Serpentine, recently discovered on Mars using Mars Reconnaissance Orbiter data, is uncommon but found in three geologic settings: (1) in mélange terrains at the Claritas Rise and the Nili Fossae, (2) ...associated with a few southern highlands impact craters, and (3) associated with a regional olivine‐rich stratigraphic unit near the Isidis basin. Any presently active serpentinization processes would be occurring beneath the surface and mineral products would not be apparent with surface and orbital data; however, finding serpentine in several Noachian terrains indicates active serpentinization processes in Mars' past. Important implications are the past production of magnetite, which may contribute to chemical remnant magnetization of Mars' crust, and production of H2, which is a suitable energy source for chemosynthetic microbial life.
Definitive exposures of pristine, ancient crust on Mars are rare, and the finding that much of the ancient Noachian terrain on Mars exhibits evidence of phyllosilicate alteration adds further ...complexity. We have analyzed high‐resolution data from the Mars Reconnaissance Orbiter in the well‐exposed Noachian crust surrounding the Isidis basin. We focus on data from the Compact Reconnaissance Imaging Spectrometer for Mars as well as imaging data sets from High Resolution Imagine Science Experiment and Context Imager. These data show the lowermost unit of Noachian crust in this region is a complex, brecciated unit of diverse compositions. Breccia blocks consisting of unaltered mafic rocks together with rocks showing signatures of Fe/Mg‐phyllosilicates are commonly observed. In regions of good exposure, layered or banded phyllosilicate‐bearing breccia rocks are observed suggestive of pre‐Isidis sedimentary deposits. In places, the phyllosilicate‐bearing material appears as a matrix surrounding mafic blocks, and the mafic rocks show evidence of complex folded relationships possibly formed in the turbulent flow during emplacement of basin‐scale ejecta. These materials likely include both pre‐Isidis basement rocks as well as the brecciated products of the Isidis basin–forming event at 3.9 Ga. A banded olivine unit capped by a mafic unit covers a large topographic and geographic range from northwest of Nili Fossae to the southern edge of the Isidis basin. This olivine‐mafic cap combination superimposes the phyllosilicate‐bearing basement rocks and distinctly conforms to the underlying basement topography. This may be due to draping of the topography by a fluid or tectonic deformation of a previously flatter lying morphology. We interpret the draping, superposed olivine‐mafic cap combination to be impact melt from the Isidis basin–forming event. While some distinct post‐Isidis alteration is evident (carbonate, kaolinite, and serpentine), the persistence of olivine from the time of Isidis basin suggests that large‐scale aqueous alteration processes had ceased by the time this unit was emplaced.
Phyllosilicates, a class of hydrous mineral first definitively identified on Mars by the OMEGA (Observatoire pour la Mineralogie, L'Eau, les Glaces et l'Activitié) instrument, preserve a record of ...the interaction of water with rocks on Mars. Global mapping showed that phyllosilicates are widespread but are apparently restricted to ancient terrains and a relatively narrow range of mineralogy (Fe/Mg and Al smectite clays). This was interpreted to indicate that phyllosilicate formation occurred during the Noachian (the earliest geological era of Mars), and that the conditions necessary for phyllosilicate formation (moderate to high pH and high water activity) were specific to surface environments during the earliest era of Mars's history. Here we report results from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) of phyllosilicate-rich regions. We expand the diversity of phyllosilicate mineralogy with the identification of kaolinite, chlorite and illite or muscovite, and a new class of hydrated silicate (hydrated silica). We observe diverse Fe/Mg-OH phyllosilicates and find that smectites such as nontronite and saponite are the most common, but chlorites are also present in some locations. Stratigraphic relationships in the Nili Fossae region show olivine-rich materials overlying phyllosilicate-bearing units, indicating the cessation of aqueous alteration before emplacement of the olivine-bearing unit. Hundreds of detections of Fe/Mg phyllosilicate in rims, ejecta and central peaks of craters in the southern highland Noachian cratered terrain indicate excavation of altered crust from depth. We also find phyllosilicate in sedimentary deposits clearly laid by water. These results point to a rich diversity of Noachian environments conducive to habitability.
