We present measurements of pion elliptic flow (ν2) in Au + Au collisions at sNN=200,62.4,39,27and19.6GeV, as a function of event-by-event charge asymmetry (A±), based on data from the STAR experiment ...at RHIC. We find that π−(π+) elliptic flow linearly increases (decreases) with charge asymmetry for most centrality bins and for all the beam energies under study. The slope parameter (r) from ν2(A±) difference between π− and π+ shows a centrality dependency similar to calculations of the Chiral Magnetic Wave. The measurements of charge separation with respect to the reaction plane in search of Local Parity Violation and the Chiral Magnetic Effect are also presented for Au+Au collisions at sNN=200,62.4,39,27,19.6,11.5and7.7GeV, and for U + U collisions at 193 GeV.
Integrating multiple mechanisms to maximize photothermal conversion efficiency is a significant strategy but remains challenging to construct therapeutic agents toward photothermal tumor treatment. ...Here, an approach to synthesize asymmetric Bi2Se3/CdSe‐Au hierarchical nanorods with excellent photothermal conversion is reported. Ag wetting‐layer is firstly grown to help overcome the interfacial lattice mismatch and promote the site‐selective growth of AgCdSe onto one end or side surface of Au nanorods. Subsequently, extraction of Ag+ ions out of lattice is observed during cation exchange reaction and epitaxial growth of Bi2Se3 shell. Bi2Se3/CdSe heterojunction with type‐II band alignment is formed and located at the plasmonic hotspots of Au nanorods, which experiences enhanced light absorption and accelerates the charge separation of photo‐excited carriers. Under excitation of near‐infrared 808 nm laser, the matchstick‐like Bi2Se3/CdSe‐Au nanorods show an excellent photothermal conversion, with 4.3 times temperature increment (ΔT) than that of bare Au nanorods. Moreover, in vitro and in vivo experiments verify them as excellent photothermal therapeutic agents.
Controlled growth of type‐II Bi2Se3/CdSe semiconductor heterojunction onto Au nanorods has spatial overlap with plasmonic hotspots. The spectral overlap of longitudinal surface plasmon resonance with near‐infrared excitation leads to optimized photothermal conversion for photothermal therapy.
In this article, we study the doubly heavy baryon states and pentaquark states with the QCD sum rules by carrying out the operator product expansion up to the vacuum condensates of dimension 7 and 13 ...respectively in a consistent way. In calculations, we separate the contributions of the negative parity and positive parity hadron states unambiguously, and study the masses and pole residues of the doubly heavy baryon states and pentaquark states in details. The present predictions can be confronted to the experimental data in the future.
Adsorption technology based on ethane‐selective materials is a promising alternative to energy‐intensive cryogenic distillation for separating ethane (C2H6) and ethylene (C2H4). We employed a pore ...engineering strategy to tune the pore environment of a metal–organic framework (MOF) through organic functional groups and boosted the C2H6/C2H4 separation of the MOF. Introduction of amino (−NH2) groups into Tb‐MOF‐76 not only decreased pore sizes but also facilitated multiple guest‐host interactions in confined pores. The NH2‐functionalized Tb‐MOF‐76(NH2) has increased C2H6 and C2H4 uptakes and C2H6/C2H4 selectivity. The results of experimental and simulated transient breakthroughs reveal that Tb‐MOF‐76(NH2) has significantly improved one‐step separation performance for C2H6/C2H4 mixtures with a high C2H4 (>99.95 %) productivity of 17.66 L kg−1 compared to 7.53 L kg−1 by Tb‐MOF‐76, resulting from the suitable pore confinement and accessible −NH2 groups on pore surfaces.
By virtue of a pore engineering strategy based on isoreticular chemistry, an amino‐functionalized metal–organic framework (MOF) with suitable pore confinement and more binding sites improved the ethane/ethylene separation performance compared to the parent MOF.
