River eco-environmental value assessment is indispensable for the optimal allocation of watershed water resources. In this study, river eco-environmental values were divided into the values inside ...and outside the river based on the energy transfer and transformation of the water cycle. Their spatial distribution characteristics (spatial distribution map, spatial autocorrelation, and spatial aggregation) of 67 regions (states, leagues, and cities) in the Yellow River Basin (YRB) were analysed by combining emergy theory and GeoDa 1.14 software (emergy-GeoDa), and the significance of the results was tested. The results showed that: (1) the eco-environmental values inside the river were higher than those outside in the YRB, proving that eco-environmental water inside the river should be guaranteed and water consumption outside the river should not occupy water inside the river from the perspective of value; (2) the spatial distributions of eco-environmental values inside and outside the river were uneven, but obvious spatial aggregations were observed; (3) high- and low-value aggregations of eco-environmental values were observed inside the river in the lower and upper reaches of the YRB, respectively; (4) high- and low-value aggregations of eco-environmental values were observed outside the river in the middle and upper reaches of the YRB, respectively. It was suggested that ecological conservation and high-quality development should be considered as the goals for consolidating the river eco-environmental values in high-value areas and promoting in low-value areas, and low-value areas should be improved by high-value areas while allocating water resources in the YRB. These results provide suggestions for the sustainable development of river eco-environmental system in the YRB from a spatial perspective. In addition, the analysis method is also applicable for studying the spatial distribution characteristics of the values generated by the water and energy cycles of other regions.
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•Deeply explore the connotation and composition of river eco-environmental values•Realize the quantification of eco-environmental value inside and outside the river•Propose Emergy-Geoda to study the spatial distribution characteristics of values•Emergy-Geoda is applied to 67 regions in the Yellow River Basin.•Uneven spatial distribution, with positive correlation and spatial aggregation
Polymer hydrogels that are capable of spontaneously healing injury are being developed at a rapid pace because of their great potential in biomedical applications. Here, the self‐healing property of ...tough graphene nanocomposite hydrogels fabricated by using graphene peroxide as polyfunctional initiating and cross‐linking centers is reported. The hydrogels show excellent self‐healing ability at ambient temperature or even lower temperatures for a short time and very high recovery degrees (up to 88% tensile strength) can be achieved at a prolonged healing time. The healed gels exhibit very high tensile strengths (up to 0.35 MPa) and extremely high elongations (up to 4900%). The strong interactions between the polyacrylamide chains and the graphene oxide sheets are essential to the mechanical strengths of the healed gels.
Graphene oxide composite hydrogels fabricated by using graphene peroxide as polyfunctional initiating and cross‐linking centers exhibit excellent self‐healing behavior. The healed gels exhibit very high tensile strength (up to 0.35 MPa) and extremely high elongations (up to 4900%).
Anthocyanin pigmentation is an important consumer trait in peach (Prunus persica). In this study, the genetic basis of the blood‐flesh trait was investigated using the cultivar Dahongpao, which shows ...high levels of cyanidin‐3‐glucoside in the mesocarp. Elevation of anthocyanin levels in the flesh was correlated with the expression of an R2R3 MYB transcription factor, PpMYB10.1. However, PpMYB10.1 did not co‐segregate with the blood‐flesh trait. The blood‐flesh trait was mapped to a 200‐kb interval on peach linkage group (LG) 5. Within this interval, a gene encoding a NAC domain transcription factor (TF) was found to be highly up‐regulated in blood‐fleshed peaches when compared with non‐red‐fleshed peaches. This NAC TF, designated BLOOD (BL), acts as a heterodimer with PpNAC1 which shows high levels of expression in fruit at late developmental stages. We show that the heterodimer of BL and PpNAC1 can activate the transcription of PpMYB10.1, resulting in anthocyanin pigmentation in tobacco. Furthermore, silencing the BL gene reduces anthocyanin pigmentation in blood‐fleshed peaches. The transactivation activity of the BL‐PpNAC1 heterodimer is repressed by a SQUAMOSA promoter‐binding protein‐like TF, PpSPL1. Low levels of PpMYB10.1 expression in fruit at early developmental stages is probably attributable to lower levels of expression of PpNAC1 plus the presence of high levels of repressors such as PpSPL1. We present a mechanism whereby BL is the key gene for the blood‐flesh trait in peach via its activation of PpMYB10.1 in maturing fruit. Partner TFs such as basic helix–loop‐helix proteins and NAC1 are required, as is the removal of transcriptional repressors.
Bidirectional interfacing with the nervous system enables neuroscience research, diagnosis, and therapy. This two-way communication allows us to monitor the state of the brain and its composite ...networks and cells as well as to influence them to treat disease or repair/restore sensory or motor function. To provide the most stable and effective interface, the tools of the trade must bridge the soft, ion-rich, and evolving nature of neural tissue with the largely rigid, static realm of microelectronics and medical instruments that allow for readout, analysis, and/or control. In this Review, we describe how the understanding of neural signaling and material-tissue interactions has fueled the expansion of the available tool set. New probe architectures and materials, nanoparticles, dyes, and designer genetically encoded proteins push the limits of recording and stimulation lifetime, localization, and specificity, blurring the boundary between living tissue and engineered tools. Understanding these approaches, their modality, and the role of cross-disciplinary development will support new neurotherapies and prostheses and provide neuroscientists and neurologists with unprecedented access to the brain.
