► The concentration of TBH was reduced by 90% following electrolysis with BDD/Ti. ► Electrolysis with BDD/Ti electrodes led to the removal of 80% of total organic carbon. ► The reduction and ...formation of the byproducts of TBH could be monitored by HPLC. ► Ion chromatography confirmed that the electrochemical breakdown of TBH with BDD/Ti. ► The least doped BDD was the more efficient.
The thiadiazolylurea derivative tebuthiuron (TBH) is commonly used as an herbicide even though it is highly toxic to humans. While various processes have been proposed for the removal of organic contaminants of this type from wastewater, electrochemical degradation has shown particular promise. The aim of the present study was to investigate the electrochemical degradation of TBH using anodes comprising boron-doped (5000 and 30000ppm) diamond (BDD) films deposited onto Ti substrates operated at current densities in the range 10–200mAcm−2. Both anodes removed TBH following a similar pseudo first-order reaction kinetics with kapp close to 3.2×10−2min−1. The maximum mineralization efficiency obtained was 80%. High-pressure liquid chromatography with UV–VIS detection established that both anodes degraded TBH via similar intermediates. Ion chromatography revealed that increasing concentrations of nitrate ions (up to 0.9ppm) were formed with increasing current density, while the formation of nitrite ions was observed with both anodes at current densities ⩾150mAcm−2. The BDD film prepared at the lower doping level (5000ppm) was more efficient in degrading TBH than its more highly doped counterpart. This unexpected finding may be explained in terms of the quantity of impurities incorporated into the diamond lattice during chemical vapor deposition.
This study investigated metal accumulation and oxidative effects in mantle, gill and digestive gland of the ribbed mussel Aulacomya atra from the Argentinean North Patagonian coastline. Mussels were ...transplanted over an 18-month period from a site with low anthropogenic impact to a harbor site with higher seawater concentration of aluminum, chromium, copper, manganese, nickel and zinc. Total trace metal concentration in seawater did not change throughout the 18-month transplant in either site. A. atra bioaccumulated metals in digestive gland, gills and mantle at different levels. Digestive gland had the highest concentration of metals, especially towards the end of the transplant experiment in the harbor area. Mussels transplanted to the harbor site experienced an upregulation in their antioxidant system, which likely explains the lack of oxidative damage to lipids despite higher metal accumulation. These results demonstrate that A. atra selectively accumulates metals from the water column and their prooxidant effects depend on the tissue antioxidant defenses and the exposure time.
•Aulacomya atra selectively accumulates metals from the water column.•atra bioaccumulated metals in digestive gland, gills and mantle at different levels.•Mussels transplanted to the harbor site experienced changes in tissue metal levels as well as pro-oxidant effects.•Pro-oxidant effects in A. atra will depend on the tissue antioxidant defenses and the time of exposure.
ABSTRACT We present a study of the angular resolution of the AGILE gamma-ray imaging detector (GRID) that has been operational in space since 2007 April. The AGILE instrument is made of an array of ...12 planes that are each equipped with a tungsten converter and silicon microstrip detectors, and is sensitive in the energy range 50 MeV-10 GeV. Among the space instruments devoted to gamma-ray astrophysics, AGILE uniquely exploit an analog readout system with dedicated electronics coupled with silicon detectors. We show the results of Monte Carlo simulations carried out to reproduce the gamma-ray detection by the GRID and we compare them to in-flight data. We use the Crab (pulsar + Nebula) system for discussion of real data performance, since its energy spectrum is representative of the majority of gamma-ray sources. For Crab-like spectrum sources, the GRID angular resolution (FWHM of at 100 MeV; at 1 GeV; integrating the full energy band from 100 MeV to tens of GeV) is stable across a large field of view, characterized by a flat response up to off-axis. A comparison of the angular resolution obtained by the two operational gamma-ray instruments, AGILE/GRID and Fermi/LAT (Large Area Telescope), is interesting in view of future gamma-ray missions, which are currently under study. The two instruments exploit different detector configurations that affect the angular resolution: the former is optimized in the readout and track reconstruction, especially in the low-energy band, the latter is optimized in terms of converter thickness and power consumption. We show that despite these differences, the angular resolution of both instruments is very similar, between 100 MeV and a few GeV.
