.
The Atmospheric Chemistry Suite (ACS) package is an element of the Russian contribution to the ESA-Roscosmos ExoMars 2016 Trace Gas Orbiter (TGO) mission. ACS consists of three separate infrared ...spectrometers, sharing common mechanical, electrical, and thermal interfaces. This ensemble of spectrometers has been designed and developed in response to the Trace Gas Orbiter mission objectives that specifically address the requirement of high sensitivity instruments to enable the unambiguous detection of trace gases of potential geophysical or biological interest. For this reason, ACS embarks a set of instruments achieving simultaneously very high accuracy (ppt level), very high resolving power (>10,000) and large spectral coverage (0.7 to 17 μm—the visible to thermal infrared range). The near-infrared (NIR) channel is a versatile spectrometer covering the 0.7–1.6 μm spectral range with a resolving power of ∼20,000. NIR employs the combination of an echelle grating with an AOTF (Acousto-Optical Tunable Filter) as diffraction order selector. This channel will be mainly operated in solar occultation and nadir, and can also perform limb observations. The scientific goals of NIR are the measurements of water vapor, aerosols, and dayside or night side airglows. The mid-infrared (MIR) channel is a cross-dispersion echelle instrument dedicated to solar occultation measurements in the 2.2–4.4 μm range. MIR achieves a resolving power of >50,000. It has been designed to accomplish the most sensitive measurements ever of the trace gases present in the Martian atmosphere. The thermal-infrared channel (TIRVIM) is a 2-inch double pendulum Fourier-transform spectrometer encompassing the spectral range of 1.7–17 μm with apodized resolution varying from 0.2 to 1.3 cm
−1
. TIRVIM is primarily dedicated to profiling temperature from the surface up to ∼60 km and to monitor aerosol abundance in nadir. TIRVIM also has a limb and solar occultation capability. The technical concept of the instrument, its accommodation on the spacecraft, the optical designs as well as some of the calibrations, and the expected performances for its three channels are described.
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