A previously unidentified artifact has been found in Compact Reconnaissance Imaging Spectrometer for Mars targeted I/F data. It exists in a small fraction (<0.05%) of pixels within 90% of images ...investigated and occurs in regions of high spectral/spatial variance. This artifact mimics real mineral absorptions in width and depth and occurs most often at 1.9 and 2.1 μm, thus interfering in the search for some mineral phases, including alunite, kieserite, serpentine, and perchlorate. A filtering step in the data processing pipeline, between radiance and I/F versions of the data, convolves narrow artifacts (“spikes”) with real atmospheric absorptions in these wavelength regions to create spurious absorption‐like features. The majority of previous orbital detections of alunite, kieserite, and serpentine we investigated can be confirmed using radiance and raw data, but few to none of the perchlorate detections reported in published literature remain robust over the 1.0‐ to 2.65‐μm wavelength range.
Plain Language Summary
Many minerals can be identified with remote sensing data by their characteristic absorptions in visible‐shortwave infrared data. This type of data has allowed geological interpretation of much of Mars' surface, using satellite‐based observation. We have discovered an issue with the Compact Reconnaissance Imaging Spectrometer for Mars instrument's data processing pipeline. In ~ <0.05% of pixels in almost all images, noise in the data is smoothed in such a way that it mimics real mineral absorptions, falsely making it look as though certain minerals are present on Mars' surface. The vast majority of previously identified minerals are still confirmed after accounting for the artifact, but some to all perchlorate detections and a few serpentine detections were not confirmed, suggesting that the artifact created false detections. This means concentrated regions of perchlorate may not occur on Mars and so may not be available to generate possibly habitable salty liquid water at very cold temperatures.
Key Points
A filtering step in conversion to I/F can cause few‐pixel artifacts in high variance regions of a CRISM image cube
Orbital detections of perchlorate and some serpentine on Mars may not be robust, instead caused by the newly discovered artifact
Few‐pixel mineral detections using visible‐shortwave infrared reflectance spectroscopy should be confirmed with radiance data
Columbus crater in the Terra Sirenum region of the Martian southern highlands contains light‐toned layered deposits with interbedded sulfate and phyllosilicate minerals, a rare occurrence on Mars. ...Here we investigate in detail the morphology, thermophysical properties, mineralogy, and stratigraphy of these deposits; explore their regional context; and interpret the crater's aqueous history. Hydrated mineral‐bearing deposits occupy a discrete ring around the walls of Columbus crater and are also exposed beneath younger materials, possibly lava flows, on its floor. Widespread minerals identified in the crater include gypsum, polyhydrated and monohydrated Mg/Fe‐sulfates, and kaolinite; localized deposits consistent with montmorillonite, Fe/Mg‐phyllosilicates, jarosite, alunite, and crystalline ferric oxide or hydroxide are also detected. Thermal emission spectra suggest abundances of these minerals in the tens of percent range. Other craters in northwest Terra Sirenum also contain layered deposits and Al/Fe/Mg‐phyllosilicates, but sulfates have so far been found only in Columbus and Cross craters. The region's intercrater plains contain scattered exposures of Al‐phyllosilicates and one isolated mound with opaline silica, in addition to more common Fe/Mg‐phyllosilicates with chlorides. A Late Noachian age is estimated for the aqueous deposits in Columbus, coinciding with a period of inferred groundwater upwelling and evaporation, which (according to model results reported here) could have formed evaporites in Columbus and other craters in Terra Sirenum. Hypotheses for the origin of these deposits include groundwater cementation of crater‐filling sediments and/or direct precipitation from subaerial springs or in a deep (∼900 m) paleolake. Especially under the deep lake scenario, which we prefer, chemical gradients in Columbus crater may have created a habitable environment at this location on early Mars.
•CRISM mapping reveals Pre-/Early-Noachian alteration is discontinuous in the crust.•Higher temperature alteration assemblages occur in Eastern Coprates Chasma.•Assemblage constrains lateral offset ...of Valles Marineris to less than ∼25–50km.•Evidence for thrust faulting in western Coprates Chasma with compositional mapping.•Diverse Noachian primary mineralogy (LCP dominates, +/− plagioclase and olivine).
