An influence of radiation-induced damage on hydrogen isotope retention and transport in a bulk tungsten (W), dense nano-structured W coatings and Eurofer was investigated under well-defined ...laboratory conditions. Radiation-induced defects in W materials and Eurofer were created by irradiation with 20MeVW ions. Following the damage production, samples were exposed to low-energy deuterium plasma. The deuterium (D) retention in each sample was subsequently measured by nuclear reaction analysis (NRA) for the depth profiling up to 6μm. It was shown that the D retention at radiation-induced damage is almost equivalent for different W grades after irradiation at high enough fluence. The kinetic of D migration and trapping in damaged area as well as recovery of radiation-induced damage were investigated by loading at different temperatures. It was shown that deuterium retention in tungsten in fusion environment will be dominated by radiation-induced effect in a wide range of investigated temperatures, namely, from room temperature to 1100K. Whereas displacement damage produced in Eurofer has less pronounced effect on the deuterium accumulation.
The structure of the Al3Mn amorphous alloy synthesized by magnetron sputtering was investigated using a combination of anomalous X-ray scattering and reverse Monte Carlo simulations. The geometrical ...features in the short- and medium-range regions around Mn were significantly different from those inferred by the dense random packing of the hard-sphere model, suggesting that the environmental structure around Mn is influenced by chemical interactions similar to those realized in the crystalline Al3Mn structure. The present advanced analysis also indicated that the medium-range ordering structure corresponding to a pre-peak signal in the X-ray diffraction profiles was because of the Al-Mn and Mn-Mn correlations accompanied by the modulation of number density and non-Bernal-type coordination geometry.
Abstract
We present the most complete to date interferometric study of the centimeter-wavelength methanol masers detected in G358.93−0.03 at the burst and post-burst epochs. A unique, ...near-IR/(sub)millimeter-dark and far-IR-loud massive young stellar object accretion burst was recently discovered in G358.93−0.03. The event was accompanied by flares of an unprecedented number of rare methanol maser transitions. The first images of three of the newly discovered methanol masers at 6.18, 12.23, and 20.97 GHz are presented in this work. The spatial structure evolution of the methanol masers at 6.67, 12.18, and 23.12 GHz is studied at two epochs. The maser emission in all detected transitions resides in a region of ∼0.″2 around the bursting source and shows a clear velocity gradient in the north–south direction, with redshifted features to the north and blueshifted features to the south. A drastic change in the spatial morphology of the masing region is found: a dense and compact “spiral” cluster detected at epoch I evolved into a disperse, “round” structure at epoch II. During the transition from the first epoch to the second, the region traced by masers expanded. The comparison of our results with the complementary Very Large Array, very long baseline interferometry, Submillimeter Array, and Atacama Large Millimeter/submillimeter Array maser data is conducted. The obtained methanol maser data support the hypothesis of the presence of spiral arm structures within the accretion disk, which was suggested in previous studies of the source.
Cold-rolled Zr55Cu30Ni5Al10 bulk metallic glasses (BMGs) exhibited volume dilatation across the entire range of thickness reduction fractions from 5.7% to 63%. The dilatation was dominantly ...attributed to the free volume generated during cold-rolling, together with any open volumes, like the voids or microcracks, or both, which survived even after sufficiently annealing the rolled sample at the temperature in the supercooled liquid region. The relaxation of free volume formed during cold-rolling resulted in more heat evolution per unit volume than that of as-cast glass. The structural change during cold-rolling could be ascribed to the increased fluctuation of atomic-level hydrostatic stress, 〈p2〉, in the glass.
•Czochralski growth of nickel single crystal with a diameter of 8 in. was achieved.•No elongation of seeds was observed in produced nickel single crystals.•Ordinary mechanical mirror polishing ...introduces strain on the nickel wafer surface.
We grew large single crystals of metal nickel with a maximum diameter of 8 in. using the Czochralski (CZ) method. Characteristics of the metal material, namely, the seed elongation and intense cooling radiation at high temperatures during crystal growth, are the main challenges when growing ingots with large diameters. These problems were resolved by optimizing the parameters related to crystal growth, such as reduction of crucible and ingot rotation speed, and adjustment of shoulder formation angle of ingot shape. The produced ingots were confirmed to be single crystals by the Laue back-reflection method. Wafers were cut from single crystal ingots using a multi-wire saw with diamond abrasive grains. A smooth, mirror-like surface was obtained on the wafers by using an ordinary mechanical polishing method. The full width at half maximum values of the X-ray rocking curve of the metal nickel crystal surface significantly depends on the surface treatment method. It was found that ordinary mechanical mirror polishing introduces strain on the surface and non-uniformity of the crystal orientation.
•Numerical simulations of moist convection in Jupiter’s atmosphere are performed.•Dependencies on several atmospheric parameters are investigated.•Intermittent emergence of vigorous convective clouds ...is a robust feature.•The period of the intermittency is nearly proportional to deep water abundance.•Mechanism of the intermittency is investigated.
