Molecular collisions in the quantum regime represent a new opportunity to explore chemical reactions. Recently, atom-exchange reactions were observed in a trapped ultracold gas of KRb molecules. In ...an external electric eld, these polar molecules can easily be oriented and the exothermic and barrierless bimolecular reactions, KRb + KRb ! K2 + Rb2, occur at a rate that rises steeply with increasing dipole moment. Here we demonstrate the suppression of the bimolecular chemical reaction rate by nearly two orders of magnitude when we use an optical lattice trap to conne the fermionic polar molecules in a quasi-two-dimensional, pancake-like geometry, with the dipoles oriented along the tight connement direction. With the combination of sufciently tight connement and Fermi statistics of the molecules, two polar molecules can approach each other only in a side-by-side collision under repulsive dipoledipole interactions. The suppression of chemical reactions is a prerequisite for the realization of new molecule-based quantum systems.
A quantum gas of ultracold polar molecules, with long-range and anisotropic interactions, not only would enable explorations of a large class of many-body physics phenomena but also could be used for ...quantum information processing. We report on the creation of an ultracold dense gas of potassium-rubidium (⁴⁰K⁸⁷Rb) polar molecules. Using a single step of STIRAP (stimulated Raman adiabatic passage) with two-frequency laser irradiation, we coherently transfer extremely weakly bound KRb molecules to the rovibrational ground state of either the triplet or the singlet electronic ground molecular potential. The polar molecular gas has a peak density of 10¹² per cubic centimeter and an expansion-determined translational temperature of 350 nanokelvin. The polar molecules have a permanent electric dipole moment, which we measure with Stark spectroscopy to be 0.052(2) Debye (1 Debye = 3.336 x 10⁻³⁰ coulomb-meters) for the triplet rovibrational ground state and 0.566(17) Debye for the singlet rovibrational ground state.
We present a novel slowing scheme for beams of laser-coolable diatomic molecules reminiscent of Zeeman slowing of atomic beams. The scheme results in efficient compression of the one-dimensional ...velocity distribution to velocities trappable by magnetic or magneto-optical traps. We experimentally demonstrate our method in an atomic testbed and show an enhancement of flux below v = 35 m s−1 by a factor of 20 compared to white light slowing. 3D Monte Carlo simulations performed to model the experiment show excellent agreement. We apply the same simulations to the prototype molecule 88Sr19F and expect 15% of the initial flux to be continuously compressed in a narrow velocity window at around 10 m s−1. This is the first experimentally shown continuous and dissipative slowing technique in molecule-like level structures, promising to provide the missing link for the preparation of large ultracold molecular ensembles.
Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range and spatially anisotropic. This is in stark contrast to the much ...studied dilute gases of ultracold atoms, which have isotropic and extremely short-range (or 'contact') interactions. Furthermore, the large electric dipole moment of polar molecules can be tuned using an external electric field; this has a range of applications such as the control of ultracold chemical reactions, the design of a platform for quantum information processing and the realization of novel quantum many-body systems. Despite intense experimental efforts aimed at observing the influence of dipoles on ultracold molecules, only recently have sufficiently high densities been achieved. Here we report the experimental observation of dipolar collisions in an ultracold molecular gas prepared close to quantum degeneracy. For modest values of an applied electric field, we observe a pronounced increase in the loss rate of fermionic potassium-rubidium molecules due to ultracold chemical reactions. We find that the loss rate has a steep power-law dependence on the induced electric dipole moment, and we show that this dependence can be understood in a relatively simple model based on quantum threshold laws for the scattering of fermionic polar molecules. In addition, we directly observe the spatial anisotropy of the dipolar interaction through measurements of the thermodynamics of the dipolar gas. These results demonstrate how the long-range dipolar interaction can be used for electric-field control of chemical reaction rates in an ultracold gas of polar molecules. Furthermore, the large loss rates in an applied electric field suggest that creating a long-lived ensemble of ultracold polar molecules may require confinement in a two-dimensional trap geometry to suppress the influence of the attractive, 'head-to-tail', dipolar interactions.
How does a chemical reaction proceed at ultralow temperatures? Can simple quantum mechanical rules such as quantum statistics, single partial-wave scattering, and quantum threshold laws provide a ...clear understanding of the molecular reactivity under a vanishing collision energy? Starting with an optically trapped near-quantum-degenerate gas of polar ⁴⁰K⁸⁷Rb molecules prepared in their absolute ground state, we report experimental evidence for exothermic atom-exchange chemical reactions. When these fermionic molecules were prepared in a single quantum state at a temperature of a few hundred nanokelvin, we observed p-wave-dominated quantum threshold collisions arising from tunneling through an angular momentum barrier followed by a short-range chemical reaction with a probability near unity. When these molecules were prepared in two different internal states or when molecules and atoms were brought together, the reaction rates were enhanced by a factor of 10 to 100 as a result of s-wave scattering, which does not have a centrifugal barrier. The measured rates agree with predicted universal loss rates related to the two-body van der Waals length.
Abstract
Magneto-optical trapping (MOT) is a key technique on the route towards ultracold molecular ensembles. However, the realization and optimization of magneto-optical traps with their wide ...parameter space is particularly difficult. Here, we present a very general method for the optimization of molecular magneto-optical trap operation by means of Bayesian optimization. As an example for a possible application, we consider the optimization of a calcium fluoride MOT for maximum capture velocity. We find that both the
X
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+
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2
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1/2
and the
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transition to allow for capture velocities with 24 m s
−1
and 23 m s
−1
respectively at a total laser power of 200 mW. In our simulation, the optimized capture velocity depends logarithmically on the beam power within the simulated power range of 25 to 400 mW. Applied to heavy molecules such as BaH, BaF, YbF and YbOH with their low capture velocity MOTs it might offer a route to far more robust MOT.
Polar molecules have bright prospects for novel quantum gases with long-range and anisotropic interactions, and could find uses in quantum information science and in precision measurements. However, ...high-density clouds of ultracold polar molecules have so far not been produced. Here, we report a key step towards this goal. We start from an ultracold dense gas of loosely bound 40K87Rb Feshbach molecules with typical binding energies of a few hundred kilohertz, and coherently transfer these molecules in a single transfer step into a vibrational level of the ground-state molecular potential bound by more than 10 GHz. Starting with a single initial state prepared with Feshbach association, we achieve a transfer efficiency of 84%. Given favourable Franck-Condon factors, the presented technique can be extended to access much more deeply bound vibrational levels and those exhibiting a significant dipole moment.
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