Identification and mapping of distinct compositional units using high-resolution orbital imagery of the walls of Valles Marineris, Mars, provide key structural and environmental constraints on the geologic history of the eastern Tharsis Rise. Our results corroborate an overall vertical structure of the upper crust consistent with that inferred from previous studies. An upper unit spectrally consistent with basalt that has variable thickness is overlain on an early to possibly pre-Noachian substrate. The pre-/early-Noachian material is heterogeneous, dominated by low-calcium pyroxene-rich material but ranging locally from feldspathic to and olivine-rich. Aqueous alteration of pre-/early-Noachian rock to dominantly Fe/Mg-smectite is widespread and observed along the chasma walls from −4 to 1km. However phyllosilicates outcrop discontinuously, suggesting that they were emplaced via impact excavation of even older altered material, or formed by non-uniform alteration driven by impact- or magma-related hydrothermal activity. A distinct, higher-temperature alteration assemblage identified by the presence of chlorite, zeolite, and associated carbonate (+/−serpentine) occurs on both the north and south walls of eastern Coprates Chasma in a confined longitudinal band, where the eastern margin of the Thaumasia Plateau intersects Valles Marineris. These secondary minerals are concentrated within a heavily fractured band exposed at a regional tectonic boundary along the margin of the Thaumasia Plateau, and likely record a regional zone of elevated crustal heat flow and fluid circulation. The generally north–south trending band exhibiting this distinct assemblage serves as a tracer for tectonic deformation; its continuity across Valles Marineris is incongruous with previously suggested lateral slip along the margin of a ‘megaslide’, and constrains left-lateral transtensional faulting to less than ∼25–50km. Mapping of compositionally distinct outcrops to the west also reveals localized uplift in western Coprates Chasma, suggesting thrust faults underlying wrinkle ridges. In western Valles Marineris, the upper basalt layer thickens dramatically, supporting either occurrence of a large, infilled basin to the west, or down-dropping and volcanic burial of material near Melas/Candor Chasma, the latter consistent with a constructional origin of the Tharsis Rise.
•A clay-bearing layer is detected within the sulfate-rich deposits of Meridiani Planum.•Landscape formation such as karst emplacement seems mineralogy-driven.•The regional mineralogy and geology is ...best explained by surficial and groundwater processes.
The area of Meridiani Planum on Mars became of particular interest after the detection of coarse-grained, gray hematite, which led to the choice of this region as final landing site for the Mars Exploration Rover Opportunity. Multiple additional minerals have since been detected in the region, both from orbit and in situ. The present paper reassesses in detail the mineralogy and geomorphology of the area (between 3.5°S to 6.5°N latitude and 8.0°W to 8.0°E longitude) using visible and near-infrared hyperspectral data, merged with high spatial resolution images into a Geographic Information System. Fe/Mg-rich phyllosilicates, as well as several types of sulfates are identified within the kilometer of sedimentary deposits constituting the etched terrains and the overlying hematite-rich plains. The mineralogical stratigraphy of the etched terrains is characterized by a sulfate-rich unit, enriched in Fe/Mg-rich clays in its uppermost part. This clay-rich horizon is capped by another sulfate-rich unit, of different composition, associated with hematite detections and constituting the material of the hematite plains unit. The clay-bearing unit, which directly underlies the hematite plains, may be exposed in the rim of Endeavour Crater and could correspond to the material that is currently being analyzed by Opportunity. Diverse landforms including karsts and pan features are observed at the surface of the hydrated etched terrains and indicate past surface water and potential groundwater aquifers. Our analysis reveals that both surficial water and groundwater processes are required to explain the diversity of morphologies and mineralogies observed in the area. Although orbital detections are consistent with the hematite and sulfate detections made in situ by Opportunity in the hematite plains, they also show the presence of a clay-rich horizon at depth, overlying another, thicker, possibly chemically distinct, sulfate-rich unit within the etched terrains. Therefore we conclude that the very acidic conditions that prevailed during the formation of the topmost sulfate-rich unit, as observed in Meridiani Planum and in the hematite plains by the rover Opportunity, are not representative of the entire history of the etched terrains. In contrast, most hydrated minerals in Meridiani Planum likely formed at more neutral pH, at the beginning of the Hesperian. The overall sulfate/clay/sulfate sequence is similar to the one observed in Gale Crater, the landing site of the Mars Science Laboratory rover.
