Widespread access to greener energy is required in order to mitigate the effects of climate change. A significant barrier to cleaner natural gas usage lies in the safety/efficiency limitations of ...storage technology. Despite highly porous metal-organic frameworks (MOFs) demonstrating record-breaking gas-storage capacities, their conventionally powdered morphology renders them non-viable. Traditional powder shaping utilising high pressure or chemical binders collapses porosity or creates low-density structures with reduced volumetric adsorption capacity. Here, we report the engineering of one of the most stable MOFs, Zr-UiO-66, without applying pressure or binders. The process yields centimetre-sized monoliths, displaying high microporosity and bulk density. We report the inclusion of variable, narrow mesopore volumes to the monoliths' macrostructure and use this to optimise the pore-size distribution for gas uptake. The optimised mixed meso/microporous monoliths demonstrate Type II adsorption isotherms to achieve benchmark volumetric working capacities for methane and carbon dioxide. This represents a critical advance in the design of air-stable, conformed MOFs for commercial gas storage.
Abstract
We have performed ground-based transmission spectroscopy of the hot Jupiter HAT-P-18b using the ACAM instrument on the William Herschel Telescope (WHT). Differential spectroscopy over an ...entire night was carried out at a resolution of R ≈ 400 using a nearby comparison star. We detect a blueward slope extending across our optical transmission spectrum that runs from 4750 to 9250 Å. The slope is consistent with Rayleigh scattering at the equilibrium temperature of the planet (852 K). We do not detect enhanced sodium absorption, which indicates that a high-altitude haze is masking the feature and giving rise to the Rayleigh slope. This is only the second discovery of a Rayleigh-scattering slope in a hot Jupiter atmosphere from the ground, and our study illustrates how ground-based observations can provide transmission spectra with precision comparable to the Hubble Space Telescope.
The ultracool dwarf star TRAPPIST-1 hosts seven Earth-size transiting planets, some of which could harbor liquid water on their surfaces. Ultraviolet observations are essential to measuring their ...high-energy irradiation and searching for photodissociated water escaping from their putative atmospheres. Our new observations of the TRAPPIST-1 Ly line during the transit of TRAPPIST-1c show an evolution of the star emission over three months, preventing us from assessing the presence of an extended hydrogen exosphere. Based on the current knowledge of the stellar irradiation, we investigated the likely history of water loss in the system. Planets b to d might still be in a runaway phase, and planets within the orbit of TRAPPIST-1g could have lost more than 20 Earth oceans after 8 Gyr of hydrodynamic escape. However, TRAPPIST-1e to h might have lost less than three Earth oceans if hydrodynamic escape stopped once they entered the habitable zone (HZ). We caution that these estimates remain limited by the large uncertainty on the planet masses. They likely represent upper limits on the actual water loss because our assumptions maximize the X-rays to ultraviolet-driven escape, while photodissociation in the upper atmospheres should be the limiting process. Late-stage outgassing could also have contributed significant amounts of water for the outer, more massive planets after they entered the HZ. While our results suggest that the outer planets are the best candidates to search for water with the JWST, they also highlight the need for theoretical studies and complementary observations in all wavelength domains to determine the nature of the TRAPPIST-1 planets and their potential habitability.
Abstract
We have performed ground-based transmission spectroscopy of the hot Jupiter orbiting the cool dwarf WASP-80 using the ACAM instrument on the William Herschel Telescope (WHT) as part of the ...Low-Resolution Ground-Based Exoplanet Atmosphere Survey using Transmission Spectroscopy programme. This is the third paper of a ground-based transmission spectroscopy survey of hot Jupiters using low-resolution grism spectrographs. We observed two transits of the planet and have constructed transmission spectra spanning a wavelength range of 4640–8840 Å. Our transmission spectrum is inconsistent with a previously claimed detection of potassium in WASP-80b's atmosphere, and is instead most consistent with a haze. We also do not see evidence for sodium absorption at a resolution of 100 Å.
We are entering an era of unprecedented quantities of data from current and planned survey telescopes. To maximize the potential of such surveys, automated data analysis techniques are required. Here ...we implement a new methodology for variable star classification, through the combination of Kohonen Self-Organizing Maps (SOMs, an unsupervised machine learning algorithm) and the more common Random Forest (RF) supervised machine learning technique. We apply this method to data from the K2 mission fields 0–4, finding 154 ab-type RR Lyraes (10 newly discovered), 377 δ Scuti pulsators, 133 γ Doradus pulsators, 183 detached eclipsing binaries, 290 semidetached or contact eclipsing binaries and 9399 other periodic (mostly spot-modulated) sources, once class significance cuts are taken into account. We present light-curve features for all K2 stellar targets, including their three strongest detected frequencies, which can be used to study stellar rotation periods where the observed variability arises from spot modulation. The resulting catalogue of variable stars, classes, and associated data features are made available online. We publish our SOM code in python as part of the open source pymvpa package, which in combination with already available RF modules can be easily used to recreate the method.