ABSTRACT We report the results of an extensive search through the AGILE data for a gamma-ray counterpart to the LIGO gravitational-wave (GW) event GW150914. Currently in spinning mode, AGILE has the ...potential of cover 80% of the sky with its gamma-ray instrument, more than 100 times a day. It turns out that AGILE came within a minute of the event time of observing the accessible GW150914 localization region. Interestingly, the gamma-ray detector exposed ∼65% of this region during the 100 s time intervals centered at −100 and +300 s from the event time. We determine a 2 flux upper limit in the band 50 MeV-10 GeV, UL = 1.9 × 10−8 erg cm−2 s−1, obtained ∼300 s after the event. The timing of this measurement is the fastest ever obtained for GW150914, and significantly constrains the electromagnetic emission of a possible high-energy counterpart. We also carried out a search for a gamma-ray precursor and delayed emission over five timescales ranging from minutes to days: in particular, we obtained an optimal exposure during the interval −150/−30 s. In all these observations, we do not detect a significant signal associated with GW150914. We do not reveal the weak transient source reported by Fermi-GBM 0.4 s after the event time. However, even though a gamma-ray counterpart of the GW150914 event was not detected, the prospects for future AGILE observations of GW sources are decidedly promising.
The aim of this work was to assess the effects of 1 week copper exposure (6.2, 108, 210 and 414
μM) on
Scenedesmus vacuolatus and
Chlorella kessleri. The strains showed different susceptibility to ...copper. Copper content was determined in both strains by total X-ray reflection fluorescence analysis (TXRF). In
S. vacuolatus, the increase of medium copper concentration induced an augmentation of protein and MDA content, and a significant decrease in the chlorophyll
a/chlorophyll
b ratio.
S. vacuolatus showed a significant increase of catalase activity in 210 and 414
μM of copper, and a significant increment of SOD activity and GSH content only in 414
μM of copper. On the contrary,
C. kessleri did not show significant differences in these parameters between 6.2 and 108
μM of copper. Increased copper in the environment evokes oxidative stress and an increase in the antioxidant defenses of
S. vacuolatus.
Vertical patellar dislocations (VPDs) are a rare event, and even more so among pediatric female patients. There have been less than 30 vertical patellar dislocations reported in the literature since ...the first in 1844. In this type of dislocation, the patella rotates about its vertical axis with the articular surface facing either medially or laterally. The mechanism of injury for a VPD can be broadly divided into two themes: a twisting injury or direct impact to the medial or lateral edge of the patella. We present a 10-year-old girl with a VPD after experiencing a twisting injury when descending a playground slide. The purpose of this study is to present a case report and review of the literature on vertical patella dislocations, including mechanisms of injury and suggested methods of treatment. We aim to provide a comprehensive understanding of the various categories of patella dislocations to alleviate confusion when classifying patellar dislocations. Furthermore, we provide clear suggestions for reduction methods and techniques with regards to vertical patellar dislocations, including a suggested protocol for an irreducible patella.
