Directive 2000/60/EC requires the achievement of a 'good chemical status' for surface water within pre-established dates. Disinfection is needed to achieve compulsory final microbial limit values (in ...Italy for wastewater discharges the parameter Escherichia coli - EC - is imposed by law with a maximum limit value of 5,000 cfu/100 mL). Liquid waste and disinfection by-products must be considered when designing appropriate monitoring of dangerous substances; the specific classes of substances must be investigated according to the typology of received wastewaters and liquid wastes (where applicable) and specific analytical techniques, with Limit of Detection (LOD) lower than the limit values, must be applied; the difficulties faced by national and regional environmental control Agencies is that these techniques have to be applied during ordinary activity and not only for research purposes. The study aims to present the control of dangerous substances, as a screening view, in wastewater treatment plant (WWTP) discharges in the province of Venice (Northern Italy) for the period 2007-2010 based on available data from institutional controls. In addition, the wastewater disinfection process with ozone applied to a medium size WWTP (45,000 Population Equivalents) is presented as a case study, with a view to assessing the microbiological abatement efficacy and the presence of dangerous substances. Discharge quality of the WWTPs in the province of Venice presented mean values that were higher than the LOD, but only for certain metals. For the Paese plant, zinc and chloroform were the only micro-pollutants detected with a higher level than the LOD. From microbiological data in the period 2006-2011 the disinfection abatement efficiency for Paese was, in most cases above 99% for EC, faecal coliform (FC), faecal streptococci (FS) while efficiency was slightly lower for total coliform (TC); however, the proposed criterion aimed at respecting 99.99% abatement was not completely satisfied. Therefore, despite the high organic and industrial load of the considered plant and the need to find an alternative system for chlorine, as chlorine disinfection has been banned in the Veneto region since December 2012, ozone efficiency is not completely satisfactory and other systems such as peracetic or performic acids and UV systems must be considered.
Abstract
Wastewater treatment plants (WWTPs) are scrutinized by Environmental Authorities particularly regarding the compliance to discharge limit values fixed by national and local regulations. An ...integrated approach is necessary to achieve the objectives established with Directive 2000/60/EC (WFD) considering the ecological status of the receiving water body and the quality of the discharge. Specifically, documentary, technical, management and analytical controls should be developed. Moreover, integrative information on the behaviour of the activated sludge in the aeration tank can be useful for plant managers as well as for the regulating Authorities. The study presents the experience concerning WWTP regulation considering the analytic assessment of the discharge as well the monitoring of the Sludge Biotic Index (SBI) for activated sludge. Data from monitoring during the period 2008–14 on SBI values and chemical and microbiological data on the discharges of a sample of 35 WWTPs in the province of Venice (north-east Italy, Veneto region) are presented and discussed. Together with chemical and microbiological analysis, the SBI appears to be a highly useful index for the integrative assessment of plant functionality, in particular when monitoring and identifying critical situations that can determine the exceedance of discharge limit values. The SBI method, in an integrated control approach, can be used for small and medium sized WWTPs that only treat domestic wastewaters. In a case by case assessment this may even substitute part of the analytical monitoring carried out in the WWTPs' control process.
Energy saving is an ever increasing need not only as a result of the growth in energy global demand and as a result of progressive erosion of supply sources. Another reason is that the environmental ...impact deriving from energy use is becoming more and more a reason for concern (60% increase of CO2 emissions over the last 30 years). Rationalizing energy use therefore is a goal in relation to global energy policies. Recently the European Union has developed a plan to reduce energy consumption (20% by 2020): it has issued rules and guidelines targeted at efficiency improvement in different areas such as infrastructure, products, processes and services. Energy saving is therefore a must in wastewater treatment, but one needs to achieve this target without damaging the process. That said, the objective could be reached only by acting contemporarily on technologies and relative selection criteria, designing procedures and, last but not least, Waste Water Treatment Plant monitoring and management practices. This paper focuses on these different areas pointing out opportunities, benefits and possible setbacks in relation to process performance, highlighting the impact of management operations. Starting from simple management variables, it also contains an example concerning the necessary instruments and the coordination of controls needed to regularly evaluate intervention needs and available margins. This paper also deals with the consequences of technologies encouraged as solutions for stable and effective processes, but which are in clear contrast to energy saving goals.