•Examined visible/near infrared spectra (0.4–3.1μm) of Phobos and Deimos.•Fe2+ electronic absorptions diagnostic of olivine and pyroxene were not detected.•Absorptions centered around 0.65μm and ...2.8μm are detected on both moons.•Both absorptions are similar to features on low-albedo asteroids.•Absorptions caused by phyllosilicates or Fe-particles/solar wind implantation of H.
Absorption features on Phobos and Deimos in the visible/near infrared wavelength region (0.4–3.9μm) are mapped using observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Fe2+ electronic absorptions diagnostic of olivine and pyroxene are not detected. A broad absorption centered around 0.65μm within the red spectral units of both moons is detected, and this feature is also evident in telescopic, Pathfinder, and Phobos-2 observations of Phobos. A 2.8μm metal–OH combination absorption on both moons is also detected in the CRISM data, and this absorption is shallower in the Phobos blue unit than in the Phobos red unit and Deimos. The strength, position, and shape of both of the 0.65μm and 2.8μm absorptions are similar to features seen on red-sloped, low-albedo primitive asteroids. Two end-member hypotheses are presented to explain the spectral features on Phobos and Deimos. The first invokes the presence of highly desiccated Fe-phyllosilicate minerals indigenous to the bodies, and the second invokes Rayleigh scattering and absorption of small iron particles formed by exogenic space weathering processing, coupled with implantation of H from solar wind. Both end-member hypotheses may play a role, and in situ exploration will be needed to ultimately determine the underlying causes for the pair of spectral features observed on Phobos and Deimos.
Ancient Aqueous Environments at Endeavour Crater, Mars Arvidson, R. E.; Squyres, S. W.; Bell, J. F. ...
Science (American Association for the Advancement of Science),
01/2014, Letnik:
343, Številka:
6169
Journal Article
Recenzirano
Odprti dostop
Opportunity has investigated in detail rocks on the rim of the Noachian age Endeavour crater, where orbital spectral reflectance signatures indicate the presence of Fe(+3)-rich smectites. The ...signatures are associated with fine-grained, layered rocks containing spherules of diagenetic or impact origin. The layered rocks are overlain by breccias, and both units are cut by calcium sulfate veins precipitated from fluids that circulated after the Endeavour impact. Compositional data for fractures in the layered rocks suggest formation of Al-rich smectites by aqueous leaching. Evidence is thus preserved for water-rock interactions before and after the impact, with aqueous environments of slightly acidic to circum-neutral pH that would have been more favorable for prebiotic chemistry and microorganisms than those recorded by younger sulfate-rich rocks at Meridiani Planum.
The earliest formed crust on a single plate planet such as Mars should be preserved, deeply buried under subsequent surface materials. Mars' extensive cratering history would have fractured and ...disrupted the upper layers of this ancient crust. Large impacts occurring late in Martian geologic history would have excavated and exposed this deeply buried material. We report the compositional analysis of unaltered mafic Martian crater central peaks with high‐resolution spectral data that was used to characterize the presence, distribution and composition of mafic mineralogy. Reflectance spectra of mafic outcrops are modeled with the Modified Gaussian Model (MGM) to determine cation composition of olivine and pyroxene mineral deposits. Observations show that central peaks with unaltered mafic units are only observed in four general regions of Mars. Each mafic unit exhibits spectrally unmixed outcrops of olivine or pyroxene, indicating dunite and pyroxenite dominated compositions instead of basaltic composition common throughout much of the planet. Compositional analysis shows a wide range of olivine Fo# ranging from Fo60 to Fo5. This variation is best explained by a high degree of fractionation in a slowly cooling, differentiating magma body. Pyroxene analysis shows that all the sites in the Southern Highlands are consistent with moderately Fe‐rich, low‐Ca pyroxene. Mineral segregation in the ancient crust could be caused by cumulate crystallization and settling in a large, potentially global, lava lake or near surface plutons driven by a hypothesized early Martian mantle overturn.
Key Points
Martian central peaks can access the deepest exposed crust on Mars
The unaltered central peaks have units of olivine or pyroxene but not both
The deep (ancient) crust of Mars has a high degree of mafic segregation
PDF