Gamma-ray emission from the Crab Nebula has been recently shown to be unsteady. In this paper, we study the flux and spectral variability of the Crab above 100 MeV on different timescales ranging ...from days to weeks. In addition to the four main intense and day-long flares detected by AGILE and Fermi-LAT between 2007 September and 2012 September, we find evidence for week-long and less intense episodes of enhanced gamma-ray emission that we call "waves." Statistically significant "waves" show timescales of 1-2 weeks, and can occur by themselves or in association with shorter flares. We present a refined flux and spectral analysis of the 2007 September-October gamma-ray enhancement episode detected by AGILE that shows both "wave" and flaring behavior. We extend our analysis to the publicly available Fermi-LAT data set and show that several additional "wave" episodes can be identified. We discuss the spectral properties of the 2007 September "wave"/flare event and show that the physical properties of the "waves" are intermediate between steady and flaring states. Plasma instabilities inducing "waves" appear to involve spatial distances l ~ 10 super(16) cm and enhanced magnetic fields B ~ (0.5-1) mG. Day-long flares are characterized by smaller distances and larger local magnetic fields. Typically, the deduced total energy associated with the "wave" phenomenon (E sub(w) ~ 10 super(42) erg, where E sub(w) is the kinetic energy of the emitting particles) is comparable with that associated to the flares, and can reach a few percent of the total available pulsar spin-down energy. Most likely, flares and waves are the product of the same class of plasma instabilities that we show acting on different timescales and radiation intensities.
We present the results of multi-year gamma-ray observations by the AGILE satellite of the black hole binary system Cygnus X-1. In a previous investigation we focused on gamma-ray observations of ...Cygnus X-1 in the hard state during the period mid-2007/2009. Here we present the results of the gamma-ray monitoring of Cygnus X-1 during the period 2010/mid-2012 which includes a remarkably prolonged "soft state" phase (2010 June-2011 May). Previous 1-10 MeV observations of Cyg X-1 in this state hinted at a possible existence of a non-thermal particle component with substantial modifications of the Comptonized emission from the inner accretion disk. Our AGILE data, averaged over the mid-2010/mid-2011 soft state of Cygnus X-1, provide a significant upper limit for gamma-ray emission above 100 MeV of F sub(soft) < 20 x 10 super(-8) photons cm super(-2) s super(-1), excluding the existence of prominent non-thermal emission above 100 MeV during the soft state of Cygnus X-1. We discuss theoretical implications of our findings in the context of high-energy emission models of black hole accretion. We also discuss possible gamma-ray flares detected by AGILE. In addition to a previously reported episode observed by AGILE in 2009 October during the hard state, we report a weak but important candidate for enhanced emission which occurred at the end of 2010 June (2010 June 30 10:00-2010 July 2 10:00 UT) exactly coinciding with a hard-to-soft state transition and before an anomalous radio flare. An appendix summarizes all previous high-energy observations and possible detections of Cygnus X-1 above 1 MeV.
During the month of 2009 December, the blazar 3C 454.3 became the brightest gamma-ray source in the sky, reaching a peak flux F {approx} 2000 x 10{sup -8} photons cm{sup -2} s{sup -1} for E > 100 ...MeV. Starting in 2009 November intensive multifrequency campaigns monitored the 3C 454 gamma-ray outburst. Here, we report on the results of a two-month campaign involving AGILE, INTEGRAL, Swift/XRT, Swift/BAT, and Rossi XTE for the high-energy observations and Swift/UVOT, KANATA, Goddard Robotic Telescope, and REM for the near-IR/optical/UV data. GASP/WEBT provided radio and additional optical data. We detected a long-term active emission phase lasting {approx}1 month at all wavelengths: in the gamma-ray band, peak emission was reached on 2009 December 2-3. Remarkably, this gamma-ray super-flare was not accompanied by correspondingly intense emission in the optical/UV band that reached a level substantially lower than the previous observations in 2007-2008. The lack of strong simultaneous optical brightening during the super-flare and the determination of the broadband spectral evolution severely constrain the theoretical modeling. We find that the pre- and post-flare broadband behavior can be explained by a one-zone model involving synchrotron self-Compton plus external Compton emission from an accretion disk and a broad-line region. However, the spectra of the 2009 December 2-3 super-flare and of the secondary peak emission on 2009 December 9 cannot be satisfactorily modeled by a simple one-zone model. An additional particle component is most likely active during these states.
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