Abstract
Clusteroluminogens refer to some non-conjugated molecules that show visible light and unique electronic properties with through-space interactions due to the formation of aggregates. ...Although mature and systematic theories of molecular photophysics have been developed to study conventional conjugated chromophores, it is still challenging to endow clusteroluminogens with designed photophysical properties by manipulating through-space interactions. Herein, three clusteroluminogens with non-conjugated donor-acceptor structures and different halide substituents are designed and synthesized. These compounds show multiple emissions and even single-molecule white-light emission in the crystalline state. The intensity ratio of these emissions is easily manipulated by changing the halide atom and excitation wavelength. Experimental and theoretical results successfully disclose the electronic nature of these multiple emissions: through-space conjugation for short-wavelength fluorescence, through-space charge transfer based on secondary through-space interactions for long-wavelength fluorescence, and room-temperature phosphorescence. The introduction of secondary through-space interactions to clusteroluminogens not only enriches their varieties of photophysical properties but also inspires the establishment of novel aggregate photophysics for clusteroluminescence.
We have developed and implemented an iterative algorithm of flux calibration for the LAMOST Spectroscopic Survey of the Galactic anticentre (LSS-GAC). For a given LSS-GAC plate, the spectra are first ...processed with a set of nominal spectral response curves (SRCs) and used to derive initial stellar atmospheric parameters (effective temperature T
eff, surface gravity log g and metallicity Fe/H) as well as dust reddening E(B − V) of all targeted stars. For each of the 16 spectrographs, several F-type stars with good signal-to-noise ratios are selected as flux standard stars for further, iterative spectral flux calibration. Comparison of spectrophotometric colours, deduced from the flux-calibrated spectra, with the photometric measurements yield average differences of 0.02 ± 0.07 and −0.04 ± 0.09 mag for (g − r) and (g − i), respectively. The relatively large negative offset in (g − i) is because we have opted not to correct for the telluric bands, most notably the atmospheric A band in the wavelength range of the i band. Comparison of LSS-GAC multi-epoch observations of duplicate targets indicates that the algorithm has achieved an accuracy of about 10 per cent in relative flux calibration for the wavelength range 4000–9000 Å. The shapes of SRCs deduced for individual LAMOST spectrographs vary by up to 30 per cent for a given night, and larger for different nights, indicating that the derivation of SRCs for the individual plates is essential to achieve accurate flux calibration for the LAMOST spectra.
For glasses, the structural origin of their flow phenomena, such as elastic and plastic deformations especially the microscopic hidden flow before yield and glass-to-liquid transition (GLT), is ...unclear yet due to the lack of structural information. Here we investigate the evolution of the microscopic localized flow during GLT in a prototypical metallic glass combining with dynamical mechanical relaxations, temperature-dependent tensile experiments and stress relaxation spectra. We show that the unstable and high mobility nano-scale liquid-like regions acting as flow units persist in the glass and can be activated by either temperature or external stress. The activation of such flow units is initially reversible and correlated with β-relaxation. As the proportion of the flow units reaches a critical percolation value, a mechanical brittle-to-ductile transition or macroscopic GLT happens. A comprehensive picture on the hidden flow as well as its correlation with deformation maps and relaxation spectrum is proposed.
The back-streaming neutrons (back-n) is a white neutron experimental facility at the China spallation neutron source (CSNS). The time structure of the primary proton beam makes it fully applicable to ...use the time-of-flight (TOF) method for neutron energy measuring. We implemented the electronics of TOF measurement on the general-purpose readout electronics designed for all the seven detectors in back-n. The electronics are based on the peripheral component interconnect express eXtensions for instrumentation (PXIe) platform, which is composed of field digitizer modules (FDM), trigger and clock modules (TCM), and signal conditioning modules. The T0 signal synchronous to the CSNS accelerator represents the neutron emission from the target. It is the start of the time stamp. The TCM receives, synchronizes, and distributes the T0 signal to each FDM based on the PXIe backplane bus. Meanwhile, the detector signals, after being conditioned, are fed into FDMs for waveform digitizing. The first sample point of the signal waveform is the stop of the time stamp. According to the time stamp and the time of the signal over the threshold, the total TOF can be obtained. The time-to-digital converter (TDC) based on field-programmable gate array (FPGA) is implemented on the TCM to accurately acquire the time interval between the asynchronous T0 signal and the global synchronous clock phase. There is also an FPGA-based TDC on the FDM to accurately acquire the time interval between the T0 signal arriving at the FDM and the first sample point of the signal waveform. The over-threshold time of signal is obtained offline. This method for TOF measurement is efficient and not needed for additional modules. Test results showed that the accuracy of TOF is subnanosecond and can meet the requirement for back-n at the CSNS.
Abstract
Ion Cyclotron Range of Frequencies (ICRF) heating and Neutral Beam Injection (NBI) can have synergy due to the acceleration of NBI beam ions by ICRF wave fields at their harmonics. To ...understand the influence of ICRF-NBI synergy on fast ion distribution and plasma performance, dedicated experiments and TRANSP simulations have been carried out on EAST. The simulation results are consistent with the experimental results. They show that the ICRF-NBI synergy not only accelerates the NBI beam ions with energy lower than 80 keV to energy larger than 300 keV, but also generates fusion neutrons with energy larger than 3 MeV. Moreover, ICRF-NBI synergy improves the plasma performance by increasing the poloidal beta, plasma stored energy, core ion temperature, total neutron yield and kinetic pressure. In a typical H-mode plasma with 1.0 MW NBI and 1.5 MW ICRF power, it was observed that ICRF-NBI synergy increases the poloidal beta, plasma stored energy, core ion temperature and neutron yield by ∼35%, 33%, 22% and 80%, respectively. Various parameter scans show that the ICRF-NBI synergetic effects can be enhanced by decreasing the minority ion concentration or the distance between the harmonic resonance and magnetic axis, or by increasing the ICRF heating power or NBI beam energy. Consequently, this leads to a generation of fast ions with higher energy. For instance, the maximum energy of the fast ion tail increases from 300 to 600 keV as n(H) decreases from 5% to 0.1%.
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