Evapotranspiration (ET) is a key link between atmospheric processes and land surface hydrological processes. With the impact of global warming and human activities, research on ET has become a hot ...topic. Supported by a total of 1,222 Chinese and English literatures from China National Knowledge Infrastructure and the Web of Science Core Collection from 2013 to 2022, this paper adopts the bibliometric visualization method to review the current research progress and future trend of ET with respect to the time of publication, countries, institutions, journals, and research hotspots. The results show that the number of related research articles is increasing rapidly and the journals with high citations are Journal of Hydrology, Agricultural and Forest Meteorology and Agricultural Water Management. The research hotspots have been focused on prototype observation, remote sensing inversion, mechanism equation, model simulation, spatial-temporal analysis, and attribution identification. In the future, there is an urgent need to integrate algorithms such as machine learning and artificial intelligence, to develop higher resolution remote sensing products, to improve the mechanism equations based on precise observations, and to clarify the impact of synergistic effects on ET among the driving factors.
Conducting polymer hydrogels represent a unique class of materials that synergizes the advantageous features of hydrogels and organic conductors and have been used in many applications such as ...bioelectronics and energy storage devices. They are often synthesized by polymerizing conductive polymer monomer within a nonconducting hydrogel matrix, resulting in deterioration of their electrical properties. Here, we report a scalable and versatile synthesis of multifunctional polyaniline (PAni) hydrogel with excellent electronic conductivity and electrochemical properties. With high surface area and three-dimensional porous nanostructures, the PAni hydrogels demonstrated potential as high-performance supercapacitor electrodes with high specific capacitance (∼480 F·g ⁻¹), unprecedented rate capability, and cycling stability (∼83% capacitance retention after 10,000 cycles). The PAni hydrogels can also function as the active component of glucose oxidase sensors with fast response time (∼0.3 s) and superior sensitivity (∼16.7 μA·mM ⁻¹). The scalable synthesis and excellent electrode performance of the PAni hydrogel make it an attractive candidate for bioelectronics and future-generation energy storage electrodes.
In 1999, the Yellow River Basin (YRB) launched the Grain for Green Program (GGP), which has had a huge impact on the Yellow River Basin vegetation. Research regarding the causes of vegetation changes ...can provide beneficial information for the management and construction of the ecological environment in the Yellow River Basin. In this study, after reconstructing the relationship between vegetation and climate change under natural conditions, topographic factors were introduced to understand vegetation change in the Yellow River Basin before and after the initiation of the Grain for Green Program, and the contribution rates of the driving factors of change were analyzed. Results show that human activities have had a great impact on the vegetation cover in the Yellow River Basin. We found that after the start of the Grain for Green Program, the vegetation recovery rate was more than six times (slope = 0.0067) that before its start (slope = 0.0011); high NDVI levels moved to lower altitudes, while low NDVI levels moved to high altitudes; and most vegetation types turned to gentle slopes. Human activities and climate change are the dominant factors influencing vegetation coverage, and the contribution rate of human activities had reached 59.3% after 2000, with a tendency to gradually dominate.
Human skin relies on cutaneous receptors that output digital signals for tactile sensing in which the intensity of stimulation is converted to a series of voltage pulses. We present a power-efficient ...skin-inspired mechanoreceptor with a flexible organic transistor circuit that transduces pressure into digital frequency signals directly. The output frequency ranges between 0 and 200 hertz, with a sublinear response to increasing force stimuli that mimics slow-adapting skin mechanoreceptors. The output of the sensors was further used to stimulate optogenetically engineered mouse somatosensory neurons of mouse cortex in vitro, achieving stimulated pulses in accordance with pressure levels. This work represents a step toward the design and use of large-area organic electronic skins with neural-integrated touch feedback for replacement limbs.
Large scale energy storage system with low cost, high power, and long cycle life is crucial for addressing the energy problem when connected with renewable energy production. To realize grid-scale ...applications of the energy storage devices, there remain several key issues including the development of low-cost, high-performance materials that are environmentally friendly and compatible with low-temperature and large-scale processing. In this report, we demonstrate that solution-exfoliated graphene nanosheets (∼5 nm thickness) can be conformably coated from solution on three-dimensional, porous textiles support structures for high loading of active electrode materials and to facilitate the access of electrolytes to those materials. With further controlled electrodeposition of pseudocapacitive MnO(2) nanomaterials, the hybrid graphene/MnO(2)-based textile yields high-capacitance performance with specific capacitance up to 315 F/g achieved. Moreover, we have successfully fabricated asymmetric electrochemical capacitors with graphene/MnO(2)-textile as the positive electrode and single-walled carbon nanotubes (SWNTs)-textile as the negative electrode in an aqueous Na(2)SO(4) electrolyte solution. These devices exhibit promising characteristics with a maximum power density of 110 kW/kg, an energy density of 12.5 Wh/kg, and excellent cycling performance of ∼95% capacitance retention over 5000 cycles. Such low-cost, high-performance energy textiles based on solution-processed graphene/MnO(2) hierarchical nanostructures offer great promise in large-scale energy storage device applications.
Functionalized graphene has been considered as one of the most important materials for preparing polymer nanocomposites due to its unique physical structure and properties. To increase the ...interfacial interaction between polymer component and graphene oxide (GO) sheets, in situ grafting polymerization initiated by a free radical initiator immobilized on GO sheets is a better choice. We report a facile and effective strategy for preparing graphene peroxide (GPO) via the radiation-induced peroxidation of GO. The formation of peroxides on GO is proven by iodometric measurement and other characterizations. Using GPO as a polyfunctional initiating and cross-linking center, we obtained GO composite hydrogels exhibiting excellent mechanical properties, namely, very high tensile strength (0.2-1.2 MPa), extremely high elongations (2000-5300%), and excellent resilience. This work provides new insight into the fabrication of GO/polymer nanocomposites to fulfill the excellent mechanical properties of graphene.
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