Molecular weight distribution of polymers, termed dispersity (Đ), is a fundamental parameter for determining polymer material properties. This paper reports a novel approach for controlling Đ by ...exploiting a temperature‐selective radical generation in organocatalyzed living radical polymerization. The polymers with tailored Đ were synthesized in a batch system without the assistance of an external pump. A unique aspect of this approach is that Đ was tuneable from 1.11 to 1.50 in any segment in diblock, triblock, and multiblock copolymers and in any form of star and brush polymer without segmental or topological restriction. This approach is amenable to various monomers and free from metals and thus attractive for applications. The approach also generated polymer brushes on surfaces with tailored Đ. An interesting finding was that the polymer brushes exhibited unique interaction with external molecules, depending on the Đ value.
Brush up: A novel approach for modulating polymer dispersity was developed. It is based on temperature‐selective organocatalyzed living radical polymerization and enabled dispersity modulation in any segment in linear and branched block copolymers as well as polymer brushes. A dispersity‐dependent size‐exclusion effect to external molecules was observed for the polymer brushes.
Single-degree-of-freedom lumped parameter model, conventional finite element method, and distributed parameter model have been developed to design, analyze, and predict the performance of ...piezoelectric energy harvesters with reasonable accuracy. In this article, a spectral finite element method for bimorph piezoelectric beam energy harvesters is developed based on the Timoshenko beam theory and the Euler–Bernoulli beam theory. Linear piezoelectric constitutive and linear elastic stress/strain models are assumed. Both beam theories are considered in order to examine the validation and applicability of each beam theory for a range of harvester sizes. Using spectral finite element method, a minimum number of elements is required because accurate shape functions are derived using the coupled electromechanical governing equations. Numerical simulations are conducted and validated using existing experimental data from the literature. In addition, parametric studies are carried out to predict the performance of a range of harvester sizes using each beam theory. It is concluded that the Euler–Bernoulli beam theory is sufficient enough to predict the performance of slender piezoelectric beams (slenderness ratio > 20, that is, length over thickness ratio > 20). In contrast, the Timoshenko beam theory, including the effects of shear deformation and rotary inertia, must be used for short piezoelectric beams (slenderness ratio < 5).
One‐step C2H4 purification from ternary C2H6/C2H4/C2H2 mixtures by a single adsorbent is of great industrial significance, but few adsorbents achieve this separation. Herein, we report a robust ...metal–organic framework (MOF) that possesses methyl‐decorated nonpolar pores and shows one‐step C2H4 purification (purity >99.9 %) from binary C2H6/C2H4 mixtures and ternary C2H6/C2H4/C2H2 mixtures. The methyl groups in pores provide a suitable pore environment to simultaneously enhance the adsorption capacity for C2H2 and C2H6 compared to C2H4. Simulations revealed the multiple interactions between C2H6 or C2H2 molecules and the pore wall, while the interactions with C2H4 molecules are weak and also unfavorable due to the repulsion from methyl groups in pores. The MOF displays high C2H6 and C2H2 uptakes and benchmark C2H6/C2H4 selectivity (2.2), surpassing all of the reported MOFs for one‐step C2H4 purification from ternary C2H6/C2H4/C2H2 mixtures.
The combination of nonpolar pore environment and accessible active sites in a metal–organic framework affords benchmark C2H6/C2H4 selectivity and realizes one‐step C2H4 purification from ternary C2H6/C2H4/C2H2 mixtures.
The recent decades have seen a surge of new nanomaterials designed for efficient drug delivery. DNA nanotechnology has been developed to construct sophisticated 3D nanostructures and artificial ...molecular devices that can be operated at the nanoscale, giving rise to a variety of programmable functions and fascinating applications. In particular, DNA‐origami nanostructures feature rationally designed geometries and precise spatial addressability, as well as marked biocompatibility, thus providing a promising candidate for drug delivery. Here, the recent successful efforts to employ self‐assembled DNA‐origami nanostructures as drug‐delivery vehicles are summarized. The remaining challenges and open opportunities are also discussed.
Structural DNA nanotechnology provides a biocompatible platform to construct customized nanocarriers. Recent developments of DNA‐origami‐based drug‐delivery systems are summarized. Multifunctional, highly tunable, and biologically amenable, DNA‐based nanomaterials will provide powerful strategies to understand and treat disease.
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