Cosmic rays are particles (mostly protons) accelerated to relativistic speeds. Despite wide agreement that supernova remnants (SNRs) are the sources of galactic cosmic rays, unequivocal evidence for ...the acceleration of protons in these objects is still lacking. When accelerated protons encounter interstellar material, they produce neutral pions, which in turn decay into gamma rays. This offers a compelling way to detect the acceleration sites of protons. The identification of pion-decay gamma rays has been difficult because high-energy electrons also produce gamma rays via bremsstrahlung and inverse Compton scattering. We detected the characteristic pion-decay feature in the gamma-ray spectra of two SNRs, IC 443 and W44, with the Fermi Large Area Telescope. This detection provides direct evidence that cosmic-ray protons are accelerated in SNRs.
Pulsar wind nebulae (PWNe) have been established as the most populous class of TeV gamma-ray emitters. Since launch, the Fermi Large Area Telescope (LAT)identified five high-energy (100MeV <E< 100 ...GeV) gamma-ray sources as PWNe, and detected a large number of PWNe candidates, all powered by young and energetic pulsars. The wealth of multi-wavelength data available and the new results provided by Fermi-LAT give us an opportunity to find new PWNe and to explore the radiative processes taking place in known ones. The TeV gamma-ray unidentifiedsources (UNIDs) are the best candidates for finding new PWNe. Using 45 months of Fermi-LAT data for energies above 10 GeV, an analysis was performed near the position of 58TeV PWNe and UNIDs within 5deg of the Galactic Plane to establish new constraints on PWNe properties and find new clues on the nature of UNIDs. Of the 58 sources, 30 were detected, and this work provides their gamma-rayfluxes for energies above 10 GeV. The spectral energy distributions (SED) andupper limits, in the multi-wavelength context, also provide new information on the source nature and can help distinguish between emission scenarios, i.e. between classification as a pulsar candidate or as a PWN candidate. Six new GeV PWNe candidates are described in detail and compared with existing models. A population study of GeV PWNe candidates as a function of the pulsar/PWN system characteristics is presented.
The geological map of Piemonte Region (Italy) is a graphic representation of the geology of the region, grounded on a large geodatabase, that can be also browsed as an interactive scalable map ...(GeoPiemonte Map) using a WebGIS application. The Map, produced at 1:250,000 scale, is the first original release of the 'GeoPiemonte Map' project. The geological data represented on the map derive from a thorough revision of available geological maps and literature, integrated with unpublished original data. The revision and harmonisation of existing and new data have been based on explicit criteria used for the classification of geologic units and their representation on the Map. These criteria firstly aimed at providing a lithostratigraphic, hierarchic subdivision of Piemonte geologic units and describing them using shared concepts and vocabularies, consistent with IUGS Descriptive Standards for the Geosciences.
The response to reactive electrophile species (RES) is now considered as part of the plant response to pathogen and insect attacks. Thanks to a previously established high-performance liquid ...chromatography tandem mass spectrometry methodology, we have investigated the production of oxylipin RES adducts to glutathione (GSH) during the hypersensitive response (HR) of plants. We have observed that RES conjugation to GSH in tobacco (Nicotiana tabacum) leaves is facile and nonspecific. In cryptogein-elicited tobacco leaves, we show that the oxylipin RES adducts to GSH are produced in correlation with GSH consumption, increase in glutathione S-transferase activity, and the appearance of the cell death symptoms. In this model, the adducts arise mainly from the downstream 13 lipoxygenase (LOX) metabolism, although the induced 9 LOX pathway leads massively to the accumulation of upstream metabolites. The main adducts were obtained from 2-hexenal and 12-oxo-phytodienoic acid. They accumulate transiently as 1-hexanol-3-GSH, a reduced adduct, and 12-oxo-phytodienoic acid-GSH, respectively. RES conjugation does not initiate cell death but explains part of the GSH depletion that accompanies HR cell death. The nature of these GSH conjugates shows the key role played by the 13 LOX pathway in RES signaling in the tobacco HR.
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