By studying Swift X-ray spectra of an optically selected, non-magnetic sample of nearby cataclysmic variables (CVs), we show that there is a population with X-ray luminosity much lower than accounted ...for in existing studies. We find an average 0.5-10.0 keV luminosity of
which is an order of magnitude lower than observed in previous samples. Looking at the co-added X-ray spectrum of 20 CVs, we show that the spectral properties of this optically selected, low X-ray luminosity sample - likely characteristic of the dominant population of CVs - resemble that of their brighter counterpart, as well as the X-ray emission originating in the Galactic ridge. It is argued that if the space density of CVs is greater than the current estimates, as it is indeed predicted by population synthesis models, then CVs can significantly contribute to the Galactic ridge emission.
Since the start of the Wide-angle Search for Planets (WASP) program, more than 160 transiting exoplanets have been discovered in the WASP data. In the past, possible transit-like events identified by ...the WASP pipeline have been vetted by human inspection to eliminate false alarms and obvious false positives. The goal of this paper is to assess the effectiveness of machine learning as a fast, automated, and reliable means of performing the same functions on ground-based wide-field transit-survey data without human intervention. To this end, we have created training and test data sets made up of stellar light curves showing a variety of signal types including planetary transits, eclipsing binaries, variable stars, and non-periodic signals. We use a combination of machine-learning methods including Random Forest Classifiers (RFCs) and convolutional neural networks (CNNs) to distinguish between the different types of signals. The final algorithms correctly identify planets in the test data ∼90 per cent of the time, although each method on its own has a significant fraction of false positives. We find that in practice, a combination of different methods offers the best approach to identifying the most promising exoplanet transit candidates in data from WASP, and by extension similar transit surveys.
The M dwarf GJ 436 hosts a transiting warm Neptune known to experience atmospheric escape. Previous observations revealed the presence of a giant hydrogen exosphere transiting the star for more than ...5 h, and absorbing up to 56% of the flux in the blue wing of the stellar Lyman-α line of neutral hydrogen (H i Lyα). The unexpected size of this comet-like exosphere prevented observing the full transit of its tail. In this Letter, we present new Lyα observations of GJ 436 obtained with the Space Telescope Imaging Spectrograph (STIS) instrument onboard the Hubble Space Telescope. The stability of the Lyα line over six years allowed us to combine these new observations with archival data sets, substantially expanding the coverage of the exospheric transit. Hydrogen atoms in the tail of the exospheric cloud keep occulting the star for 10–25 h after the transit of the planet, remarkably confirming a previous prediction based on 3D numerical simulations with the EVaporating Exoplanet code (EVE). This result strengthens the interpretation that the exosphere of GJ 436b is shaped by both radiative braking and charge exchanges with the stellar wind. We further report flux decreases of 15 ± 2% and 47 ± 10% in the red wing of the Lyα line and in the line of ionised silicon (Si iii). Despite some temporal variability possibly linked with stellar activity, these two signals occur during the exospheric transit and could be of planetary origin. Follow-up observations will be required to assess the possibility that the redshifted Lyα and Si iii absorption signatures arise from interactions between the exospheric flow and the magnetic field of the star.
Atmospheric escape has been detected from the exoplanet HD 209458b through transit observations of the hydrogen Lyman-α line. Here we present spectrally resolved Lyman-α transit observations of the ...exoplanet HD 189733b at two different epochs. These HST/STIS observations show for the first time that there are significant temporal variations in the physical conditions of an evaporating planetary atmosphere. While atmospheric hydrogen is not detected in the first epoch observations, it is observed at the second epoch, producing a transit absorption depth of 14.4 ± 3.6% between velocities of −230 to −140 km s-1. Contrary to HD 209458b, these high velocities cannot arise from radiation pressure alone and require an additional acceleration mechanism, such as interactions with stellar wind protons. The observed absorption can be explained by an atmospheric escape rate of neutral hydrogen atoms of about 109 g s-1, a stellar wind with a velocity of 190 km s-1 and a temperature of ~105 K. An X-ray flare from the active star seen with Swift/XRT 8 h before the second-epoch observation supports the idea that the observed changes within the upper atmosphere of the planet can be caused by variations in the stellar wind properties, or by variations in the stellar energy input to the planetary escaping gas (or a mix of the two effects). These observations provide the first indication of interaction between the exoplanet’s atmosphere and stellar variations.
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