•B2- Cu-enriched precipitates exist in the studied model alloys.•The maximum contribution to precipitation hardening is attributed to Cu-enriched precipitates.•Ni addition led to relatively higher ...precipitation nucleation and growth of Cu-enriched precipitates.•Small-angle scattering could provide better details when analyzing nano-sized precipitates.
To better understand the mechanisms of thermally aged and embrittled reactor pressure vessel steels, the hardening behavior and microstructure evolution of different Fe-Cu and Fe-Cu-Ni model alloys were investigated using transmission electron microscopy (TEM) and small-angle neutron scattering (SANS) analysis methods. The effects of different aging conditions and alloy composition on the formation and growth of Cu-enriched precipitates were discussed. The results showed that the hardness of the Fe-Cu model alloys with low copper content continuously increased with aging, increasing to peak hardness and then decreasing for the Fe-Cu model alloys with high copper content. The aging time to reach peak hardness was greatly reduced due to the addition of Ni in the Fe-Cu model alloys. The TEM results showed that with increased aging temperature and copper content, the Cu-enriched precipitates with a B2 structure precipitated in the ferritic matrix following a direct relationship. Therefore, Ni addition led to relatively higher precipitation nucleation and growth, and the size distribution of the Cu-enriched precipitates derived from the SANS was in overall good agreement with the TEM observations for 6–25 nm regions. Therefore, small-angle scattering could provide better details when analyzing smaller, nano-sized precipitates.
17-4PH martensitic steel is usually used as valve stems in nuclear power plants and it suffers from thermal aging embrittlement due to long-time service in a high-temperature and high-pressure ...environment. Here, we characterized the evolution of microstructures at the nano-scale in 17-4PH steel by in situ small-angle neutron scattering (SANS) with a thermo-mechanically coupled loading device. The device could set different temperatures and tensile so that an in situ SANS experiment could dynamically characterize the process of nanoscale structural changes. The results showed that with increasing thermal aging time, the ε-Cu phase precipitates and grows as the temperature is 475 °C and 590 °C, and the ε-Cu phase is spherical at 475 °C but became elongated cylinders at 590 °C. Moreover, the loading stress could aid in the growth of the ε-Cu phase at 475 °C.
The advantages of time of flight method enable it to be widely used on stationary reactors. In this study, we reported several typical applications of time of flight method on the China Advanced ...Research Reactor (CARR). First, a new solution is designed to measure the beam characteristics including wavelengths, wavelength resolution rates and intensities of HOPG(002) monochromator for the unfiltered and filtered cases. Second, the changes in neutron wavelength spectra on the cross section of curved neutron guide CNGB end were examined and studied. It can be concluded that evident shape changes between neutron wavelength spectra along horizontal direction are mainly caused by the horizontal curving of curved neutron guide and dips at other wavelengths apart from 4 Å are mainly caused by small radius of curvature of curved neutron guide. Third, based on neutron velocity selector of small angle neutron scattering instrument at CARR, a calibration instrument is designed, and calibration experiments are conducted and simulated. The results indicate that the discrepancy between the experimental wavelength resolution rate and the theoretical one is caused by beam divergence linked with the critical reflection angle of neutron guide coating and the difference between experimental wavelength and the theoretical one is caused by the shape change of source neutron wavelength spectrum. These findings are reported here for the first time.
Microstructure evolution and mechanical properties in an Fe-17Cr-4Ni-4Cu alloy aged at 475 °C after different aging times were studied. Conventional transmission electron microscopy (TEM) and ...high-resolution electron microscopy (HREM) studies revealed the formation of 9R-structure Cu-rich precipitates and Cr-rich α’ phase by spinodal decomposition in the samples aged at 475 °C after 100–1000 h. The fine Cu-rich precipitates and Cr-rich α’ phase by spinodal decomposition lead to a significant increase in the hardness, together in the early stages (100 h). Continued aging to 500 h leads to increased precipitation of the Cr-rich α’, which provides significant strengthening, reaching maximum hardening, despite the continued loss of hardening by weakening by the Ostwald ripening of the Cu-rich precipitates. Extending the aging time to 1000 h leads to substantial reversed austenite transformation and a large number of ripening -copper precipitates that causes softening. The results of the impact tests showed that the major fracture mode was cleavage and/or quasi-cleavage.