A series of long-term numerical simulations of moist convection in Jupiter’s atmosphere is performed in order to investigate the idealized characteristics of the vertical structure of multi-composition clouds and the convective motions associated with them, varying the deep abundances of condensable gases and the autoconversion time scale, the latter being one of the most questionable parameters in cloud microphysical parameterization. The simulations are conducted using a two-dimensional cloud resolving model that explicitly represents the convective motion and microphysics of the three cloud components, H2O, NH3, and NH4SH imposing a body cooling that substitutes the net radiative cooling. The results are qualitatively similar to those reported in Sugiyama et al. (Sugiyama, K. et al. 2011. Intermittent cumulonimbus activity breaking the three-layer cloud structure of Jupiter. Geophys. Res. Lett. 38, L13201. doi:10.1029/2011GL047878): stable layers associated with condensation and chemical reaction act as effective dynamical and compositional boundaries, intense cumulonimbus clouds develop with distinct temporal intermittency, and the active transport associated with these clouds results in the establishment of mean vertical profiles of condensates and condensable gases that are distinctly different from the hitherto accepted three-layered structure (e.g., Atreya, S.K., Romani, P.N. 1985. Photochemistry and clouds of Jupiter, Saturn and Uranus. In: Recent Advances in Planetary Meteorology. Cambridge Univ. Press, London, pp. 17–68). Our results also demonstrate that the period of intermittent cloud activity is roughly proportional to the deep abundance of H2O gas. The autoconversion time scale does not strongly affect the results, except for the vertical profiles of the condensates. Changing the autoconversion time scale by a factor of 100 changes the intermittency period by a factor of less than two, although it causes a dramatic increase in the amount of condensates in the upper troposphere.
The moist convection layer becomes potentially unstable with respect to an air parcel rising from below the H2O lifting condensation level (LCL) well before the development of cumulonimbus clouds. The instability accumulates until an appropriate trigger is provided by the H2O condensate that falls down through the H2O LCL; the H2O condensate drives a downward flow below the H2O LCL as a result of the latent cooling associated with the re-evaporation of the condensate, and the returning updrafts carry moist air from below to the moist convection layer. Active cloud development is terminated when the instability is completely exhausted. The period of intermittency is roughly equal to the time obtained by dividing the mean temperature increase, which is caused by active cumulonimbus development, by the body cooling rate.
ABSTRACT
The source G9.62+0.20E surprises yet again! Analysis of the associated methanol maser feature at vlsr = +8.8 km s−1 revealed a second period of P = 52.1 ± 0.3 d, along with the previously ...reported period P = 243 d for this source. Various explanations, harmonic flaring, Dicke’s superradiance, a secondary pulsation, or two different periodically varying radio sources in the field of view with associated methanol masers are presented. The latter two hypotheses appear more plausible but it is not clear which, if any, best describe these observations.
We present (sub)millimeter imaging at 0 5 resolution of the massive star-forming region G358.93−0.03 acquired in multiple epochs at 2 and 3 months following the recent flaring of its 6.7 GHz CH3OH ...maser emission. Using the Submillimeter Array and Atacama Large Millimeter/submillimeter Array, we have discovered 14 new Class II CH3OH maser lines ranging in frequency from 199 to 361 GHz, which originate mostly from = 1 torsionally excited transitions and include one = 2 transition. The latter detection provides the first observational evidence that Class II maser pumping involves levels in the = 2 state. The masers are associated with the brightest continuum source (MM1), which hosts a line-rich hot core. The masers present a consistent curvilinear spatial velocity pattern that wraps around MM1, suggestive of a coherent physical structure 1200 au in extent. In contrast, the thermal lines exhibit a linear pattern that crosses MM1 but at progressive position angles that appear to be a function of either increasing temperature or decreasing optical depth. The maser spectral profiles evolved significantly over one month, and the intensities dropped by factors of 3.0-7.2, with the = 2 line showing the largest change. A small area of maser emission from only the highest excitation lines closest to MM1 has disappeared. There are seven additional dust continuum sources in the protocluster, including another hot core (MM3). We do not find evidence for a significant change in (sub)millimeter continuum emission from any of the sources during the one month interval, and the total protocluster emission remains comparable to prior single-dish measurements.
Quantitative structure−activity relationship (QSAR) models are powerful in silico tools for predicting the mutagenicity of unstable compounds, impurities and metabolites that are difficult to examine ...using the Ames test. Ideally, Ames/QSAR models for regulatory use should demonstrate high sensitivity, low false-negative rate and wide coverage of chemical space. To promote superior model development, the Division of Genetics and Mutagenesis, National Institute of Health Sciences, Japan (DGM/NIHS), conducted the Second Ames/QSAR International Challenge Project (2020–2022) as a successor to the First Project (2014–2017), with 21 teams from 11 countries participating. The DGM/NIHS provided a curated training dataset of approximately 12,000 chemicals and a trial dataset of approximately 1,600 chemicals, and each participating team predicted the Ames mutagenicity of each trial chemical using various Ames/QSAR models. The DGM/NIHS then provided the Ames test results for trial chemicals to assist in model improvement. Although overall model performance on the Second Project was not superior to that on the First, models from the eight teams participating in both projects achieved higher sensitivity than models from teams participating in only the Second Project. Thus, these evaluations have facilitated the development of QSAR models.
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